Leonardo Tensi
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View article: Mechanism of Action of MAO’s <i>Molecular Cousin</i>
Mechanism of Action of MAO’s <i>Molecular Cousin</i> Open
The aluminum-alkyl borate (AAB) salt {[iBu2(DMA)-Al]2(μ-H)}+[B-(C6F5)4]- (AlHAl_DMA; DMA = N,N-dimethylaniline) is able of fully activating d…
View article: A Multinuclear NMR Study on the Speciation in the Liquid-Phase Synthesis of Sulfide-Based Electrolytes for All-Solid-State Lithium Batteries
A Multinuclear NMR Study on the Speciation in the Liquid-Phase Synthesis of Sulfide-Based Electrolytes for All-Solid-State Lithium Batteries Open
The preparation of Li2S-P4S10 (LPS) solid electrolytes for all-solid-state lithium batteries through liquid-phase methods has attracted much attention over the last years. One of the most critical aspects t…
View article: A Tale of Two Designs: Comparing Design of Experiment Strategies for Reaction Optimization
A Tale of Two Designs: Comparing Design of Experiment Strategies for Reaction Optimization Open
The application of Design of Experiments (DoE) significantly accelerates the optimization of reaction conditions for previously unreported transformations. DoE achieves this by focusing experimental efforts, enabling efficient exploration …
View article: Organometallic Catalysis Catches up with Enzymatic in the Regeneration of NADH
Organometallic Catalysis Catches up with Enzymatic in the Regeneration of NADH Open
A rational design, based on a deep understanding of the reaction mechanism, led to the development of an iridium organometallic catalyst with activity comparable to that of enzymes in the chemical regeneration of NADH, using phosphite as a…
View article: Starch-Based scaffold produced by FDM 3D printing technique as Innovative and biosustainable wound dressing
Starch-Based scaffold produced by FDM 3D printing technique as Innovative and biosustainable wound dressing Open
Starch is a safe biopolymer, whose use for the production of scaffolds intended for deep wounds treatment is limited, due to its low mechanical and thermal properties. For this reason, until now, it has been used in low amounts and/or in c…
View article: Equisetum arvense standardized dried extract hinders age-related osteosarcopenia
Equisetum arvense standardized dried extract hinders age-related osteosarcopenia Open
Age-associated osteosarcopenia is an unresolved syndrome characterized by the concomitant loss of bone (osteopenia) and skeletal muscle (sarcopenia) tissues increasing falls, immobility, morbidity, and mortality. Unbalanced resorption of b…
View article: CCDC 2272133: Experimental Crystal Structure Determination
CCDC 2272133: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Zirconium complexes of an aminophenolate-etherphenolate ONO'O ligand: Synthesis, characterization and catalytic properties
Zirconium complexes of an aminophenolate-etherphenolate ONO'O ligand: Synthesis, characterization and catalytic properties Open
A synthetic protocol to access new aminophenolate-etherphenolate ONO'O ligands is presented. Zirconium iso-propoxide and benzyl complexes of a prototypical tert-butyl substituted ONO'O ligand can be synthesized in high yields as single con…
View article: CCDC 2272131: Experimental Crystal Structure Determination
CCDC 2272131: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2272132: Experimental Crystal Structure Determination
CCDC 2272132: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Octahedral Zirconium Salan Catalysts for Olefin Polymerization: Substituent and Solvent Effects on Structure and Dynamics
Octahedral Zirconium Salan Catalysts for Olefin Polymerization: Substituent and Solvent Effects on Structure and Dynamics Open
Group 4 metal-Salan olefin polymerization catalysts typically have relatively low activity, being slowed down by a pre-equilibrium favoring a non-polymerization active resting state identified as a mer-mer isomer (MM); formation of …
View article: CCDC 2254888: Experimental Crystal Structure Determination
CCDC 2254888: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2254890: Experimental Crystal Structure Determination
CCDC 2254890: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2254889: Experimental Crystal Structure Determination
CCDC 2254889: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Molecular <i>versus</i> Silica‐Supported Iridium Water Oxidation Catalysts
Molecular <i>versus</i> Silica‐Supported Iridium Water Oxidation Catalysts Open
A stringent comparison between two pairs of molecular/immobilized water oxidation catalysts ([Cp * Ir(Me‐pica)Cl], 1 , versus 1_SiO 2 , Me‐pica=κ 2 ‐N‐methyl‐picolinamide; [Cp * Ir(pysa)NO 3 ], 2 , versus 2_SiO 2 , pysa=κ 2 ‐pyridine‐2‐sul…
View article: Formulation and characterization of sustainable bioadhesive films for wound treatment based on barley β-glucan extract obtained using the high power ultrasonic technique
Formulation and characterization of sustainable bioadhesive films for wound treatment based on barley β-glucan extract obtained using the high power ultrasonic technique Open
β-glucan is a well-known functional and bioactive food ingredient. Recently, some studies highlighted several interesting pharmacological activities, such as hypocholesterolemic, hypoglycemic, immunomodulatory, antitumor, antioxidant and a…
View article: CCDC 2212488: Experimental Crystal Structure Determination
CCDC 2212488: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212489: Experimental Crystal Structure Determination
CCDC 2212489: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212490: Experimental Crystal Structure Determination
CCDC 2212490: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis and Characterization of Chiral Iridium Complexes Bearing Carbohydrate Functionalized Pyridincarboxamide Ligands and Their Application as Catalysts in the Asymmetric Transfer Hydrogenation of α-Ketoacids in Water
Synthesis and Characterization of Chiral Iridium Complexes Bearing Carbohydrate Functionalized Pyridincarboxamide Ligands and Their Application as Catalysts in the Asymmetric Transfer Hydrogenation of α-Ketoacids in Water Open
[Cp*IrLnCl] complexes [L1 = (methyl-β-d-glucopyranosid-2-yl)picolinamide, 1; L2 = (methyl-3,4,6-tri-O-acetyl-β-d-glucopyranosid-2-yl)picolinamide, 2; L3 = (2,3,4,6-tetra-O-acetyl-β-d-glucopyranosid-1-yl)picolinamide, 3] have been synthesiz…
View article: Zirconium Complexes of Aminophenolate-Etherphenolate Ono'O Ligands: Synthesis, Characterization and Catalytic Properties
Zirconium Complexes of Aminophenolate-Etherphenolate Ono'O Ligands: Synthesis, Characterization and Catalytic Properties Open
View article: Elucidating the intimate mechanism of NAD<sup>+</sup> hydrogenation with phosphonic acid catalysed by Cp*Ir(pyridine-2-sulfonamidate) complexes
Elucidating the intimate mechanism of NAD<sup>+</sup> hydrogenation with phosphonic acid catalysed by Cp*Ir(pyridine-2-sulfonamidate) complexes Open
Cp*Ir(pyridine-2-sulfonamidate) complexes undergo pyridine displacement when catalysing nicotine amide dinucleotide hydrogenation in the presence of phosphonic acid, thus explaining the molecular origin of their improved performance.
View article: CCDC 2174843: Experimental Crystal Structure Determination
CCDC 2174843: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2174842: Experimental Crystal Structure Determination
CCDC 2174842: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Ion Pairing in Cationic Au(I)(μ‐H)<sub>2</sub>WCp<sub>2</sub> Bimetallic Dihydrides
Ion Pairing in Cationic Au(I)(μ‐H)<sub>2</sub>WCp<sub>2</sub> Bimetallic Dihydrides Open
The interionic structure in solution of a series of [LAu(μ‐H) 2 WCp 2 ][BF 4 ] ion pairs (L=N‐heterocyclic carbene, phosphine or phosphite) has been elucidated by means of heteronuclear NOE and diffusion NMR. Selective ion pairing based on…
View article: CCDC 2164448: Experimental Crystal Structure Determination
CCDC 2164448: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Single-Site Iridium Picolinamide Catalyst Immobilized onto Silica for the Hydrogenation of CO<sub>2</sub> and the Dehydrogenation of Formic Acid
Single-Site Iridium Picolinamide Catalyst Immobilized onto Silica for the Hydrogenation of CO<sub>2</sub> and the Dehydrogenation of Formic Acid Open
The development of an efficient heterogeneous catalyst for storing H2 into CO2 and releasing it from the produced formic acid, when needed, is a crucial target for overcoming some intrinsic criticalities of green hydr…
View article: CCDC 2141405: Experimental Crystal Structure Determination
CCDC 2141405: Experimental Crystal Structure Determination Open
View article: CCDC 2121516: Experimental Crystal Structure Determination
CCDC 2121516: Experimental Crystal Structure Determination Open
View article: CCDC 2121515: Experimental Crystal Structure Determination
CCDC 2121515: Experimental Crystal Structure Determination Open