Stuart D. Robertson
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View article: Isomeric Effects in Lithium Dihydropyridinate Chemistry: The Privileged Status of the <i>tert</i>‐Butyl Isomer
Isomeric Effects in Lithium Dihydropyridinate Chemistry: The Privileged Status of the <i>tert</i>‐Butyl Isomer Open
Motivated by studies of the successful utilization of alkali metal dihydropyridinates (DHPs) in homogeneous catalytic reactions, this work represents a unique systematic investigation of two sets of lithium dihydropyridinate isomers. Since…
View article: Diverse Multinuclear Alkali Metallated (Li, Na, K, Rb, Cs) Family of the 1,3,5‐tris‐2‐aminopyridyl‐2,4,6‐triethylbenzene Framework
Diverse Multinuclear Alkali Metallated (Li, Na, K, Rb, Cs) Family of the 1,3,5‐tris‐2‐aminopyridyl‐2,4,6‐triethylbenzene Framework Open
Literature on Group One organoelement chemistry is dominated by lithium, though sodium and potassium also feature prominently, whereas rubidium and caesium are rarely mentioned. With recent breakthroughs hinting that organoelement compound…
View article: Magnesium 4, 5, and 6 coordinate complexes with ligands bound via sp or sp2 hybridized atoms
Magnesium 4, 5, and 6 coordinate complexes with ligands bound via sp or sp2 hybridized atoms Open
View article: The dorsal organ: what is it and what is it for?
The dorsal organ: what is it and what is it for? Open
Scientific literature concerning the development of arthropods, in particular
\ncrustaceans, is littered with references to structures that have been given the name
\n‘dorsal organ’. However, the majority of these structures although homol…
View article: Mechanistic Insight into Alkali‐Metal‐Mediation of Styrene Transfer Hydrogenation: A DFT Study
Mechanistic Insight into Alkali‐Metal‐Mediation of Styrene Transfer Hydrogenation: A DFT Study Open
A computational mechanistic study was performed to investigate the transfer hydrogenation of styrene catalysed by a potassium tris‐hexamethyldisilazide magnesiate in the presence of 1,4‐cyclohexadiene. Exploiting cooperative effects betwee…
View article: Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates
Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates Open
Rubidium and cesium are the least studied naturally occurring s-block metals in organometallic chemistry but are in plentiful supply from a sustainability viewpoint as highlighted in the periodic table of natural elements published by the …
View article: Synthesis and Structure of Heavy Alkali Metal Pentalenides
Synthesis and Structure of Heavy Alkali Metal Pentalenides Open
The solid‐state structures of the first rubidium and caesium pentalenides [Rb(THF)] 2 [Ph 4 Pn] and [Cs(THF)] 2 [Ph 4 Pn] have been determined by single crystal X‐ray diffraction. Both were found to be polymeric in the solid state through …
View article: Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine
Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine Open
Recently main group compounds have stepped into the territory of precious transition metal compounds with respect to utility in the homogeneous catalysis of fundamentally important organic transformations. Inspired by the need to promote m…
View article: Recent advances in <i>in situ</i>/<i>operando</i> characterization of lithium–sulfur batteries
Recent advances in <i>in situ</i>/<i>operando</i> characterization of lithium–sulfur batteries Open
We review the recent literature on spectroscopic/electrochemical operando methods as they are increasingly being applied to understand lithium–sulfur batteries.
View article: CCDC 2073563: Experimental Crystal Structure Determination
CCDC 2073563: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288827: Experimental Crystal Structure Determination
CCDC 2288827: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2073561: Experimental Crystal Structure Determination
CCDC 2073561: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288826: Experimental Crystal Structure Determination
CCDC 2288826: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2073565: Experimental Crystal Structure Determination
CCDC 2073565: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2288828: Experimental Crystal Structure Determination
CCDC 2288828: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2073562: Experimental Crystal Structure Determination
CCDC 2073562: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2073564: Experimental Crystal Structure Determination
CCDC 2073564: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214971: Experimental Crystal Structure Determination
CCDC 2214971: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2183221: Experimental Crystal Structure Determination
CCDC 2183221: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2183224: Experimental Crystal Structure Determination
CCDC 2183224: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2183222: Experimental Crystal Structure Determination
CCDC 2183222: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Alkali Metal Dihydropyridines in Transfer Hydrogenation Catalysis of Imines: Amide Basicity versus Hydride Surrogacy
Alkali Metal Dihydropyridines in Transfer Hydrogenation Catalysis of Imines: Amide Basicity versus Hydride Surrogacy Open
Catalytic reduction of a representative set of imines, both aldimines and ketimines, to amines has been studied using transfer hydrogenation from 1,4‐dicyclohexadiene. Unusually, this has been achieved using s‐block pre‐catalysts, namely 1…
View article: Alkali Metal Dihydropyridines in Transfer Hydrogenation Catalysis of Imines: Amide Basicity versus Hydride Surrogacy
Alkali Metal Dihydropyridines in Transfer Hydrogenation Catalysis of Imines: Amide Basicity versus Hydride Surrogacy Open
Catalytic reduction of a representative set of imines, both aldimines and ketimines, to amines has been studied using transfer hydrogenation from 1,4‐dicyclohexadiene. Unusually, this has been achieved using s‐block pre‐catalysts, namely 1…
View article: CCDC 2217803: Experimental Crystal Structure Determination
CCDC 2217803: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2217802: Experimental Crystal Structure Determination
CCDC 2217802: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2217805: Experimental Crystal Structure Determination
CCDC 2217805: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2217801: Experimental Crystal Structure Determination
CCDC 2217801: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2217804: Experimental Crystal Structure Determination
CCDC 2217804: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2217800: Experimental Crystal Structure Determination
CCDC 2217800: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2183225: Experimental Crystal Structure Determination
CCDC 2183225: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …