Sandeepan Maity
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View article: Organic Halogenation using Inorganic Halides and Visible-Light Photocatalyst Perylenediimide
Organic Halogenation using Inorganic Halides and Visible-Light Photocatalyst Perylenediimide Open
Halogenation reactions are fundamental in organic synthesis. While halogenation with fragile N-X (nitrogen-halogen) bonds is well-known in the literature, metal halide salts often require electrolysis. In this study, we unveil a novel and …
View article: Interplay of Solvent Polarity and Hydrogen Bonding in Thermal Isomerization of Spiropyran
Interplay of Solvent Polarity and Hydrogen Bonding in Thermal Isomerization of Spiropyran Open
View article: Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening
Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening Open
Highly reducing Sm(II) reductants and protic ligands were used as a platform to ascertain the relationship between low-valent metal-protic ligand affinity and degree of ligand X-H bond weakening with the goal of forming potent proton-coupl…
View article: Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening
Accessing Unusual Reactivity through Chelation-Promoted Bond Weakening Open
Highly reducing Sm(II) reductants and protic ligands were used as a platform to ascertain the relationship between low-valent metal-protic ligand affinity and degree of ligand X-H bond weakening with the goal of forming potent PCET reducta…
View article: Mechanistic Study and Development of Catalytic Reactions of Sm(II)
Mechanistic Study and Development of Catalytic Reactions of Sm(II) Open
Samarium diiodide (SmI2) is one of the most widely used single-electron reductants available to organic chemists because it is effective in reducing and coupling a wide range of functional groups. Despite the broad utility and a…
View article: Mechanistic Study and Development of Catalytic Reactions of Sm(II)
Mechanistic Study and Development of Catalytic Reactions of Sm(II) Open
Despite the broad utility and application of SmI2in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight, resulting in a large amount of material being used for reactions requiring one or more…
View article: Mechanistic Study and Development of Catalytic Reactions of Sm(II)
Mechanistic Study and Development of Catalytic Reactions of Sm(II) Open
Despite the broad utility and application of SmI 2 in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight, resulting in a large amount of material being used for reactions requiring one or more equivale…