Ron Raphaeli
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View article: N<sub>2</sub> Dissociation vs Reversible 1,2-Methyl Migration in PC<sub>NHC</sub>P Cobalt(I) Complexes in the Stereoselective Isomerization (<i>E/Z</i>) of Allyl Ethers
N<sub>2</sub> Dissociation vs Reversible 1,2-Methyl Migration in PC<sub>NHC</sub>P Cobalt(I) Complexes in the Stereoselective Isomerization (<i>E/Z</i>) of Allyl Ethers Open
With growing efforts pushing toward sustainable catalysis, using earth-abundant metals has become increasingly important. Here, we present the first examples of cobalt PCNHCP pincer complexes that demonstrate dual stereoselectivity for all…
View article: Reversible 1,2-Methyl Migration to an N-Heterocyclic Carbene in a PCNHCP Cobalt(I) Complex Enables Stereoselective (E and Z) Allyl Ether Isomerization
Reversible 1,2-Methyl Migration to an N-Heterocyclic Carbene in a PCNHCP Cobalt(I) Complex Enables Stereoselective (E and Z) Allyl Ether Isomerization Open
With growing efforts pushing towards sustainable catalysis, using earth-abundant metals has become increasingly important. Here we present the first examples of cobalt PCNHCP pincer complexes that demonstrate dual stereoselectivity for all…