Horst Hahn
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View article: Influence of In‐Doping on the Structure and Electrochemical Performance of Compositionally Complex Garnet‐Type Solid Electrolytes
Influence of In‐Doping on the Structure and Electrochemical Performance of Compositionally Complex Garnet‐Type Solid Electrolytes Open
The electrochemical instability of electrode active materials as well as the flammability of the organic liquid electrolytes in Li‐ion batteries pose challenges for their safety and long cycle life. Solid electrolytes (SEs) that exhibit hi…
View article: Simultaneous improvement of mechanical strength and electrical conductivity in Al-2.5 wt% Fe alloy rods with high thermal stability by high-pressure torsion extrusion
Simultaneous improvement of mechanical strength and electrical conductivity in Al-2.5 wt% Fe alloy rods with high thermal stability by high-pressure torsion extrusion Open
View article: High quality superconducting tantalum resonators with beta phase defects
High quality superconducting tantalum resonators with beta phase defects Open
For practical superconducting quantum processors, orders of magnitude improvement in coherence is required, motivating efforts to optimize hardware design and explore new materials. Among the latter, the coherence of superconducting transm…
View article: Nanocolumnar Zrcu Thin Film Metallic Glass with Tailored Mechanical and Electrical Properties
Nanocolumnar Zrcu Thin Film Metallic Glass with Tailored Mechanical and Electrical Properties Open
View article: Printed High‐Entropy Prussian Blue Analogs for Advanced Non‐Volatile Memristive Devices
Printed High‐Entropy Prussian Blue Analogs for Advanced Non‐Volatile Memristive Devices Open
Non‐volatile memristors dynamically switch between high (HRS) and low resistance states (LRS) in response to electrical stimuli, essential for electronic memories, neuromorphic computing, and artificial intelligence. High‐entropy Prussian …
View article: Photonic Synthesis and Coating of High‐Entropy Oxide on Layered Ni‐Rich Cathode Particles
Photonic Synthesis and Coating of High‐Entropy Oxide on Layered Ni‐Rich Cathode Particles Open
View article: Air cleaner prototype: Reduction of airborne viruses and effects of UV-C irradiation on virus concentration and RNA copy numbers considering modeled residence times and doses
Air cleaner prototype: Reduction of airborne viruses and effects of UV-C irradiation on virus concentration and RNA copy numbers considering modeled residence times and doses Open
View article: Layered high-entropy sulfides: boosting electrocatalytic performance for hydrogen evolution reaction by cocktail effects
Layered high-entropy sulfides: boosting electrocatalytic performance for hydrogen evolution reaction by cocktail effects Open
This study explores high-entropy sulfides (HESs) as potential electrocatalysts for the hydrogen evolution reaction (HER). Novel Pa -3 and Pnma structured HESs containing Fe, Mn, Ni, Co and Mo, were synthesized via a facile mechanochemical …
View article: Photonic Synthesis and Coating of High‐Entropy Oxide on Layered Ni‐Rich Cathode Particles
Photonic Synthesis and Coating of High‐Entropy Oxide on Layered Ni‐Rich Cathode Particles Open
High‐entropy materials have drawn much attention as battery materials due to their distinctive properties. Lithiated high‐entropy oxide (Li 0.33 (MgCoNiCuZn) 0.67 O, LiHEO) exhibits both high lithium‐ion and electronic conductivity, making…
View article: Using the High-Entropy Approach to Obtain Multimetal Oxide Nanozymes: Library Synthesis, <i>In Silico</i> Structure–Activity, and Immunoassay Performance
Using the High-Entropy Approach to Obtain Multimetal Oxide Nanozymes: Library Synthesis, <i>In Silico</i> Structure–Activity, and Immunoassay Performance Open
High-entropy nanomaterials exhibit exceptional mechanical, physical, and chemical properties, finding applications in many industries. Peroxidases are metalloenzymes that accelerate the decomposition of hydrogen peroxide. This study uses t…
View article: K‐Doping Suppresses Oxygen Redox in P2‐Na<sub>0.67</sub>Ni<sub>0.11</sub>Cu<sub>0.22</sub>Mn<sub>0.67</sub>O<sub>2</sub> Cathode Materials for Sodium‐Ion Batteries
K‐Doping Suppresses Oxygen Redox in P2‐Na<sub>0.67</sub>Ni<sub>0.11</sub>Cu<sub>0.22</sub>Mn<sub>0.67</sub>O<sub>2</sub> Cathode Materials for Sodium‐Ion Batteries Open
In P2‐type layered oxide cathodes, Na site‐regulation strategies are proposed to modulate the Na + distribution and structural stability. However, their impact on the oxygen redox reactions remains poorly understood. Herein, the incorporat…
View article: Overcoming plasticity reduction in a severely deformed nano-grained metastable alloy
Overcoming plasticity reduction in a severely deformed nano-grained metastable alloy Open
Most bulk metallic materials reveal an increased strength but a loss of ductility after cold deformation, a phenomenon known as the strength–ductility trade-off. In this study, we propose a strategy to overcome this problem by introducing …
View article: Processing of high-strength thermal-resistant Al-2.2% cerium-1.3% lanthanum alloy rods with high electric conductivity by High Pressure Torsion Extrusion
Processing of high-strength thermal-resistant Al-2.2% cerium-1.3% lanthanum alloy rods with high electric conductivity by High Pressure Torsion Extrusion Open
A novel severe plastic deformation (SPD) process of High Pressure Torsion Extrusion (HPTE) was applied to the rods of the Al-2.2 wt.% Ce-1.3 wt.% La (Al–3.5RE) alloy. The microstructure, microhardness, the mechanical strength, thermal stab…
View article: Influence of Zr-doping on the structure and transport properties of rare earth high-entropy oxides
Influence of Zr-doping on the structure and transport properties of rare earth high-entropy oxides Open
Fluorite-type ceria-based ceramics are well established as oxygen ion conductors due to their high conductivity, superseding state-of-the-art electrolytes such as yttria-stabilized zirconia. However, at a specific temperature and oxygen pa…
View article: Elucidation of the Transport Properties of Calcium‐Doped High Entropy Rare Earth Aluminates for Solid Oxide Fuel Cell Applications
Elucidation of the Transport Properties of Calcium‐Doped High Entropy Rare Earth Aluminates for Solid Oxide Fuel Cell Applications Open
Solid oxide fuel cells (SOFCs) are paving the way to clean energy conversion, relying on efficient oxygen‐ion conductors with high ionic conductivity coupled with a negligible electronic contribution. Doped rare earth aluminates are promis…
View article: Demystifying the Semiconductor‐to‐Metal Transition in Amorphous Vanadium Pentoxide: The Role of Substrate/Thin Film Interfaces
Demystifying the Semiconductor‐to‐Metal Transition in Amorphous Vanadium Pentoxide: The Role of Substrate/Thin Film Interfaces Open
The precise mechanism governing the reversible semiconductor‐to‐metal transition (SMT) in V 2 O 5 remains elusive, yet its investigation is of paramount importance due to the remarkable potential of V 2 O 5 as a versatile “smart” material …
View article: Improved Performance of High‐Entropy Disordered Rocksalt Oxyfluoride Cathode by Atomic Layer Deposition Coating for Li‐Ion Batteries
Improved Performance of High‐Entropy Disordered Rocksalt Oxyfluoride Cathode by Atomic Layer Deposition Coating for Li‐Ion Batteries Open
Lithium‐excess cation‐disordered rocksalt materials are a promising class of transition metal‐based cathodes that exhibit high specific capacity and energy density. The exceptional performance is achieved through participation of anionic r…
View article: Cover Picture: Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries (Angew. Chem. Int. Ed. 7/2024)
Cover Picture: Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries (Angew. Chem. Int. Ed. 7/2024) Open
Angewandte Chemie International Edition is one of the prime chemistry journals in the world, publishing research articles, highlights, communications and reviews across all areas of chemistry.
View article: Titelbild: Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries (Angew. Chem. 7/2024)
Titelbild: Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries (Angew. Chem. 7/2024) Open
Graphical Abstract The high-entropy approach is applied to a monoclinic Prussian white material, introducing an innovative concept for developing robust cathodes for use in Na-ion batteries. In their Research Article (e202315371), Torsten …
View article: Developing of superconducting RF guns at BNL
Developing of superconducting RF guns at BNL Open
BNL is developing several superconducting RF guns for different applications. The first gun is based on a half-cell 1.3 GHz elliptical cavity. This gun is used to study generation of polarized electrons from GaAs photocathodes. The second …
View article: Fine structure tuning for strongly correlated functionalities in high entropy oxides
Fine structure tuning for strongly correlated functionalities in high entropy oxides Open
View article: In-situ/ Opernado (S)TEM on Mass Selected Pt Clusters Deposited on CeO2 for CO Oxidation Catalysis
In-situ/ Opernado (S)TEM on Mass Selected Pt Clusters Deposited on CeO2 for CO Oxidation Catalysis Open
View article: Enhanced diffusion in thin-film Cu-Zr nanoglasses
Enhanced diffusion in thin-film Cu-Zr nanoglasses Open
Tracer measurements with both radioactive, 55Fe, as well as natural, mainly 56Fe, isotopes are used to investigate Fe diffusion in a Cu-Zr nanoglass in comparison to their diffusion rates in a homogeneous amorphous counterpart. The columna…
View article: Voltage-driven 90 switching of bulk perpendicular magnetic anisotropy in ferrimagnets
Voltage-driven 90 switching of bulk perpendicular magnetic anisotropy in ferrimagnets Open
Unravelling the mechanism behind bulk perpendicular magnetic anisotropy (PMA) in amorphous rare earth-transition metal films has proven challenging. This is largely due to the inherent complexity of amorphous structure and the entangled po…
View article: Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries
Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries Open
The high‐entropy approach is applied to monoclinic Prussian White (PW) Na‐ion cathodes to address the issue of unfavorable multilevel phase transitions upon electrochemical cycling, leading to poor stability and capacity decay. A series of…
View article: Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries
Entropy‐Mediated Stable Structural Evolution of Prussian White Cathodes for Long‐Life Na‐Ion Batteries Open
The high‐entropy approach is applied to monoclinic Prussian White (PW) Na‐ion cathodes to address the issue of unfavorable multilevel phase transitions upon electrochemical cycling, leading to poor stability and capacity decay. A series of…
View article: Nanoscale Confinement of Dip‐Pen Nanolithography Written Phospholipid Structures on CuZr Nanoglasses
Nanoscale Confinement of Dip‐Pen Nanolithography Written Phospholipid Structures on CuZr Nanoglasses Open
Nanoglasses have attracted considerable interest among material scientists due to their novel and surprising properties. However, there is still a significant gap in understanding how nanoglasses interact with biomaterials and their effect…
View article: In situ TEM studies of relaxation dynamics and crystal nucleation in thin film nanoglasses
In situ TEM studies of relaxation dynamics and crystal nucleation in thin film nanoglasses Open
Crystallization processes of glass-glass interfaces in sputtered CuZr thin film nanoglasses were directly studied using in situ heating experiments in a transmission electron microscope (TEM). By combining the in situ technique with a soph…
View article: High‐Entropy Sulfides as Highly Effective Catalysts for the Oxygen Evolution Reaction
High‐Entropy Sulfides as Highly Effective Catalysts for the Oxygen Evolution Reaction Open
Oxygen Evolution Reaction As a newly developed class of materials, high entropy sulphides (HES) are promising electrocatalysts for a variety of different reactions. In article 2300012, Ben Breitung, Simon Schweidler, and co-workers investi…
View article: Synthesis of Free‐Standing Pd‐Ni‐P Metallic Glass Nanoparticles with Durable Medium‐Range Ordered Structure for Enhanced Electrocatalytic Properties (Small 33/2023)
Synthesis of Free‐Standing Pd‐Ni‐P Metallic Glass Nanoparticles with Durable Medium‐Range Ordered Structure for Enhanced Electrocatalytic Properties (Small 33/2023) Open
Metallic Glass Nanoparticles During the synthesis of free-standing metallic glass nanoparticles with laser-evaporated inert-gas condensation, metallic atoms, and distorted short-range-order (SRO) clusters are evaporated to collide and coal…