Stefania Baronio
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View article: Local Geometry, Structure and Electronic Resonances Enhancing the SFG Signal from CO on Ir Surfaces
Local Geometry, Structure and Electronic Resonances Enhancing the SFG Signal from CO on Ir Surfaces Open
Sum frequency generation (SFG) spectroscopy was used to study CO adsorption on smooth and rough Ir(111) single crystal surfaces, the cleanliness, composition, order and morphology of which were comprehensively characterized by Auger electr…
View article: Thermally Activated on‐Surface Self‐Metalation of Pd‐Phthalocyanines
Thermally Activated on‐Surface Self‐Metalation of Pd‐Phthalocyanines Open
Phthalocyanines (Pcs) are essential organic molecules with wide‐ranging applications in fields such as catalysis and optoelectronics, owing to their stable aromatic structure and exceptional thermal stability. Equally important is their ve…
View article: Single atom coordination in a manganese–cobalt bi-metallic framework on graphene: geometric and electronic structures
Single atom coordination in a manganese–cobalt bi-metallic framework on graphene: geometric and electronic structures Open
Geometric structure and oxidation states can be tuned upon tetra-coordination of single Mn and Co metal atoms within a porphyrin-based network on graphene.
View article: Seeking borophene on Ni<sub>3</sub>Al(111): an experimental characterization of boron segregation and oxidation
Seeking borophene on Ni<sub>3</sub>Al(111): an experimental characterization of boron segregation and oxidation Open
Synthesis of a stable, well ordered honeycomb borophene (hB) phase has been achieved to date by exploiting Al(111) as a growth substrate, which provides the necessary charge doping to compensate the high hexagonal-holes density. However, B…
View article: Stabilization <i>versus</i> competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface
Stabilization <i>versus</i> competing de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface Open
Competition with de-metalation, trans-metalation and (cyclo)-dehydrogenation of Pd porphyrins at a copper surface can be tuned by means of an oxygen decoupling layer, which stabilizes the pristine PdTPP species.
View article: Single Metal Atom Catalysts and ORR: H-Bonding, Solvation, and the Elusive Hydroperoxyl Intermediate
Single Metal Atom Catalysts and ORR: H-Bonding, Solvation, and the Elusive Hydroperoxyl Intermediate Open
The widely investigated oxygen reduction reaction (ORR) is well-known to proceed via two competing routes, involving two or four electrons, and yielding different reaction products, respectively. Both pathways are believed to share a commo…
View article: Vibrational Fine Structure in C 1s High-Resolution Core-Level Spectra of CO Chemisorbed on Ir(111)
Vibrational Fine Structure in C 1s High-Resolution Core-Level Spectra of CO Chemisorbed on Ir(111) Open
The vibrational features of carbon monoxide (CO) adsorbed on Ir(111) were studied by means of high-resolution core-level spectroscopy. By monitoring the Ir 4f7/2 core level as a function of exposure, we proved that the CO adsorbs on the su…