Steven E. Kalman
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View article: CCDC 2193082: Experimental Crystal Structure Determination
CCDC 2193082: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Selective Photo‐Oxygenation of Light Alkanes Using Iodine Oxides and Chloride
Selective Photo‐Oxygenation of Light Alkanes Using Iodine Oxides and Chloride Open
Partial oxidation of light alkanes to generate alkyl esters has been achieved under photochemical conditions using mixtures of iodine oxides and chloride salts in trifluoroacetic acid (HTFA). The reactions are catalytic in chloride and are…
View article: Mechanism of Hydrocarbon Functionalization by an Iodate/Chloride System: The Role of Ester Protection
Mechanism of Hydrocarbon Functionalization by an Iodate/Chloride System: The Role of Ester Protection Open
Mixtures of chloride and iodate salts for light alkane oxidation achieve > 20% yield of methyl trifluoroacetate (TFA) from methane with > 85% selectivity (J. Am. Chem. Soc. 2014, 136, 8393-8401). The mechanism of this C–H oxygenation has b…
View article: CCDC 1851813: Experimental Crystal Structure Determination
CCDC 1851813: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Combined Furan C–H Activation and Furyl Ring-Opening by an Iron(II) Complex
Combined Furan C–H Activation and Furyl Ring-Opening by an Iron(II) Complex Open
Cp*Fe[P(OCH2)3CEt]2Ph (Cp* = η5-1,2,3,4,5-pentamethylcyclopentadienyl, P(OCH2)3CEt = 2,6,7-trioxa-1-phosphabicyclo[2,2,1]heptane) reacts with furan and 2-methylfuran under photolytic conditions to selectively activate the α-C–H bond to pro…
View article: CCDC 1497646: Experimental Crystal Structure Determination
CCDC 1497646: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1497647: Experimental Crystal Structure Determination
CCDC 1497647: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …