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View article: Engineering Alloying and Conversion Interlayers for Anode‐Less Solid‐State Batteries
Engineering Alloying and Conversion Interlayers for Anode‐Less Solid‐State Batteries Open
Anode‐less solid‐state batteries offer a pathway to maximize energy density while simplifying device manufacturing. However, the absence of an initial lithium (Li) reservoir demands precise control over Li deposition, a process usually hin…
View article: Engineering a Stable Solid–Electrolyte Interphase through a Novel Trifluoromethyl‐Free Lithium Salt for Lithium Metal Polymer Batteries
Engineering a Stable Solid–Electrolyte Interphase through a Novel Trifluoromethyl‐Free Lithium Salt for Lithium Metal Polymer Batteries Open
The deployment of safe and high‐energy density lithium metal polymer batteries (LMPBs) still requires further advances in the quest for new solid polymer electrolytes (SPEs). In this regard, salt anions have a decisive role in the overall …
View article: Nanoscale sputtered buffer layers for <i>in situ</i> fabrication of thin sodium metal anodes
Nanoscale sputtered buffer layers for <i>in situ</i> fabrication of thin sodium metal anodes Open
Sodium (Na) metal is a highly attractive anode material for next-generation batteries due to its natural abundance and low cost, but its practical use is limited by the poor reversibility of the Na plating/stripping process and instability…
View article: Imidazole-based LiHDI salt for SEI optimization in silicon anodes
Imidazole-based LiHDI salt for SEI optimization in silicon anodes Open
View article: Enabling Anode-Less Lithium Batteries via Sacrificial Salts: An In-Depth Feasibility Analysis
Enabling Anode-Less Lithium Batteries via Sacrificial Salts: An In-Depth Feasibility Analysis Open
Anode-less batteries have gained due attention, considering the easy industrial and safer processes involved. The initial absence of an anode ideally improves the gravimetric and volumetric capacity in a battery, and the assembly process i…
View article: Advanced manufacturing of thin-film lithium metal anode by pulsed-laser deposition for next-generation solid-state batteries
Advanced manufacturing of thin-film lithium metal anode by pulsed-laser deposition for next-generation solid-state batteries Open
View article: Quasi-solid polymer electrolytes with binary and ternary salt mixtures for high-voltage lithium metal batteries
Quasi-solid polymer electrolytes with binary and ternary salt mixtures for high-voltage lithium metal batteries Open
Quasi-solid polymer electrolytes (QSPEs) are considered a promising alternative to liquid electrolytes for high-voltage lithium metal batteries. Herein, we present their properties and performance supported on polyolefin microporous separa…
View article: Failure mode diagnosis and stabilization of an efficient reverse-bias bipolar membrane CO<sub>2</sub> to CO electrolyzer
Failure mode diagnosis and stabilization of an efficient reverse-bias bipolar membrane CO<sub>2</sub> to CO electrolyzer Open
Efficient and stable CO 2 -to-CO electrolyzers are key process components for the generation of green CO gas and its downstream conversion and valorization to carbonaceous e-chemicals and e-fuels.
View article: Investigation of Ni2p XPS spectra and Bonding in Oxide-Free Nickel Nitride Compounds
Investigation of Ni2p XPS spectra and Bonding in Oxide-Free Nickel Nitride Compounds Open
View article: Investigation of Ni2p Xps Spectra and Bonding in Nickel Nitride Compounds
Investigation of Ni2p Xps Spectra and Bonding in Nickel Nitride Compounds Open
View article: On the role of ultrathin lithium metal anodes produced by thermal evaporation
On the role of ultrathin lithium metal anodes produced by thermal evaporation Open
View article: Influence of physicochemical properties on the thermochemical water splitting performance and H2 production of CoFe2O4
Influence of physicochemical properties on the thermochemical water splitting performance and H2 production of CoFe2O4 Open
This research investigates the impact of physicochemical properties on the thermochemical redox ability of CoFe2O4 for water splitting application. Three samples with different properties (CFO-A, CFO-B, and CFO-C) are evaluated. The result…
View article: On the practical applicability of thermal evaporation technique to fabricate Na thin metal anodes for Na-metal batteries
On the practical applicability of thermal evaporation technique to fabricate Na thin metal anodes for Na-metal batteries Open
We demonstrate, as proof of concept, a materials design path that allows us to exploit thermal deposition technique to fabricate sodium (Na) metal anodes at the microscale. Our study reveals that Na thin anodes <10 μm, directly coated on a…
View article: On the X-Ray Photoelectron Spectroscopy of Nickel Nitride Compounds
On the X-Ray Photoelectron Spectroscopy of Nickel Nitride Compounds Open
View article: Benchmarking La‐Based Perovskites as Bifunctional Cathodes For Primary and Rechargeable Zinc−Air Batteries with Biopolymer‐Based Electrolyte
Benchmarking La‐Based Perovskites as Bifunctional Cathodes For Primary and Rechargeable Zinc−Air Batteries with Biopolymer‐Based Electrolyte Open
State‐of‐the‐art perovskite‐based electrocatalysts for zinc−air batteries (ZABs) may include one or more Critical Raw Materials (CRMs) like Co, Ru, and rare earth elements, for oxygen reduction/evolution reactions. Under the warnings descr…
View article: Evaluation of Electronic–Ionic Transport Properties of a Mg/Zr-Modified LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4</sub> Cathode for Li-Ion Batteries
Evaluation of Electronic–Ionic Transport Properties of a Mg/Zr-Modified LiNi<sub>0.5</sub>Mn<sub>1.5</sub>O<sub>4</sub> Cathode for Li-Ion Batteries Open
There is an enormous drive for moving toward cathode material research in LIBs due to the proposal of zero-emission electric vehicles together with the restriction of cathode materials in design. LiNi0.5Mn1.5O4
View article: Graphene‐Based Sulfur Cathodes and Dual Salt‐Based Sparingly Solvating Electrolytes: A Perfect Marriage for High Performing, Safe, and Long Cycle Life Lithium‐Sulfur Prototype Batteries
Graphene‐Based Sulfur Cathodes and Dual Salt‐Based Sparingly Solvating Electrolytes: A Perfect Marriage for High Performing, Safe, and Long Cycle Life Lithium‐Sulfur Prototype Batteries Open
The growing requirements for electrified applications entail exploring alternative battery systems. Lithium‐sulfur batteries (LSBs) have emerged as a promising, cost‐effective, and sustainable solution; however, their practical commerciali…
View article: Dehydrofluorination Process of Poly(vinylidene difluoride) PVdF-Based Gel Polymer Electrolytes and Its Effect on Lithium-Sulfur Batteries
Dehydrofluorination Process of Poly(vinylidene difluoride) PVdF-Based Gel Polymer Electrolytes and Its Effect on Lithium-Sulfur Batteries Open
Gel polymer electrolytes (GPEs) are emerging as suitable candidates for high-performing lithium-sulfur batteries (LSBs) due to their excellent performance and improved safety. Within them, poly(vinylidene difluoride) (PVdF) and its derivat…
View article: Brewery waste derived activated carbon for high performance electrochemical capacitors and lithium-ion capacitors
Brewery waste derived activated carbon for high performance electrochemical capacitors and lithium-ion capacitors Open
View article: Electrochemical Evaluation of Different Graphite Felt Electrode Treatments in Full Vanadium Redox Flow Batteries
Electrochemical Evaluation of Different Graphite Felt Electrode Treatments in Full Vanadium Redox Flow Batteries Open
The use of flow batteries for energy storage has attracted considerable attention with the increased use of renewable resources. It is well known that the performance of a flow battery depends, among other factors, on the properties of the…
View article: Monolithic All-Solid-State High-Voltage Li-Metal Thin-Film Rechargeable Battery
Monolithic All-Solid-State High-Voltage Li-Metal Thin-Film Rechargeable Battery Open
The substitution of an organic liquid electrolyte with lithium-conducting solid materials is a promising approach to overcome the limitations associated with conventional lithium-ion batteries. These constraints include a reduced electroch…
View article: Microstructured nitrogen-doped graphene-Sn composites as a negative electrode for high performance lithium-ion hybrid supercapacitors
Microstructured nitrogen-doped graphene-Sn composites as a negative electrode for high performance lithium-ion hybrid supercapacitors Open
Microstructured nitrogen-doped graphene-Sn synthetized in one step for high performance and long-term cycling stability lithium-ion capacitors.
View article: Enhancing the polymer electrolyte–Li metal interface on high-voltage solid-state batteries with Li-based additives inspired by the surface chemistry of Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub>
Enhancing the polymer electrolyte–Li metal interface on high-voltage solid-state batteries with Li-based additives inspired by the surface chemistry of Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> Open
High-voltage Li metal solid-state batteries are in the spotlight as high energy and power density devices for the next generation of batteries.
View article: Unveiling the Role of Tetrabutylammonium and Cesium Bulky Cations in Enhancing Na‐O<sub>2</sub> Battery Performance
Unveiling the Role of Tetrabutylammonium and Cesium Bulky Cations in Enhancing Na‐O<sub>2</sub> Battery Performance Open
The use of two types of bulky cations, tetrabutylammonium (TBA + ) and Cs + , as electrolyte additives in Na‐O 2 batteries is investigated. These cations facilitate the stabilization of sodium superoxide in the electrolyte, promoting the s…
View article: Improving the CO and CH4 Gas Sensor Response at Room Temperature of α-Fe2O3(0001) Epitaxial Thin Films Grown on SrTiO3(111) Incorporating Au(111) Islands
Improving the CO and CH4 Gas Sensor Response at Room Temperature of α-Fe2O3(0001) Epitaxial Thin Films Grown on SrTiO3(111) Incorporating Au(111) Islands Open
In this work, the functional character of complex α-Fe2O3(0001)/SrTiO3(111) and Au(111) islands/α-Fe2O3(0001)/SrTiO3(111) heterostructures has been proven as gas sensors at room temperature. Epitaxial Au islands and α-Fe2O3 thin film are g…
View article: Improving the CO and CH4 Gas Sensor Response at Room Temperature of α-Fe2O3(0001) Epitaxial Thin Films Grown on SrTiO3(111) Incorporating Au(111) Islands
Improving the CO and CH4 Gas Sensor Response at Room Temperature of α-Fe2O3(0001) Epitaxial Thin Films Grown on SrTiO3(111) Incorporating Au(111) Islands Open
In this work epitaxial Au islands have been grown on epitaxial α-Fe2O3 thin film by pulsed laser deposition on SrTiO3(111) substrate. Both Au and α-Fe2O3 layer show an island-type growth with an average particle size of 40 and …
View article: A multi-technique approach to understanding delithiation damage in LiCoO2 thin films
A multi-technique approach to understanding delithiation damage in LiCoO2 thin films Open
View article: Salt Additives for Improving Cyclability of Polymer-Based All-Solid-State Lithium–Sulfur Batteries
Salt Additives for Improving Cyclability of Polymer-Based All-Solid-State Lithium–Sulfur Batteries Open
Lithium–sulfur batteries are attracting extensive attention for energy storage owing to their high theoretical energy density. However, their practical implementation is hindered because of inherent issues of the technology such as the shu…
View article: A multi-technique approach to understanding delithiation damage in LiCoO2 thin films
A multi-technique approach to understanding delithiation damage in LiCoO2 thin films Open
We report on the delithiation of LiCoO2 thin films using oxalic acid (C2H2O4) with the goal of understanding the structural degradation of an insertion oxide associated with Li chemical extraction. Using a multi-technique approach that inc…
View article: Structural damage in LiCoO2 films during chemical delithiation
Structural damage in LiCoO2 films during chemical delithiation Open
The development of suitable Li leaching methods to recover Li in all-solid Lithium-ion batteries (LIBs) is essential for the sustainable mass production of these novel devices. As part of this effort, we investigate here the capacity of th…