S. Skanthakumar
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View article: Magnetic Properties of Tetravalent Pu in the Perovskites BaPuO<sub>3</sub> and SrPuO<sub>3</sub>
Magnetic Properties of Tetravalent Pu in the Perovskites BaPuO<sub>3</sub> and SrPuO<sub>3</sub> Open
BaPuO3 and SrPuO3 were synthesized, and their structures were refined in the orthorhombic space group Pbnm, a common distortion from the classic Pm3̅m cubic perovskite. Magnetic-susceptibility measurements, obtained as a function of tempera…
View article: CCDC 2168256: Experimental Crystal Structure Determination
CCDC 2168256: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168247: Experimental Crystal Structure Determination
CCDC 2168247: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168251: Experimental Crystal Structure Determination
CCDC 2168251: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168254: Experimental Crystal Structure Determination
CCDC 2168254: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168249: Experimental Crystal Structure Determination
CCDC 2168249: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168245: Experimental Crystal Structure Determination
CCDC 2168245: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168244: Experimental Crystal Structure Determination
CCDC 2168244: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168248: Experimental Crystal Structure Determination
CCDC 2168248: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168253: Experimental Crystal Structure Determination
CCDC 2168253: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168243: Experimental Crystal Structure Determination
CCDC 2168243: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168255: Experimental Crystal Structure Determination
CCDC 2168255: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168257: Experimental Crystal Structure Determination
CCDC 2168257: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168250: Experimental Crystal Structure Determination
CCDC 2168250: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168252: Experimental Crystal Structure Determination
CCDC 2168252: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168246: Experimental Crystal Structure Determination
CCDC 2168246: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis of an Isostructural Series of 12-Coordinate Lanthanide Nitrate Hybrid Double Perovskites with Cubic Symmetry
Synthesis of an Isostructural Series of 12-Coordinate Lanthanide Nitrate Hybrid Double Perovskites with Cubic Symmetry Open
In efforts to study the periodic chemical properties of the rare earth elements and their structural chemistry, a hybrid double perovskite phase A2B'BX6 with the formula ((CH3)4N)2KLn(NO3)6 (Ln = La-Lu, Y ex. Pm) was synthesized that cryst…
View article: CCDC 2168159: Experimental Crystal Structure Determination
CCDC 2168159: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2168158: Experimental Crystal Structure Determination
CCDC 2168158: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Hexanitrato complexes and hybrid double perovskites of Am<sup>3+</sup>and Cm<sup>3+</sup>
Hexanitrato complexes and hybrid double perovskites of Am<sup>3+</sup>and Cm<sup>3+</sup> Open
Isostructural, homoleptic twelve-coordinate nitrato complexes of the 5f-ions Am and Cm are reported that occur as hybrid double perovskites.
View article: Effect of Background Electrolyte Composition on the Interfacial Formation of Th(IV) Nanoparticles on the Muscovite (001) Basal Plane
Effect of Background Electrolyte Composition on the Interfacial Formation of Th(IV) Nanoparticles on the Muscovite (001) Basal Plane Open
Understanding the impact of actinide nanoparticle (NP) formation is important to assess radionuclide mobility in the environment. We combined surface X-ray diffraction (SXRD) and in situ AFM to investigate the previously reported unusual e…
View article: Molecular-scale origins of solution nanostructure and excess thermodynamic properties in a water/amphiphile mixture
Molecular-scale origins of solution nanostructure and excess thermodynamic properties in a water/amphiphile mixture Open
The molecular and nanoscale origins of nonideality in excess thermodynamic properties are essential to understanding cosolvent mixtures, yet they remain challenging to determine.
View article: Leveraging Actinide Hydrolysis Chemistry for Targeted Th and U Separations using Amidoxime‐Functionalized Poly(HIPE)s
Leveraging Actinide Hydrolysis Chemistry for Targeted Th and U Separations using Amidoxime‐Functionalized Poly(HIPE)s Open
P olymerized h igh i nternal p hase e mulsion s (poly(HIPE)s) are porous polymer monoliths whose synthesis can easily be tailored to allow incorporation of functional units. In this work, nitrile containing poly(HIPE)s have been prepared w…
View article: CSD 1857877: Experimental Crystal Structure Determination
CSD 1857877: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: Applications of Alkali Metal Hydroxide Hydrofluxes to the Synthesis of Single‐Crystal Ternary Actinide Oxides
Applications of Alkali Metal Hydroxide Hydrofluxes to the Synthesis of Single‐Crystal Ternary Actinide Oxides Open
Hydrofluxes are hydrated salts with melting points well below that of the dehydrated salt and boiling points well above that of water, affording a reaction medium, in which mild temperatures and pressures can be accessed for the synthesis …
View article: NpSe<sub>2</sub>: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal
NpSe<sub>2</sub>: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal Open
Eine neue binäre Verbindung, NpSe2, enthält Metall-Chalkogen- und Chalkogen-Chalkogen-Wechselwirkungen, die sich von denen anderer Metall-Dichalkogenide unterscheiden. Die Struktur von NpSe2 ist inkommensurabel moduliert und weist lineare …
View article: NpSe<sub>2</sub>: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal
NpSe<sub>2</sub>: a Binary Chalcogenide Containing Modulated Selenide Chains and Ambiguous‐Valent Metal Open
A new binary compound, NpSe2, possesses metal-chalcogen and chalcogen-chalcogen interactions different from those reported for other metal dichalcogenides. Its structure is incommensurately modulated and features linear Se chains and valen…