Shigeki Mori
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View article: μ‐Oxo Dimers of Silicon Porphyrazines and Their Interlayer Interactions
μ‐Oxo Dimers of Silicon Porphyrazines and Their Interlayer Interactions Open
μ‐Oxo dimers of octaaryl‐substituted silicon porphyrazines (SiPzs) were synthesized for the first time. The steric congestion due to the peripheral aryl groups attenuated the rotation of the SiPz units around the Si–O–Si axis, resulting in…
View article: Boi‐Ogi‐To, a Traditional Japanese Kampo Medicine, Promotes Cellular Excretion of Chloride and Water by Activating Volume‐Sensitive Outwardly Rectifying Anion Channels
Boi‐Ogi‐To, a Traditional Japanese Kampo Medicine, Promotes Cellular Excretion of Chloride and Water by Activating Volume‐Sensitive Outwardly Rectifying Anion Channels Open
The Japanese Kampo medicine Boi‐ogi‐to (BOT) is known as an effective therapeutic agent for edema and nephrosis by promoting the excretion of excess body fluids. Despite its empirical effectiveness, scientific evidence supporting its effec…
View article: Synthesis of [34]Octaphyrin(1.0.1.0.1.0.1.0)
Synthesis of [34]Octaphyrin(1.0.1.0.1.0.1.0) Open
Ring‐expanded porphyrins are attracted because of their absorptions in the near‐infrared (NIR) region, redox behavior, and aromaticity. We have succeeded in the synthesis of planar ring‐expanded porphyrins starting from rigidified β,β’‐con…
View article: AzUlene‐Fused Polycyclic Aromatic Hydrocarbons: Synthesis, Structural, Optical, and Electrochemical Properties of Azuleno[2,1‐a]phenalenones
AzUlene‐Fused Polycyclic Aromatic Hydrocarbons: Synthesis, Structural, Optical, and Electrochemical Properties of Azuleno[2,1‐a]phenalenones Open
The preparation of 2‐arylazulenes possessing 1‐naphthyl substructure is achieved via Suzuki–Miyaura coupling with various arylboronic acids. Intramolecular cyclization using Brønsted acids is examined, yielding azulene‐fused polycyclic aro…
View article: Synthesis and Fluorescence Properties of Oxazolo[5,4‐<i>b</i>]quinolines: Exploring Structure‐Property Relationships and Design Strategies for Tailored Photophysical Characteristics
Synthesis and Fluorescence Properties of Oxazolo[5,4‐<i>b</i>]quinolines: Exploring Structure‐Property Relationships and Design Strategies for Tailored Photophysical Characteristics Open
A series of oxazolo[5,4‐ b ]quinoline derivatives were synthesized via a two‐step process involving the reaction of 4‐trifluoroacetylazlactones with various substituted anilines, followed by intramolecular Friedel‐Crafts‐type cyclization a…
View article: Development of a bio-based adhesive by polymerization of Boc-protected vinyl catechol derived from caffeic acid
Development of a bio-based adhesive by polymerization of Boc-protected vinyl catechol derived from caffeic acid Open
Catechol polymers enabled the preparation of a biomimetic adhesive using a bio-based raw material, in which the deprotection proceeded just upon heating with neither any solvent nor catalyst, releasing only gaseous byproducts without purif…
View article: Metal‐Bridging Cyclic Bilatriene Analogue Affords Stable π‐Radicaloid Dyes with Near‐Infrared II Absorption
Metal‐Bridging Cyclic Bilatriene Analogue Affords Stable π‐Radicaloid Dyes with Near‐Infrared II Absorption Open
Stable neutral metal radicaloid complexes have been synthesized from a modified tetrapyrrolic pigment, bilatriene, with iridium(I) and rhodium(I) cyclooctadiene (COD) synthons. The bilatriene skeleton contains α‐linked conjugated pyrrole u…
View article: Synthesis and Properties of 5,15‐Dioxaporphyrin Bearing Various <i>meso</i>‐Aryl Substituents
Synthesis and Properties of 5,15‐Dioxaporphyrin Bearing Various <i>meso</i>‐Aryl Substituents Open
Herein, a scope of meso ‐substituents for the synthesis of 5,15‐dioxaporphyrins (DOPs), a novel antiaromatic porphyrinoid, was investigated. DOPs with various types of aryl substituents were synthesized by nucleophilic aromatic substitutio…
View article: Effect of reinforcing plates on tensile shear strength test of adhesive bonded aluminum alloys
Effect of reinforcing plates on tensile shear strength test of adhesive bonded aluminum alloys Open
View article: Effect of surface treatments on the adhesion durability of aluminum alloys in warm water environment
Effect of surface treatments on the adhesion durability of aluminum alloys in warm water environment Open
View article: Metalla‐Carbaporphyrinoids Consisting of an Acyclic N‐Confused Tetrapyrrole Analogue Served as Stable Near‐Infrared‐II Dyes
Metalla‐Carbaporphyrinoids Consisting of an Acyclic N‐Confused Tetrapyrrole Analogue Served as Stable Near‐Infrared‐II Dyes Open
We present herein the synthesis of novel pseudo ‐metalla‐carbaporphyrinoid species ( 1M : M=Pd and Pt) achieved through the inner coordination of palladium(II) and platinum(II) with an acyclic N‐confused tetrapyrrin analogue. Despite their…
View article: Metalla‐Carbaporphyrinoids Consisting of an Acyclic N‐Confused Tetrapyrrole Analogue Served as Stable Near‐Infrared‐II Dyes
Metalla‐Carbaporphyrinoids Consisting of an Acyclic N‐Confused Tetrapyrrole Analogue Served as Stable Near‐Infrared‐II Dyes Open
We present herein the synthesis of novel pseudo ‐metalla‐carbaporphyrinoid species ( 1M : M=Pd and Pt) achieved through the inner coordination of palladium(II) and platinum(II) with an acyclic N‐confused tetrapyrrin analogue. Despite their…
View article: Synthesis of 10<i>H</i>-di(1-benzothiopheno)[2,3-<i>b</i>:3′,2′-<i>d</i>]pyrrole: re-investigation of the Cadogan cyclization route
Synthesis of 10<i>H</i>-di(1-benzothiopheno)[2,3-<i>b</i>:3′,2′-<i>d</i>]pyrrole: re-investigation of the Cadogan cyclization route Open
The reaction of 2-nitro-3,3′-bi(1-benzothiophene) bearing ester groups at 7- and 7′-positions under the Cadogan cyclization conditions (PPh3, o-C6H4Cl2, refl.) afforded the targeted 10H-di(1-benzothiopheno)[2,3-b:3′,2′-d]pyrrole-1,8-dicarb…
View article: Molecular Design for Stable Near-Infrared-II Two-Photon Excitation-Induced Photoacoustic Contrast Agents Based on Donor-Substituted BODIPYs
Molecular Design for Stable Near-Infrared-II Two-Photon Excitation-Induced Photoacoustic Contrast Agents Based on Donor-Substituted BODIPYs Open
We present the synthesis of donor–acceptor-type bis(triisopropylsilyl-ethynyl)-substituted boron-dipyrromethene (BODIPY) derivatives (2 and 5) with the capability for concerted two-photon (TP) excitation-induced photoacoustic (PA) imaging …
View article: CCDC 1959812: Experimental Crystal Structure Determination
CCDC 1959812: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1959814: Experimental Crystal Structure Determination
CCDC 1959814: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2297127: Experimental Crystal Structure Determination
CCDC 2297127: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2296859: Experimental Crystal Structure Determination
CCDC 2296859: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2296819: Experimental Crystal Structure Determination
CCDC 2296819: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2296873: Experimental Crystal Structure Determination
CCDC 2296873: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2296868: Experimental Crystal Structure Determination
CCDC 2296868: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Cover Picture: Synthesis of 2‐Perfluoroalkylazuleno[2,1‐<i>d</i>]pyrimidin‐4(3<i>H</i>)‐ones via Brønsted Acid‐Mediated Intramolecular Cyclization and Transformation into Pyrimidines (Adv. Synth. Catal. 21/2023)
Cover Picture: Synthesis of 2‐Perfluoroalkylazuleno[2,1‐<i>d</i>]pyrimidin‐4(3<i>H</i>)‐ones via Brønsted Acid‐Mediated Intramolecular Cyclization and Transformation into Pyrimidines (Adv. Synth. Catal. 21/2023) Open
The inside cover picture illustrates the stepwise transformation of 1-cyano-2-aminoazulenes to azuleno[2,1-d]pyrimidine derivatives via azuleno[2,1-d]pyrimidin-4(3H)-ones. In this study, we described a new strategy for the azuleno[2,1-d]py…
View article: CCDC 2207142: Experimental Crystal Structure Determination
CCDC 2207142: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2207141: Experimental Crystal Structure Determination
CCDC 2207141: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2207143: Experimental Crystal Structure Determination
CCDC 2207143: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262492: Experimental Crystal Structure Determination
CCDC 2262492: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262487: Experimental Crystal Structure Determination
CCDC 2262487: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262494: Experimental Crystal Structure Determination
CCDC 2262494: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262488: Experimental Crystal Structure Determination
CCDC 2262488: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262493: Experimental Crystal Structure Determination
CCDC 2262493: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …