Samuel Rieder
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View article: Radical Chain Monoalkylation of Pyridines
Radical Chain Monoalkylation of Pyridines Open
The monoalkylation of N-methoxypyridinium salts with alkyl radicals generated from alkenes (via hydroboration with catecholborane), alkyl iodides (via iodine atom transfer) and xanthates is reported. The reaction proceeds under neutral con…
View article: Organoboron Mediated Homolytic Aromatic Substitution of N-Methoxypyridinium Salts
Organoboron Mediated Homolytic Aromatic Substitution of N-Methoxypyridinium Salts Open
The monoalkylation of N-methoxypyridinium salts with alkyl radicals generated from alkenes (via hydroboration with catecholborane), alkyl iodides (via iodine atom transfer) and xanthates is reported. The reaction proceeds under neutral con…
View article: Radical Chain Monoalkylation of Pyridines
Radical Chain Monoalkylation of Pyridines Open
The monoalkylation of N-methoxypyridinium salts with alkyl radicals generated from alkenes (via hydroboration with catecholborane), alkyl iodides (via iodine atom transfer) and xanthates is reported. The reaction proceeds under neutral con…
View article: Radical chain monoalkylation of pyridines
Radical chain monoalkylation of pyridines Open
N -Methoxypyridinium salts are exceptionally reactive radical traps that can be used in efficient radical chain reactions with organoboranes.
View article: Radical chain repair: The hydroalkylation of polysubstituted unactivated alkenes
Radical chain repair: The hydroalkylation of polysubstituted unactivated alkenes Open
A bioinspired repair process allows to expand the synthetic scope of radical reactions.