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View article: Sodium-based Donor-Acceptor Assemblies Featuring Thermally Activated Delayed Fluorescence Enabled by Highly Efficient Through-Space Charge Transfer
Sodium-based Donor-Acceptor Assemblies Featuring Thermally Activated Delayed Fluorescence Enabled by Highly Efficient Through-Space Charge Transfer Open
Exploring more economical and innovative alternatives to precious 4d and 5d metal complexes used in photocatalysis, OLEDs, or energy conversion has primarily focused on 3d metals, leaving highly abundant alkali...
View article: Sodium-Based Donor-Acceptor Assemblies Featuring Thermally Activated Delayed Fluorescence Enabled by Highly Efficient Through-Space Charge Transfer
Sodium-Based Donor-Acceptor Assemblies Featuring Thermally Activated Delayed Fluorescence Enabled by Highly Efficient Through-Space Charge Transfer Open
Exploring more economical and innovative alternatives to precious 4d and 5d metal complexes used in photocatalysis, OLEDs, or energy conversion has primarily focused on 3d metals, leaving highly abundant alkali metals underexplored. We sho…
View article: Sodium-Based Donor-Acceptor Assemblies Featuring Thermally Activated Delayed Fluorescence Enabled by Highly Efficient Through-Space Charge Transfer
Sodium-Based Donor-Acceptor Assemblies Featuring Thermally Activated Delayed Fluorescence Enabled by Highly Efficient Through-Space Charge Transfer Open
Exploring more economical and innovative alternatives to precious second- and third-row metal complexes widely used in photocatalysis, electroluminescent devices, or energy conversion has primarily focused on 3d metals, leaving abundant re…
View article: DiICz MR-TADF Emitters as Energy Transfer Photocatalysts
DiICz MR-TADF Emitters as Energy Transfer Photocatalysts Open
Photoinduced energy transfer (PEnT) reactions are a subset of photochemical reactions that involve the indirect photoactivation of substrates following an energy transfer from a photoexcited sensitizer/photocatalyst. Examples of PEnT react…
View article: DiICz MR-TADF emitters as potent energy transfer photocatalysts
DiICz MR-TADF emitters as potent energy transfer photocatalysts Open
Here we introduce a family of diindolocarbazole (DiICz) multi-resonant thermally activated delayed fluorescent (MR-TADF) compounds DiICztBu4, DiICzMes4, DiICztBuCz4, and DiICztBuDPA4, as potent energy transfer photocatalysts (PCs).
View article: The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation
The Golden Age of Thermally Activated Delayed Fluorescence Materials: Design and Exploitation Open
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable explosion of interest in the design of thermally activated delayed fluorescence (TADF) compounds, particularly as emitters for organic light-emitting dio…
View article: CCDC 2173213: Experimental Crystal Structure Determination
CCDC 2173213: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Revisiting Ligand‐to‐Ligand Charge Transfer Phosphorescence Emission from Zinc(II) Diimine Bis‐Thiolate Complexes: It is Actually Thermally Activated Delayed Fluorescence
Revisiting Ligand‐to‐Ligand Charge Transfer Phosphorescence Emission from Zinc(II) Diimine Bis‐Thiolate Complexes: It is Actually Thermally Activated Delayed Fluorescence Open
In this work we revisit and re‐evaluate the photophysical behavior of the prototypical complex [Zn(SC 6 H 4 ‐4‐R) 2 (phen)] as the most in‐depth studied type of Zn(II)‐based triplet state emitters. Previous reports suggest population of li…