Thomas E. Albrecht‐Schmitt
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View article: Recent Advances in Rare Earth Element Recovery: Liquid–Liquid Extraction and Magnetophoretic Separation
Recent Advances in Rare Earth Element Recovery: Liquid–Liquid Extraction and Magnetophoretic Separation Open
The unique physicochemical properties of rare earth elements (REEs) make them imperative for the production and improvement of advanced technology, renewable energy, and national defense applications. As these fields rapidly develop, there…
View article: Structural complexity in the <i>f</i> -block: small deviations of the complexation of lanthanides by <i>O,Oʹ</i> -diethylmonothiophosphate
Structural complexity in the <i>f</i> -block: small deviations of the complexation of lanthanides by <i>O,Oʹ</i> -diethylmonothiophosphate Open
View article: Non–linear bonding trends in maleonitrile-1,2–dithiolate complexes of the transuranium actinides
Non–linear bonding trends in maleonitrile-1,2–dithiolate complexes of the transuranium actinides Open
View article: Synthesis, Crystal Structure, and Optical Properties of the Barium <i>meta</i>-Pertechnetate Ba[TcO<sub>4</sub>]<sub>2</sub>
Synthesis, Crystal Structure, and Optical Properties of the Barium <i>meta</i>-Pertechnetate Ba[TcO<sub>4</sub>]<sub>2</sub> Open
High-quality single crystals of the colorless title compound Ba[99TcO4]2 were prepared from radioactive, isotope-pure 99TcO2 by oxidation with H2O2 in an aqueous …
View article: High-Pressure Effects on an Octa-Hydrated Curium Complex: An Experimental and Theoretical Investigation
High-Pressure Effects on an Octa-Hydrated Curium Complex: An Experimental and Theoretical Investigation Open
An octa-hydrated curium compound [Cm(H2O)8](Hdtp)(dtp)·H2O (Cm1, H2dtp = 2,3-di(tetrazol-5-yl)pyrazine) along with its lanthanide analogues [Ln(H2O)8](Hdtp)(dtp)·H
View article: Synthesis and Characterization of Homo- and Heteroleptic Neptunium(IV) Heteroarylalkenolate Complexes
Synthesis and Characterization of Homo- and Heteroleptic Neptunium(IV) Heteroarylalkenolate Complexes Open
Heteroleptic AnIV (An = U, Np) chlorido-ketoenaminate complexes of the type [AnCl2(TFB-tBuA)2(THF)] (An-1 type: U-1, Np-1; TFB-tBuA = 4-(tert-butylamino)-1,1,1-trif…
View article: A comprehensive approach for elucidating the interplay between 4f<sup><i>n</i>+1</sup> and 4f<sup><i>n</i></sup>5d<sup>1</sup> configurations in Ln<sup>2+</sup> complexes
A comprehensive approach for elucidating the interplay between 4f<sup><i>n</i>+1</sup> and 4f<sup><i>n</i></sup>5d<sup>1</sup> configurations in Ln<sup>2+</sup> complexes Open
To advance our ability to control the electronic properties of divalent lanthanides, the interplay between deformation densities, 4f interelectronic repulsion, and ligand field effects is discussed to predict the nature of their ground sta…
View article: Unveiling the covalency of versatile Pu(iii)-N bonds in a unique plutonium(iii) complex
Unveiling the covalency of versatile Pu(iii)-N bonds in a unique plutonium(iii) complex Open
This study shows that negatively charged tetrazolate nitrogen atoms enhance Pu–N electrostatic interactions and shorten Pu–N bond lengths, leading to greater orbital overlap and covalent character compared to Pu–N bonds with neutral nitrog…
View article: Comprehensive Analysis of Pseudo-Octahedral Lanthanide(III) and Uranium(IV and VI) Tri-(3,5-Dimethoxyphenyl)phosphine Oxide Complexes
Comprehensive Analysis of Pseudo-Octahedral Lanthanide(III) and Uranium(IV and VI) Tri-(3,5-Dimethoxyphenyl)phosphine Oxide Complexes Open
View article: Correction: A comprehensive approach for elucidating the interplay between 4f<sup><i>n</i>+1</sup> and 4f<sup><i>n</i></sup>5d<sup>1</sup> configurations in Ln<sup>2+</sup> complexes
Correction: A comprehensive approach for elucidating the interplay between 4f<sup><i>n</i>+1</sup> and 4f<sup><i>n</i></sup>5d<sup>1</sup> configurations in Ln<sup>2+</sup> complexes Open
Correction for ‘A comprehensive approach for elucidating the interplay between 4f n +1 and 4f n 5d 1 configurations in Ln 2+ complexes’ by Maria J. Beltran-Leiva et al. , Chem. Sci ., 2025, 16 , 2024–2033, https://doi.org/10.1039/d4sc05438…
View article: Smooth trends in fermium charge radii and the impact of shell effects
Smooth trends in fermium charge radii and the impact of shell effects Open
View article: Comprehensive Synthesis and Structural Trends in Tetramethyl Diglycolamide (TMDGA) Nitrate Complexes with Lanthanides and Americium
Comprehensive Synthesis and Structural Trends in Tetramethyl Diglycolamide (TMDGA) Nitrate Complexes with Lanthanides and Americium Open
Complexes of N,N,N',N'-tetramethyl diglycolamide (TMDGA), a hydrophilic diglycolamide (DGA) proposed as an aqueous phase holdback reagent, have been crystallized for the majority of the lanthanide series (excluding promethium), yttrium, an…
View article: Center For Actinide Science and Technology (CAST)
Center For Actinide Science and Technology (CAST) Open
CAST encompassed 17 senior researchers in its first funding cycle and added two additional theorists briefly in the final two years. Approximately 37 graduate students and post-doctoral associates were supported by CAST. Within the 19 seni…
View article: U(V) Stabilization via Aliovalent Incorporation of Ln(III) into Oxo‐salt Framework
U(V) Stabilization via Aliovalent Incorporation of Ln(III) into Oxo‐salt Framework Open
Pentavalent uranium compounds are key components of uranium‘s redox chemistry and play important roles in environmental transport. Despite this, well‐characterized U(V) compounds are scarce primarily because of their instability with respe…
View article: Comparison of Americium(III) and Neodymium(III) Monothiophosphate Complexes
Comparison of Americium(III) and Neodymium(III) Monothiophosphate Complexes Open
Mixed-donor ligands, such as those containing a combination of O/N or O/S, have been studied extensively for the selective extraction of trivalent actinides, especially Am3+ and Cm3+, from lanthanides during the recyc…
View article: Correction to “Chemical Kinetics for the Oxidation of Californium(III) Ions with Select Radiation-Induced Inorganic Radicals (Cl<sub>2</sub><sup>•–</sup> and SO<sub>4</sub><sup>•–</sup>)”
Correction to “Chemical Kinetics for the Oxidation of Californium(III) Ions with Select Radiation-Induced Inorganic Radicals (Cl<sub>2</sub><sup>•–</sup> and SO<sub>4</sub><sup>•–</sup>)” Open
ADVERTISEMENT RETURN TO ISSUEPREVAddition/CorrectionNEXTORIGINAL ARTICLEThis notice is a correctionCorrection to "Chemical Kinetics for the Oxidation of Californium(III) Ions with Select Radiation-Induced Inorganic Radicals (Cl2•– and SO4•…
View article: Frontier Actinide Radiation Chemistry
Frontier Actinide Radiation Chemistry Open
View article: Chemical Kinetics for the Oxidation of Californium(III) Ions with Select Radiation-Induced Inorganic Radicals (Cl<sub>2</sub><sup>•–</sup> and SO<sub>4</sub><sup>•–</sup>)
Chemical Kinetics for the Oxidation of Californium(III) Ions with Select Radiation-Induced Inorganic Radicals (Cl<sub>2</sub><sup>•–</sup> and SO<sub>4</sub><sup>•–</sup>) Open
Despite the availability of transuranic elements increasing in recent years, our understanding of their most basic and inherent radiation chemistry is limited and yet essential for the accurate interpretation of their physical and chemical…
View article: A new chapter in chemistry
A new chapter in chemistry Open
View article: CCDC 2265396: Experimental Crystal Structure Determination
CCDC 2265396: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265399: Experimental Crystal Structure Determination
CCDC 2265399: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265397: Experimental Crystal Structure Determination
CCDC 2265397: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265398: Experimental Crystal Structure Determination
CCDC 2265398: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265402: Experimental Crystal Structure Determination
CCDC 2265402: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265401: Experimental Crystal Structure Determination
CCDC 2265401: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265400: Experimental Crystal Structure Determination
CCDC 2265400: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2284164: Experimental Crystal Structure Determination
CCDC 2284164: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265395: Experimental Crystal Structure Determination
CCDC 2265395: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2236793: Experimental Crystal Structure Determination
CCDC 2236793: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Characterization of the Organoamericium Complex Cp′<sub>3</sub>Am
Characterization of the Organoamericium Complex Cp′<sub>3</sub>Am Open
Here, in this paper, we report the synthesis and structural characterization as well as solid- and solution-phase studies of Cp'3Am (Cp'– = trimethylsilylcyclopentadienide). The addition of KCp' to AmBr3(DME)2