Sebastian Henke
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View article: Luminescent chiral molecular glasses by melt-quenching enantiopure BINAP
Luminescent chiral molecular glasses by melt-quenching enantiopure BINAP Open
Chiral organic glasses combine unique optical properties with processing advantages of amorphous solids. Here, we demonstrate melt-quenching as a strategy for preparing optically active glasses from enantiopure BINAP (2,2’-bis(diphenylphos…
View article: Isoreticular Expansion in Porous Al(III) and Ga(III) Phosphonates: Synthesis, Structure, and Properties
Isoreticular Expansion in Porous Al(III) and Ga(III) Phosphonates: Synthesis, Structure, and Properties Open
We report the synthesis and structural elucidation of two metal-organic frameworks (MOFs), [M(OH)(H₂BPD)]·xH₂O (M = Al³⁺, Ga³⁺), denoted as M-CAU-67, synthesized using the ditopic linker molecule N, N’ 4,4’ bipiperidine bis(methylenephosph…
View article: Understanding the High-Pressure Behavior of MOF-74-Type Materials: The Influence of Metal Identity and Linker Extension
Understanding the High-Pressure Behavior of MOF-74-Type Materials: The Influence of Metal Identity and Linker Extension Open
MOF-74 (M2(dobdc); dobdc4– = 2,5-dioxido-1,4-benzenedicarboxylate) and its isoreticular derivatives represent a chemically versatile class of metal-organic frameworks (MOFs) with high densities of open metal sites and one-dimensional chann…
View article: Organic flux-mediated ligand exchange enables coordination sphere engineering and topological restructuring in metal-organic framework glasses
Organic flux-mediated ligand exchange enables coordination sphere engineering and topological restructuring in metal-organic framework glasses Open
Melt-quenched glasses derived from metal-organic frameworks (MOFs) combine the processability of glasses with the modularity and microporosity of MOFs, yet remain structurally and functionally less diverse than their crystalline analogues.…
View article: Emergent Spin-Glass Behavior in an Iron(II)-based Metal-Organic Framework Glass
Emergent Spin-Glass Behavior in an Iron(II)-based Metal-Organic Framework Glass Open
Metal-organic framework (MOF) glasses combine the structural tunability of crystalline MOFs with the processability of amorphous materials, offering exciting opportunities for functional hybrid materials. Here, we report a one-pot, solvent…
View article: Engineering a Meltable MOF to Tune Liquid Transition and Promote Coenzyme Regeneration
Engineering a Meltable MOF to Tune Liquid Transition and Promote Coenzyme Regeneration Open
Modulating the liquid phase of metal–organic frameworks (MOFs) presents new opportunities for functionalizing glassy MOFs, expanding the fundamental science and practical application for this emerging family of materials. Herein, we report…
View article: Mechanochemical Synthesis Enables Melting, Glass Formation and Glass-Ceramic Conversion in a Cadmium-based Zeolitic Imidazolate Framework
Mechanochemical Synthesis Enables Melting, Glass Formation and Glass-Ceramic Conversion in a Cadmium-based Zeolitic Imidazolate Framework Open
Metal-organic frameworks (MOFs) are versatile materials with tunable properties and broad applications. Here, we report the first cadmium-based zeolitic imidazolate framework (ZIF) glass, prepared by melt-quenching sub-micrometer-sized Cd(…
View article: Mechanochemical Crystal Downsizing Enables Melting, Glass Formation and Glass-Ceramic Conversion in a Cadmium-based Zeolitic Imidazolate Framework
Mechanochemical Crystal Downsizing Enables Melting, Glass Formation and Glass-Ceramic Conversion in a Cadmium-based Zeolitic Imidazolate Framework Open
Metal-organic frameworks (MOFs) are versatile materials with tunable properties and broad applications. Here, we report the first cadmium‐based zeolitic imidazolate framework (ZIF) glass, prepared by melt-quenching sub-micrometer-sized Cd(…
View article: Sodium-Ion-Modified Zeolitic Imidazolate Framework Glasses
Sodium-Ion-Modified Zeolitic Imidazolate Framework Glasses Open
Modifying glass compositions is key to creating silicate-based glasses for technologies like optical fibres, catalytic supports, protective coatings, and separation membranes. Here, we extend this concept to metal-organic framework (MOF) g…
View article: Emergent Magnetic Ordering in Iron(II)-based Metal-Organic Framework Glasses
Emergent Magnetic Ordering in Iron(II)-based Metal-Organic Framework Glasses Open
Metal-organic framework (MOF) glasses combine the structural tunability of crystalline MOFs with the processability of amorphous materials, offering exciting opportunities for functional hybrid materials. We report a one-pot, solvent-free …
View article: Xenon adsorption-induced flexibility of the zeolitic imidazolate framework ZIF-4 observed by <i>in situ</i> <sup>129</sup> Xe NMR spectroscopy
Xenon adsorption-induced flexibility of the zeolitic imidazolate framework ZIF-4 observed by <i>in situ</i> <sup>129</sup> Xe NMR spectroscopy Open
An unexpected reversible xenon-induced structural transition is found in ZIF-4 by in situ 129 Xe NMR spectroscopy.
View article: Pore Structure Modulation in Kirigamic Zeolitic Imidazolate Framework
Pore Structure Modulation in Kirigamic Zeolitic Imidazolate Framework Open
Paper crafts, such as origami and kirigami, have become an interdisciplinary research theme transportable from art to science, and further to engineering. Kirigami‐inspired architectural design strategies allow the establishment of three‐d…
View article: Pore Structure Modulation in Kirigamic Zeolitic Imidazolate Framework
Pore Structure Modulation in Kirigamic Zeolitic Imidazolate Framework Open
Paper crafts, such as origami and kirigami, have become an interdisciplinary research theme transportable from art to science, and further to engineering. Kirigami‐inspired architectural design strategies allow the establishment of three‐d…
View article: Lithium and Sodium Benzimidazolate Coordination Networks: Syntheses, Structures and Thermal Properties
Lithium and Sodium Benzimidazolate Coordination Networks: Syntheses, Structures and Thermal Properties Open
Alkali metal imidazolates are important compounds, serving as intermediates in organic synthesis and additives in alkali ion electrolytes. However, their solid-state structures and thermal behaviors remain largely unexplored. In this study…
View article: Insights Into the Mechanochemical Glass Formation of Zeolitic Imidazolate Frameworks
Insights Into the Mechanochemical Glass Formation of Zeolitic Imidazolate Frameworks Open
Metal–organic framework (MOF) glasses, known for their potential in gas separation, optics, and solid‐state electrolytes, benefit from the processability of their (supercooled) liquid state. Traditionally, MOF glasses are produced by heati…
View article: Pore Structure Modulation in Kirigamic Zeolitic Imidazolate Framework
Pore Structure Modulation in Kirigamic Zeolitic Imidazolate Framework Open
Paper crafts, such as origami and kirigami, have become an interdisciplinary research theme transportable from art to science, and further to engineering. Kirigami-inspired architectural design strategies allow the establishment of three-d…
View article: Insights into the Mechanochemical Glass Formation of Zeolitic Imidazolate Frameworks
Insights into the Mechanochemical Glass Formation of Zeolitic Imidazolate Frameworks Open
Metal-organic framework (MOF) glasses, known for their potential in gas separation, optics, and solid-state electrolytes, benefit from the processability of their (supercooled) liquid state. Traditionally, MOF glasses are produced by heati…
View article: Unlocking Diabetic Acetone Vapor Detection by A Portable Metal‐Organic Framework‐Based Turn‐On Optical Sensor Device
Unlocking Diabetic Acetone Vapor Detection by A Portable Metal‐Organic Framework‐Based Turn‐On Optical Sensor Device Open
Despite exhaled human breath having enabled noninvasive diabetes diagnosis, selective acetone vapor detection by fluorescence approach in the diabetic range (1.8–3.5 ppm) remains a long‐standing challenge. A set of water‐resistant luminesc…
View article: CCDC 2211193: Experimental Crystal Structure Determination
CCDC 2211193: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236677: Experimental Crystal Structure Determination
CCDC 2236677: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Highly porous metal-organic framework liquids and glasses via a solvent-assisted linker exchange strategy of ZIF-8
Highly porous metal-organic framework liquids and glasses via a solvent-assisted linker exchange strategy of ZIF-8 Open
By combining the porosity of crystalline metal-organic frameworks (MOFs) with the unique processability of the liquid state, melt-quenched MOF glasses offer exciting opportunities for molecular separation. However, progress in this field i…
View article: Unlocking diabetic acetone vapor detection by a portable metal-organic framework-based optical sensor device
Unlocking diabetic acetone vapor detection by a portable metal-organic framework-based optical sensor device Open
Despite exhaled human breath having enabled noninvasive diabetes diagnosis, selective acetone vapor detection by fluorescence approach in the diabetic range (1.8-3.5 ppm) remains a long-standing challenge. We report a set of water-resistan…
View article: CCDC 2220445: Experimental Crystal Structure Determination
CCDC 2220445: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2220446: Experimental Crystal Structure Determination
CCDC 2220446: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2220441: Experimental Crystal Structure Determination
CCDC 2220441: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2220442: Experimental Crystal Structure Determination
CCDC 2220442: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …