Shang‐Dong Yang
YOU?
Author Swipe
View article: Pd-Catalyzed Direct Diarylation of Sodium Hypophosphite Enables the Synthesis of Diarylphosphonates
Pd-Catalyzed Direct Diarylation of Sodium Hypophosphite Enables the Synthesis of Diarylphosphonates Open
A facile and efficient method for synthesizing diarylphosphinates from alcohols and aryl halides, using stable, green, and readily available sodium hypophosphite as a phosphorus source, is disclosed herein for the first time. This method o…
View article: CCDC 2130450: Experimental Crystal Structure Determination
CCDC 2130450: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters
Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence to access phosphoric esters Open
Herein, we report a Lewis acid-catalyzed Pudovik reaction–phospha-Brook rearrangement sequence between diarylphosphonates or -phosphinates and α-pyridinealdehydes to access valuable phosphoric ester compounds. This transformation provides …
View article: CCDC 1959970: Experimental Crystal Structure Determination
CCDC 1959970: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2043003: Experimental Crystal Structure Determination
CCDC 2043003: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2043002: Experimental Crystal Structure Determination
CCDC 2043002: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: The sequential C–H oxidation/asymmetric phosphonylation of primary alcohols to synthesize α-hydroxy phosphonates
The sequential C–H oxidation/asymmetric phosphonylation of primary alcohols to synthesize α-hydroxy phosphonates Open
A new strategy for the sequential C–H oxidation/asymmetric phosphonylation of primary alcohols has been developed. It involves a combination of Cu(I)/TEMPO/NMI (N-methylimidazole) oxidation, under an air atmosphere, with chiral Al (salalen…
View article: New Staudinger Strategy Enabled <i>N</i> -Acyl Phosphinamidites Synthesis
New Staudinger Strategy Enabled <i>N</i> -Acyl Phosphinamidites Synthesis Open
A new Staudinger strategy entails a unique C-P bond cleavage, instead of N-P bond cleavage, during the construction of N-acyl phosphinamidites by using acyl-phosphine substrates. The reaction is performed under very mild conditions, with n…
View article: Recent advances in radical phosphorylation
Recent advances in radical phosphorylation Open
Chemical Synthesis is an open access peer-reviewed journal publishing original research involving all areas of the chemical sciences. The journal aims to be the premier resource of seminal and insightful research and showcases for research…
View article: CCDC 2042999: Experimental Crystal Structure Determination
CCDC 2042999: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2043000: Experimental Crystal Structure Determination
CCDC 2043000: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2042997: Experimental Crystal Structure Determination
CCDC 2042997: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Applications of transition metal catalyzed <i>P</i>-radical for synthesis of organophosphorus compounds
Applications of transition metal catalyzed <i>P</i>-radical for synthesis of organophosphorus compounds Open
Phosphorus-radical participated difunctionalization reactions with unsaturated compounds have been recognized as powerful method for organic synthesis. This review covers our recent work on the application of transition metal catalyzed P -…
View article: CCDC 1839679: Experimental Crystal Structure Determination
CCDC 1839679: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Cover Picture: Silver‐Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides (Chin. J. Chem. 3/2017)
Cover Picture: Silver‐Catalyzed Cascade Radical Cyclization for Stereoselective Synthesis of Exocyclic Phosphine Oxides (Chin. J. Chem. 3/2017) Open
The cover picture shows a concise and effective protocol for the synthesis of valuable exocyclic phosphine oxides via the process of free radical cascade cyclization. Waterwheel in series shows the implied meaning in the process of phospho…
View article: CCDC 1449751: Experimental Crystal Structure Determination
CCDC 1449751: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1444038: Experimental Crystal Structure Determination
CCDC 1444038: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Back Cover: Asymmetric Suzuki–Miyaura Cross‐Coupling for the Synthesis of Chiral Biaryl Compounds as Potential Monophosphine Ligands (Chem. Eur. J. 18/2015)
Back Cover: Asymmetric Suzuki–Miyaura Cross‐Coupling for the Synthesis of Chiral Biaryl Compounds as Potential Monophosphine Ligands (Chem. Eur. J. 18/2015) Open
Asymmetric Suzuki–Miyaura couplings between chiral phosphine substrates and aryl bromides are used to efficiently synthesize biaryl compounds with phosphinate groups as chiral auxiliaries in excellent yields and diastereoselectivities, as …
View article: CCDC 1045456: Experimental Crystal Structure Determination
CCDC 1045456: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Silver-Catalyzed Tandem Radical Cyclization for the Synthesis of 3,3'-Disubstituted Oxindoles
Silver-Catalyzed Tandem Radical Cyclization for the Synthesis of 3,3'-Disubstituted Oxindoles Open
A new silver-catalyzed oxidative ring opening of cyclopropanols to functionalize alkenes of N-arylacrylamides leading to 3,3'-disubstituted oxindoles has been developed. This reaction is proposed to proceed through oxidative radical ring-o…
View article: Copper(I) Bromide-Catalyzed for the Synthesis of Sulfoxonium Ylides
Copper(I) Bromide-Catalyzed for the Synthesis of Sulfoxonium Ylides Open
A simple and efficient method for the synthesis of substituted sulfoxonium ylides from diazocompounds in dimethyl sulfoxide was developed. It is notable that the reaction employs cheap and harmless copper(I) bromide as catalyst. Moreover, …