Sylvain Duval
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View article: Polynuclear tantalum( <scp>v</scp> ) coordination complexes: from dinuclear {Ta <sub>2</sub> O} to octanuclear {Ta <sub>8</sub> O <sub>12</sub> } oxo species connected through aryl monotopic carboxylate linkers
Polynuclear tantalum( <span>v</span> ) coordination complexes: from dinuclear {Ta <sub>2</sub> O} to octanuclear {Ta <sub>8</sub> O <sub>12</sub> } oxo species connected through aryl monotopic carboxylate linkers Open
Carboxylate ligand reaction with a tantalum ethoxide precursor led to the formation of molecular polynuclear tantalum clusters, from {Ta 2 O} dimers to {Ta 8 O 12 } octamers. They are further used for DHA conversion tests to assess their a…
View article: CCDC 2280853: Experimental Crystal Structure Determination
CCDC 2280853: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Isolation of a Dodecanuclear Polyoxo Cluster {Nb<sub>12</sub>O<sub>21</sub>} Showing a Rare Case of Five‐fold Coordinated Niobium(V) Centers with a Square Pyramidal Geometry
Isolation of a Dodecanuclear Polyoxo Cluster {Nb<sub>12</sub>O<sub>21</sub>} Showing a Rare Case of Five‐fold Coordinated Niobium(V) Centers with a Square Pyramidal Geometry Open
The reactivity of the complexing anthracene‐9‐carboxylate ligand has been investigated with a niobium(IV) tetrachloride precursor (NbCl 4 ⋅ 2THF) in isopropanol solvent. This resulted in the crystallization of a molecular assembly containi…
View article: CCDC 2153000: Experimental Crystal Structure Determination
CCDC 2153000: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2153011: Experimental Crystal Structure Determination
CCDC 2153011: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties
Facile synthesis of paramagnetic Co(II)-hexaborate(2-) based semiorganic complexes: A combined investigation on X-Ray crystal structure, Hirshfield surfaces analysis, optical and magnetic properties Open
Two new paramagnetic hybrid cobalt(II)-hexaborate(2-) based semiorganic complexes; (2A3MP) 2 [Co{κ 3 O-B 6 O 7 (OH) 6 } 2 ].2H 2 O( 1 ) and (2A4MP) 2 [Co{κ 3 O-B 6 O 7 (OH) 6 } 2 ].2H 2 O ( 2 )(2A3MP = 2-amino-3-methylpyridinium, 2A4MP = 2…
View article: Raman Mapping as a Tool for Evaluating I<sub>2</sub> and I<sub>3</sub><sup>–</sup> Diffusion Over Single-Crystal UiO-67_NH<sub>2</sub>(M) (M = Zr, Zr/Hf, or Hf)
Raman Mapping as a Tool for Evaluating I<sub>2</sub> and I<sub>3</sub><sup>–</sup> Diffusion Over Single-Crystal UiO-67_NH<sub>2</sub>(M) (M = Zr, Zr/Hf, or Hf) Open
Le captage de l'iode gazeux a été profondément étudié pour tenter de pallier les dangers de l'énergie nucléaire. La famille UiO de matériaux MOF est considérée comme l'un des meilleurs candidats à cet effet car elle couple des surfaces spé…
View article: CCDC 2172035: Experimental Crystal Structure Determination
CCDC 2172035: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172038: Experimental Crystal Structure Determination
CCDC 2172038: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172036: Experimental Crystal Structure Determination
CCDC 2172036: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172034: Experimental Crystal Structure Determination
CCDC 2172034: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172041: Experimental Crystal Structure Determination
CCDC 2172041: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172040: Experimental Crystal Structure Determination
CCDC 2172040: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172039: Experimental Crystal Structure Determination
CCDC 2172039: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2172037: Experimental Crystal Structure Determination
CCDC 2172037: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Airborne Release Fraction of Dissolved Materials During the Combustion of Liquids Representative of Nuclear Waste Treatment Process
Airborne Release Fraction of Dissolved Materials During the Combustion of Liquids Representative of Nuclear Waste Treatment Process Open
International audience
View article: CCDC 2171872: Experimental Crystal Structure Determination
CCDC 2171872: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2171874: Experimental Crystal Structure Determination
CCDC 2171874: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2171875: Experimental Crystal Structure Determination
CCDC 2171875: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2171873: Experimental Crystal Structure Determination
CCDC 2171873: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Crystalline Molecular Assemblies of Complexes Showing Eightfold Coordinated Niobium(IV) Dodecahedral Geometry in the Pyridine-Dicarboxylic Acid System
Crystalline Molecular Assemblies of Complexes Showing Eightfold Coordinated Niobium(IV) Dodecahedral Geometry in the Pyridine-Dicarboxylic Acid System Open
The reactivity of 2,3-pyridine-dicarboxylic (known as quinolinic or H2qui) acid and 2,5-pyridine-dicarboxylic (known as isocinchomeronic or H2icc) acid has been investigated as a complexing agent toward …
View article: CCDC 2179578: Experimental Crystal Structure Determination
CCDC 2179578: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2179579: Experimental Crystal Structure Determination
CCDC 2179579: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2179580: Experimental Crystal Structure Determination
CCDC 2179580: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Investigation of pyrene vs Anthracene-based oxime esters: Role of the excited states on their polymerization initiating abilities
Investigation of pyrene vs Anthracene-based oxime esters: Role of the excited states on their polymerization initiating abilities Open
View article: Structural Variety of Niobium(V) Polyoxo Clusters Obtained from the Reaction with Aromatic Monocarboxylic Acids: Isolation of {Nb<sub>2</sub>O}, {Nb<sub>4</sub>O<sub>4</sub>} and {Nb<sub>8</sub>O<sub>12</sub>} Cores
Structural Variety of Niobium(V) Polyoxo Clusters Obtained from the Reaction with Aromatic Monocarboxylic Acids: Isolation of {Nb<sub>2</sub>O}, {Nb<sub>4</sub>O<sub>4</sub>} and {Nb<sub>8</sub>O<sub>12</sub>} Cores Open
The reactivity of aryl monocarboxylic acids (benzoic, 1‐ or 2‐naphtoic, 4’‐methylbiphenyl‐4‐carboxylic, and anthracene‐9‐carboxylic acids) as complexing agents for the ethoxide niobium(V) (Nb(OEt) 5 precursor has been investigated. A total…
View article: Microwave-Assisted Synthesis of Porous Composites MOF–Textile for the Protection against Chemical and Nuclear Hazards
Microwave-Assisted Synthesis of Porous Composites MOF–Textile for the Protection against Chemical and Nuclear Hazards Open
Since the emergence of chemical, biological, radiological, and nuclear risks, significant efforts have been made to create efficient personal protection equipment. Recently, metal-organic framework (MOF) materials have emerged as new promi…
View article: Capture of Gaseous Iodine in Isoreticular Zirconium‐Based UiO‐n Metal‐Organic Frameworks: Influence of Amino Functionalization, DFT Calculations, Raman and EPR Spectroscopic Investigation
Capture of Gaseous Iodine in Isoreticular Zirconium‐Based UiO‐n Metal‐Organic Frameworks: Influence of Amino Functionalization, DFT Calculations, Raman and EPR Spectroscopic Investigation Open
A series of Zr‐based UiO‐n MOF materials ( n =66, 67, 68) have been studied for iodine capture. Gaseous iodine adsorption was collected kinetically from a home‐made set‐up allowing the continuous measurement of iodine content trapped withi…
View article: Molecular niobium(<scp>v</scp>) complexes with mononuclear {Nb<sub>1</sub>} and dinuclear oxo species {Nb<sub>2</sub>O} connected through aryl di- or tetra-carboxylate linker
Molecular niobium(<span>v</span>) complexes with mononuclear {Nb<sub>1</sub>} and dinuclear oxo species {Nb<sub>2</sub>O} connected through aryl di- or tetra-carboxylate linker Open
Di- or tetracarboxylic acid ligands were used to isolate molecular coordination complexes containing the association of several mononuclear {Nb 1 } moiety and dinuclear {Nb 2 O} niobium( v ) polyoxo clusters.
View article: 5,12-Dihydroindolo[3,2-a]carbazole: A promising scaffold for the design of visible light photoinitiators of polymerization
5,12-Dihydroindolo[3,2-a]carbazole: A promising scaffold for the design of visible light photoinitiators of polymerization Open