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View article: Photoionization Mass Spectrometry Unveils Siloxane Sequence Isomers: Advancing Molecular Tagging Applications
Photoionization Mass Spectrometry Unveils Siloxane Sequence Isomers: Advancing Molecular Tagging Applications Open
Sequence‐defined polymers, which encode information through their monomer sequence, are promising candidates for molecular tagging. However, conventional sequence‐defined polymers often degrade in harsh conditions, limiting their practical…
View article: Alkali-cation-free electrochemical CO<sub>2</sub> reduction to multicarbon products in aqueous electrolytes containing tetraalkylammonium cations
Alkali-cation-free electrochemical CO<sub>2</sub> reduction to multicarbon products in aqueous electrolytes containing tetraalkylammonium cations Open
We achieved CO 2 electroreduction to C 2+ products ( j C 2+ = 0.7 A cm −2 ) in aqueous electrolytes containing tetramethylammonium cations without alkali metals. Smaller cations enhance the electric field in the double layer, promoting C 2…
View article: Quantitative Analysis and Manipulation of Alkali Metal Cations at the Cathode Surface in Membrane Electrode Assembly Electrolyzers for CO <sub>2</sub> Reduction Reactions
Quantitative Analysis and Manipulation of Alkali Metal Cations at the Cathode Surface in Membrane Electrode Assembly Electrolyzers for CO <sub>2</sub> Reduction Reactions Open
The stable operation of the CO 2 reduction reaction (CO 2 RR) in membrane electrode assembly (MEA) electrolyzers is known to be hindered by the accumulation of bicarbonate salt, which are derived from alkali metal cations in anolytes, on t…
View article: Suppression of Salt Precipitation in Membrane Electrode Assembly Electrolyzers for CO2 reduction reactions by Intermittent Supply of Alkali Metal Cations
Suppression of Salt Precipitation in Membrane Electrode Assembly Electrolyzers for CO2 reduction reactions by Intermittent Supply of Alkali Metal Cations Open
The electrolysis of CO2 into value-added products holds great potential for closing the carbon cycle. A membrane electrode assembly (MEA) that uses solid polymer electrolytes is a critical technology for enhancing the energy efficiency for…
View article: Visible-Light-Photomeltable Azobenzenes as Solar Thermal Fuels
Visible-Light-Photomeltable Azobenzenes as Solar Thermal Fuels Open
Photomelting of azobenzene is a phenomenon that is typically achieved by UV-light irradiation. However, many applications based on azobenzene photomelting, including the solar thermal fuel (STF) application, require responsiveness to visib…
View article: CCDC 2191231: Experimental Crystal Structure Determination
CCDC 2191231: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191233: Experimental Crystal Structure Determination
CCDC 2191233: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2191232: Experimental Crystal Structure Determination
CCDC 2191232: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Azobenzene‐Containing Triblock Copolymer Adhesive Based on Light‐Induced Solid–Liquid Phase Transition: Application to Bonding for Various Substrates
Azobenzene‐Containing Triblock Copolymer Adhesive Based on Light‐Induced Solid–Liquid Phase Transition: Application to Bonding for Various Substrates Open
Front Cover: In the article number 1900105, Haruhisa Akiyama, Hideyuki Kihara, and co-workers demonstrate the repeatable bonding/debonding of various substrates such as plastics and metals by using photoresponsive adhesive tapes consisting…
View article: Structural and functional characterization of a bifunctional GH30-7 xylanase B from the filamentous fungus Talaromyces cellulolyticus
Structural and functional characterization of a bifunctional GH30-7 xylanase B from the filamentous fungus Talaromyces cellulolyticus Open
Glucuronoxylanases are endo-xylanases and members of the glycoside hydrolase family 30 subfamilies 7 (GH30-7) and 8 (GH30-8). Unlike for the well-studied GH30-8 enzymes, the structural and functional characteristics of GH30-7 enzymes remai…
View article: Isolation of <i>Streptococcus dysgalactiae</i> from farmed striped jack <i>Pseudocaranx dentex</i>
Isolation of <i>Streptococcus dysgalactiae</i> from farmed striped jack <i>Pseudocaranx dentex</i> Open
2015年夏季に養殖シマアジ病魚からランスフィールドC群Streptococcus dysgalactiae（GCSD）が宮崎県内で初めて分離された。シマアジから分離されたGCSDはカンパチやブリから分離されたGCSDと同様の生化学的性状を示し，GCSD同定用のPCRにおいても陽性であった。また，攻撃実験により，シマアジ由来GCSD株のシマアジに対する病原性が確認された。本報はシマアジにおけるGCSD感染症国内症例の初報告である。
View article: Precise Synthesis of Macromolecular Architectures by Novel Iterative Methodology Combining Living Anionic Polymerization with Specially Designed Linking Chemistry
Precise Synthesis of Macromolecular Architectures by Novel Iterative Methodology Combining Living Anionic Polymerization with Specially Designed Linking Chemistry Open
This article reviews the development of a novel all-around iterative methodology combining living anionic polymerization with specially designed linking chemistry for macromolecular architecture syntheses. The methodology is designed in su…
View article: Facile synthesis of multiarmed and multicomponent star polymers by a new iterative methodology using (formyl-protected 1,3-dioxolane)-end-functionalized polymer anions
Facile synthesis of multiarmed and multicomponent star polymers by a new iterative methodology using (formyl-protected 1,3-dioxolane)-end-functionalized polymer anions Open
In this manuscript, we have developed a new and efficient iterative methodology using formyl-protected 1,3-dioxolane-end-functionalized polymer anions for the facile synthesis of multiarmed and multicomponent miktoarm star polymers.
View article: Macromol. Chem. Phys. 14/2015
Macromol. Chem. Phys. 14/2015 Open
Front Cover: Multi-armed and multi-component star polymers are successfully synthesized by development of a new iterative methodology using block copolymer in-chain anions, whose anions are positioned between the blocks. A series of 3-arm …