Peter S. Schulz
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View article: Liquid Viscosity and Surface Tension of Cyclohexane Between 280 and 473 K by Surface Light Scattering
Liquid Viscosity and Surface Tension of Cyclohexane Between 280 and 473 K by Surface Light Scattering Open
The present study provides experimental data for the liquid viscosity and surface tension of cyclohexane at or close to saturation conditions by surface light scattering between (280 and 473) K. By applying the hydrodynamic theory for surf…
View article: Functionalized ionic liquid coatings in the Pd-catalyzed selective hydrogenation of acetylene in ethylene-rich feeds
Functionalized ionic liquid coatings in the Pd-catalyzed selective hydrogenation of acetylene in ethylene-rich feeds Open
This study explores the tuning of a Pd/Al2O3 hydrogenation catalyst for the selective removal of trace acetylene from ethylene-rich feeds by coating the catalyst with non-functionalized and functionalized ionic liquids (denoted as SCILL an…
View article: Isomers of perhydro-benzytoluene
Isomers of perhydro-benzytoluene Open
NMR spectra of the ortho-, meta- and para isomers of perhydro-benzytoluene, each as cis- and trans-mixture By using a quantitative reverse gated 13C-NMR pulse seqeunce, the fractions of cis and trans isomers can be determined from the inte…
View article: Isomers of perhydro-benzytoluene
Isomers of perhydro-benzytoluene Open
NMR spectra of the ortho-, meta- and para isomers of perhydro-benzytoluene, each as cis- and trans-mixture By using a quantitative reverse gated 13C-NMR pulse seqeunce, the fractions of cis and trans isomers can be determined from the inte…
View article: Front Cover: Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS (ChemPhysChem 2/2023)
Front Cover: Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS (ChemPhysChem 2/2023) Open
The Front Cover shows substitution of volatile acetonitrile ligands by a nitrile-functionalized imidazolium cation. The formed cationic complex and the counter ions exhibit a specific preferential orientation at the ionic liquid/gas interf…
View article: Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS
Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS Open
The front cover artwork is provided by the groups of Prof. Hans‐Peter Steinrück and Prof. Peter Wasserscheid at the Friedrich‐Alexander‐Universität (FAU) Erlangen‐Nürnberg. The image shows substitution of volatile acetonitrile ligands by a…
View article: The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design
The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design Open
Invited for the cover of this issue are the groups of Hans‐Peter Steinrück and Peter Wasserscheid at the Friedrich‐Alexander‐Universität Erlangen‐Nürnberg. The image depicts two Pt catalysts dissolved in an ionic liquid. For one of them, f…
View article: Front Cover: The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design (Chem. Eur. J. 3/2023)
Front Cover: The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design (Chem. Eur. J. 3/2023) Open
Fluorinated side chains of a functionalized Pt complex in an ionic liquid act as buoys, leading to pronounced enrichment of the complex at the IL/gas interface, as is evidenced by strongly enhanced Pt signals in angle-resolved photoelectro…
View article: The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design
The Buoy Effect: Surface Enrichment of a Pt Complex in IL Solution by Ligand Design Open
The targeted enrichment of a Pt complex with an ionic liquid (IL)‐derived ligand system in IL solution is demonstrated by using angle‐resolved X‐ray photoelectron spectroscopy. When the ligand system is complemented with fluorinated side c…
View article: Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS
Formation and Surface Behavior of Pt and Pd Complexes with Ligand Systems Derived from Nitrile‐functionalized Ionic Liquids Studied by XPS Open
We studied the formation and surface behavior of Pt(II) and Pd(II) complexes with ligand systems derived from two nitrile‐functionalized ionic liquids (ILs) in solution using angle‐resolved X‐ray photoelectron spectroscopy (ARXPS). These l…
View article: UiO‐66 and hcp UiO‐66 Catalysts Synthesized from Ionic Liquids as Linker Precursors
UiO‐66 and hcp UiO‐66 Catalysts Synthesized from Ionic Liquids as Linker Precursors Open
Using ionic liquids (ILs) as linker precursors, the well‐known metal‐organic framework (MOF) UiO‐66 (Universitetet i Oslo) and the recently reported MOF hcp UiO‐66 (hexagonal closed packed) have been successfully synthesized and characteri…
View article: Volatility of molten salts [Ph<sub>4</sub>P][NTf<sub>2</sub>] and Cs[NTf<sub>2</sub>]
Volatility of molten salts [Ph<sub>4</sub>P][NTf<sub>2</sub>] and Cs[NTf<sub>2</sub>] Open
The two ionic compounds [Ph 4 P][NTf 2 ] and Cs[NTf 2 ] were qualified to be suitable liquid materials for different high temperature applications. Development and optimization of these application techniques require knowledge of the therm…
View article: Influence of Carboxylate Anions on Phase Behavior of Choline Ionic Liquid Mixtures
Influence of Carboxylate Anions on Phase Behavior of Choline Ionic Liquid Mixtures Open
Mixing ionic liquids is a suitable strategy to tailor properties, e.g., to reduce melting points. The present study aims to widen the application range of low-toxic choline-based ionic liquids by studying eight binary phase diagrams of six…
View article: CCDC 1854712: Experimental Crystal Structure Determination
CCDC 1854712: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Interaction of Ester‐Functionalized Ionic Liquids with Atomically‐Defined Cobalt Oxides Surfaces: Adsorption, Reaction and Thermal Stability
Interaction of Ester‐Functionalized Ionic Liquids with Atomically‐Defined Cobalt Oxides Surfaces: Adsorption, Reaction and Thermal Stability Open
Hybrid materials consisting of ionic liquid (ILs) films on supported oxides hold a great potential for applications in electronic and energy materials. In this work, we have performed surface science model studies scrutinizing the interact…
View article: Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide
Gluing Ionic Liquids to Oxide Surfaces: Chemical Anchoring of Functionalized Ionic Liquids by Vapor Deposition onto Cobalt(II) Oxide Open
Ionic liquids (IL) hold a great potential as novel electrolytes for applications in electronic materials and energy technology. The functionality of ILs in these applications relies on their interface to semiconducting nanomaterials. There…
View article: Bone Morphogenetic Protein-7 Enhances Degradation of Osteoinductive Bioceramic Implants in an Ectopic Model
Bone Morphogenetic Protein-7 Enhances Degradation of Osteoinductive Bioceramic Implants in an Ectopic Model Open
Background: The aim of the present study was to evaluate the degradation pattern of highly porous bioceramics as well as the bone formation in presence of bone morphogenetic protein 7 (BMP-7) in an ectopic site. Methods: Novel calcium phos…
View article: BMP-7 Preserves Surface Integrity of Degradable-ceramic Cranioplasty in a Göttingen Minipig Model
BMP-7 Preserves Surface Integrity of Degradable-ceramic Cranioplasty in a Göttingen Minipig Model Open
Background: The aim of the study was to evaluate the integrity of a craniotomy grafted site in a minipig model using different highly porous calcium phosphate ceramic scaffolds either loaded or nonloaded with bone morphogenetic protein-7 (…
View article: CCDC 1415703: Experimental Crystal Structure Determination
CCDC 1415703: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1498196: Experimental Crystal Structure Determination
CCDC 1498196: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1415704: Experimental Crystal Structure Determination
CCDC 1415704: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1498197: Experimental Crystal Structure Determination
CCDC 1498197: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1498195: Experimental Crystal Structure Determination
CCDC 1498195: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …