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View article: New Thermoplastic Elastomers based on Ethylene‐Butadiene‐Rubber (EBR) by Switching from Anionic to Coordinative Chain Transfer Polymerization
New Thermoplastic Elastomers based on Ethylene‐Butadiene‐Rubber (EBR) by Switching from Anionic to Coordinative Chain Transfer Polymerization Open
Olefin triblock copolymers based on glassy polystyrene (PS), ethylene butadiene rubber (EBR) and highly crystalline polyethylene (PE) segments were prepared for the first time using a switch strategy from anionic polymerization to coordina…
View article: Multiblock Copolymers Based on Highly Crystalline Polyethylene and Soft Poly(ethylene‐<i>co</i>‐butadiene) Segments: Towards Polyolefin Thermoplastic Elastomers
Multiblock Copolymers Based on Highly Crystalline Polyethylene and Soft Poly(ethylene‐<i>co</i>‐butadiene) Segments: Towards Polyolefin Thermoplastic Elastomers Open
Block copolymers based on polyethylene (PE) and ethylene butadiene rubber (EBR) were obtained by successive controlled coordinative chain transfer polymerization (CCTP) of a mixture of ethylene and butadiene (80/20) and pure ethylene. EBR‐…
View article: Microscopic versus Macroscopic Glass Transitions and Relevant Length Scales in Mixtures of Industrial Interest
Microscopic versus Macroscopic Glass Transitions and Relevant Length Scales in Mixtures of Industrial Interest Open
We have combined X-ray diffraction, neutron diffraction with polarization analysis, small-angle neutron scattering (SANS), neutron elastic fixed window scans (EFWS), and differential scanning calorimetry (DSC) to investigate polymeric blen…
View article: Disentangling the Calorimetric Glass-Transition Trace in Polymer/Oligomer Mixtures from the Modeling of Dielectric Relaxation and the Input of Small-Angle Neutron Scattering
Disentangling the Calorimetric Glass-Transition Trace in Polymer/Oligomer Mixtures from the Modeling of Dielectric Relaxation and the Input of Small-Angle Neutron Scattering Open
We have disentangled the contributions to the glass transition as observed by differential scanning calorimetry (DSC) on simplified systems of industrial interest consisting of blends of styrene-butadiene rubber (SBR) and polystyrene (PS) …
View article: Microscopic versus Macroscopic Glass Transition(s) in Blends of Industrial Interest
Microscopic versus Macroscopic Glass Transition(s) in Blends of Industrial Interest Open
We investigate by neutron scattering and calorimetry a mixture of styrene-butadiene rubber (SBR) and a commercial resin. The neat materials present a large dynamic contrast, having SBR a much lower glass-transition temperature than the res…
View article: Combined dielectric spectroscopy and neutron scattering study of a polymer blend as a simplified industrial system
Combined dielectric spectroscopy and neutron scattering study of a polymer blend as a simplified industrial system Open
Resumen del trabajo presentado a la 10th Conference on Broadband Dielectric Spectroscopy and its Applications (BDS) celebrada en Bruselas (Belgica) del 26 al 31 de agosto de 2018.