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View article: Advancing Bidirectional Photoswitching of Norbornadienes: Exclusively Light‐Induced Interconversion of <i>Imide</i> ‐ and <i>Ortho</i> ‐Connected Norbornadiene‐Perylene Diimide Hybrids
Advancing Bidirectional Photoswitching of Norbornadienes: Exclusively Light‐Induced Interconversion of <i>Imide</i> ‐ and <i>Ortho</i> ‐Connected Norbornadiene‐Perylene Diimide Hybrids Open
The norbornadiene/quadricyclane (NBD/QC) photoswitch is a promising candidate for molecular solar energy storage. Isomerization to the energy‐storing, metastable QC occurs upon UV light irradiation, while the back‐switching can be triggere…
View article: Driving the quadricyclane-to-norbornadiene isomerization by charge separation with perylenediimide as electron acceptor
Driving the quadricyclane-to-norbornadiene isomerization by charge separation with perylenediimide as electron acceptor Open
The complementary use of time-resolved and steady-state spectroscopies has made it possible to describe the full reaction coordinate regarding the photoisomerization of NBDs featuring electron accepting PDIs.