Ross McLellan
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View article: Structural Studies of Donor‐Free and Donor‐Solvated Sodium Carboxylates
Structural Studies of Donor‐Free and Donor‐Solvated Sodium Carboxylates Open
Focusing mainly on sodium 2‐ethylhexanoate, this study reveals that the carboxylate exists as a dimer in MeOD solution as evidenced by Diffusion Ordered NMR SpectroscopY (DOSY). Two crystalline varieties with distinct polymeric structures …
View article: Structurally Defined Ring‐Opening and Insertion of Pinacolborane into Aluminium‐Nitrogen Bonds of Sterically Demanding Dialkylaluminium Amides
Structurally Defined Ring‐Opening and Insertion of Pinacolborane into Aluminium‐Nitrogen Bonds of Sterically Demanding Dialkylaluminium Amides Open
Dialkylaluminium amides i Bu 2 Al(TMP) and i Bu 2 Al(HMDS) can perform catalytic hydroboration of ketones with pinacolborane to form the expected boronic esters. However, repeating the same reactions stoichiometrically without a ketone lea…
View article: CCDC 2020851: Experimental Crystal Structure Determination
CCDC 2020851: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2020853: Experimental Crystal Structure Determination
CCDC 2020853: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2020849: Experimental Crystal Structure Determination
CCDC 2020849: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2020852: Experimental Crystal Structure Determination
CCDC 2020852: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2020850: Experimental Crystal Structure Determination
CCDC 2020850: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting Co<sup>II</sup> Complexes through Agostic Interactions
Isomerization Reactions in Anionic Mesoionic Carbene‐Borates and Control of Properties and Reactivities in the Resulting Co<sup>II</sup> Complexes through Agostic Interactions Open
We present herein anionic borate‐based bi‐mesoionic carbene compounds of the 1,2,3‐triazol‐4‐ylidene type that undergo C−N isomerization reactions. The isomerized compounds are excellent ligands for Co II centers. Strong agostic interactio…
View article: Isomerization Reactions in Anionic Mesoionic Carbene-Borates and Control of Properties and Reactivities in the resulting CoII Complexes through Agostic Interactions
Isomerization Reactions in Anionic Mesoionic Carbene-Borates and Control of Properties and Reactivities in the resulting CoII Complexes through Agostic Interactions Open
A unique rearrangement reaction is presented for borate containing mesoionic carbenes. The corresponding CoII complexes display spin states, coordination geeometries and reactivities that are controlled through aogstic interactions on the …
View article: Isomerization Reactions in Anionic Mesoionic Carbene-Borates and Control of Properties and Reactivities in the resulting CoII Complexes through Agostic Interactions
Isomerization Reactions in Anionic Mesoionic Carbene-Borates and Control of Properties and Reactivities in the resulting CoII Complexes through Agostic Interactions Open
A unique rearrangement reaction is presented for borate containing mesoionic carbenes. The corresponding Co II complexes display spin states, coordination geeometries and reactivities that are controlled through aogstic interactions on the…
View article: CCDC 1947189: Experimental Crystal Structure Determination
CCDC 1947189: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1947187: Experimental Crystal Structure Determination
CCDC 1947187: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1947188: Experimental Crystal Structure Determination
CCDC 1947188: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1947186: Experimental Crystal Structure Determination
CCDC 1947186: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A regioselectively 1,1′,3,3′-tetrazincated ferrocene complex displaying core and peripheral reactivity
A regioselectively 1,1′,3,3′-tetrazincated ferrocene complex displaying core and peripheral reactivity Open
A tetrazincated ferrocene complex displays divergent basicity towards aromatic substrates through either its core or peripheral ligands.
View article: Structural and metal–halogen exchange reactivity studies of sodium magnesiate biphenolate complexes
Structural and metal–halogen exchange reactivity studies of sodium magnesiate biphenolate complexes Open
Sodium magnesiates incorporating the (rac)-BIPHEN ligand have been prepared and characterised and subsequently used in metal–halogen exchange reactions.
View article: CCDC 1906538: Experimental Crystal Structure Determination
CCDC 1906538: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1906537: Experimental Crystal Structure Determination
CCDC 1906537: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …