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View article: Novel Co<sub>5</sub> Cluster Based Triazole Bridged Cobalt‐Fluorophosphate: Synthesis, Structure, Magnetic and Heterogeneous Catalytic Epoxidation Studies
Novel Co<sub>5</sub> Cluster Based Triazole Bridged Cobalt‐Fluorophosphate: Synthesis, Structure, Magnetic and Heterogeneous Catalytic Epoxidation Studies Open
A novel triazole bridged cobalt fluorophosphate coordination polymer with the formula {Co 5 (1,2,4‐triazole) 2 (OH) 2 (PO 3 F) 4 } n has been synthesized. Single crystal X‐ray studies reveal that the compound comprises of Co 5 clusters whi…
View article: Pure silica-supported transition metal catalysts for the non-oxidative dehydrogenation of ethane: confinement effects on the stability
Pure silica-supported transition metal catalysts for the non-oxidative dehydrogenation of ethane: confinement effects on the stability Open
All-silica MFI zeolite was used as a support for the synthesis of promoter-free robust transition metal catalysts. Effects of different physical parameters and catalyst deactivation mechanism were studied for the ethane dehydrogenation rea…
View article: Stable Cr-MFI Catalysts for the Nonoxidative Dehydrogenation of Ethane: Catalytic Performance and Nature of the Active Sites
Stable Cr-MFI Catalysts for the Nonoxidative Dehydrogenation of Ethane: Catalytic Performance and Nature of the Active Sites Open
The nonoxidative catalytic dehydrogenation of ethane allows the production of ethylene at lower temperatures than those applied in steam crackers. This, however, requires stable catalysts that minimize coke production. Here, we report a si…
View article: Conversion of Formic Acid into Methanol Using a Bipyridine-Functionalized Molecular Heterogeneous Catalyst
Conversion of Formic Acid into Methanol Using a Bipyridine-Functionalized Molecular Heterogeneous Catalyst Open
Although the conversion of carbon dioxide (and its derivatives) into methanol has attracted remarkable attention in the last two decades, performing this process over a heterogeneous catalyst under mild conditions is still a challenging ta…
View article: Acid functionalized ionic liquid catalyzed transformation of non-food biomass into platform chemical and fuel additive
Acid functionalized ionic liquid catalyzed transformation of non-food biomass into platform chemical and fuel additive Open
View article: Mechanochemical synthesis of graphene oxide-supported transition metal catalysts for the oxidation of isoeugenol to vanillin
Mechanochemical synthesis of graphene oxide-supported transition metal catalysts for the oxidation of isoeugenol to vanillin Open
Vanillin is one of the most commonly used natural products, which can also be produced from lignin-derived feedstocks. The chemical synthesis of vanillin is well-established in large-scale production from petrochemical-based starting mater…
View article: Catalytic Conversion of Biomass
Catalytic Conversion of Biomass Open
Petroleum, natural gas and coal supply most of the energy consumed worldwide and their massive utilization has allowed our society to reach high levels of development in the past century.[...]
View article: Ni-based bimetallic heterogeneous catalysts for energy and environmental applications
Ni-based bimetallic heterogeneous catalysts for energy and environmental applications Open
This review provides a comprehensive overview of nickel based bimetallic catalysts for energy and environmental applications.
View article: Critical design of heterogeneous catalysts for biomass valorization: current thrust and emerging prospects
Critical design of heterogeneous catalysts for biomass valorization: current thrust and emerging prospects Open
Catalysis in the heterogeneous phase plays a crucial role in the valorization of biorenewable substrates with controlled reactivity, efficient mechanical process separation, greater recyclability and minimization of environmental effects.
View article: Sustainable Biomaterials: Current Trends, Challenges and Applications
Sustainable Biomaterials: Current Trends, Challenges and Applications Open
Biomaterials and sustainable resources are two complementary terms supporting the development of new sustainable emerging processes. In this context, many interdisciplinary approaches including biomass waste valorization and proper usage o…
View article: Microwave-Assisted Conversion of Levulinic Acid to γ-Valerolactone Using Low-Loaded Supported Iron Oxide Nanoparticles on Porous Silicates
Microwave-Assisted Conversion of Levulinic Acid to γ-Valerolactone Using Low-Loaded Supported Iron Oxide Nanoparticles on Porous Silicates Open
The microwave-assisted conversion of levulinic acid (LA) has been studied using low-loaded supported Fe-based catalysts on porous silicates. A very simple, productive, and highly reproducible continuous flow method has been used for the ho…
View article: Integrated enzymatic catalysis for biomass deconstruction: a partnership for a sustainable future
Integrated enzymatic catalysis for biomass deconstruction: a partnership for a sustainable future Open
Deconstruction of lignocellulosic biomass using enzymatic catalysis can offer several advantages as compared to chemical catalysis in terms of product selectivity, production cost and sustainability issues. This contribution aims to provid…