Thomas Weyhermüller
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View article: CCDC 2418227: Experimental Crystal Structure Determination
CCDC 2418227: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Multicomponent Electrosynthesis of Enaminyl Sulfonates Starting from Alkylamines, SO<sub>2</sub>, and Alcohols
Multicomponent Electrosynthesis of Enaminyl Sulfonates Starting from Alkylamines, SO<sub>2</sub>, and Alcohols Open
An electrochemical one-pot synthesis of enaminyl sulfonate esters was established, featuring a quasidivided cell under constant current conditions. The multicomponent reaction utilizes simple and readily available alkylamines and an easy-t…
View article: Electrochemical aldehyde hydrogenation: probing the inner-sphere strategy with nickel-bipyridine complexes
Electrochemical aldehyde hydrogenation: probing the inner-sphere strategy with nickel-bipyridine complexes Open
An inner-sphere approach to aldehyde electrohydrogenation leads to a key nickeloxirane. Protonation of that intermediate yields the hydrogenation products, but electrocatalysis remains challenging.
View article: Experimentally Assessing the Electronic Structure and Spin-State Energetics in MnFe Dimers Using 1s3p Resonant Inelastic X-ray Scattering
Experimentally Assessing the Electronic Structure and Spin-State Energetics in MnFe Dimers Using 1s3p Resonant Inelastic X-ray Scattering Open
The synergistic interaction between Mn and Fe centers is investigated via a comprehensive analysis of full 1s3p resonant inelastic X-ray scattering (RIXS) planes at both the Fe and Mn K-edges in a series of homo- and heterometallic molecul…
View article: Controlling hydrogen transfer dynamics in adaptive semihydrogenation of alkynes: Unveiling and directing outer- vs. inner-sphere mechanisms
Controlling hydrogen transfer dynamics in adaptive semihydrogenation of alkynes: Unveiling and directing outer- vs. inner-sphere mechanisms Open
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View article: The spin-forbidden transition in iron(IV)-oxo catalysts relevant to two-state reactivity
The spin-forbidden transition in iron(IV)-oxo catalysts relevant to two-state reactivity Open
Quintet oxoiron(IV) intermediates are often invoked in nonheme iron enzymes capable of performing selective oxidation, while most well-characterized synthetic model oxoiron(IV) complexes have a triplet ground state. These differing spin st…
View article: Understanding Ligand Effects on Bielectronic Transitions: Chemo‐ and Electroreduction of Rhodium Bis(Diphosphine) Complexes to Low Oxidation States
Understanding Ligand Effects on Bielectronic Transitions: Chemo‐ and Electroreduction of Rhodium Bis(Diphosphine) Complexes to Low Oxidation States Open
Rhodium complexes in the −I and 0 oxidation states are of great potential interest in catalytic applications. In contrast to their rhodium +I congeners, however, the structural and electronic parameters governing their access and stability…
View article: Understanding Ligand Effects on Bielectronic Transitions: Chemo‐ and Electroreduction of Rhodium Bis(Diphosphine) Complexes to Low Oxidation States
Understanding Ligand Effects on Bielectronic Transitions: Chemo‐ and Electroreduction of Rhodium Bis(Diphosphine) Complexes to Low Oxidation States Open
Rhodium complexes in the −I and 0 oxidation states are of great potential interest in catalytic applications. In contrast to their rhodium +I congeners, however, the structural and electronic parameters governing their access and stability…
View article: CCDC 2280989: Experimental Crystal Structure Determination
CCDC 2280989: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2169091: Experimental Crystal Structure Determination
CCDC 2169091: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2169090: Experimental Crystal Structure Determination
CCDC 2169090: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2169092: Experimental Crystal Structure Determination
CCDC 2169092: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Cooperative Cobalt-Driven System for One-Carbon Extension in the Synthesis of (<i>Z</i>)-Silyl Enol Ethers from Aldehydes: Unlocking Regio- and Stereoselectivity
A Cooperative Cobalt-Driven System for One-Carbon Extension in the Synthesis of (<i>Z</i>)-Silyl Enol Ethers from Aldehydes: Unlocking Regio- and Stereoselectivity Open
The research presented herein explores a cobalt-based catalytic system, distinctively featuring a cooperative boron-centric element within its intricate ligand architecture. This system is strategically engineered to enable the integration…
View article: Activated Mn‐MACHO Complexes Form Stable CO<sub>2</sub> Adducts
Activated Mn‐MACHO Complexes Form Stable CO<sub>2</sub> Adducts Open
Manganese(I) carbonyl complexes bearing a MACHO‐type ligand (HN(CH 2 CH 2 PR 2 ) 2 ) readily react in their amido form with CO 2 to generate 4‐membered {Mn−N−C−O} metallacycles. The stability of the adducts decreases with the steric demand…
View article: CCDC 2226437: Experimental Crystal Structure Determination
CCDC 2226437: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Hydride-Free Hydrogenation: Unraveling the Mechanism of Electrocatalytic Alkyne Semihydrogenation by Nickel–Bipyridine Complexes
Hydride-Free Hydrogenation: Unraveling the Mechanism of Electrocatalytic Alkyne Semihydrogenation by Nickel–Bipyridine Complexes Open
Hydrogenation reactions of carbon-carbon unsaturated bonds are central in synthetic chemistry. Efficient catalysis of these reactions classically recourses to heterogeneous or homogeneous transition-metal species. Whether thermal or electr…
View article: Inside Cover: A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes (Angew. Chem. Int. Ed. 23/2023)
Inside Cover: A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes (Angew. Chem. Int. Ed. 23/2023) Open
Two cooperative robotic arms [Rh/P(O)nBu2] are in the process of activating and breaking C−F bonds to create C−H bonds. In their Research Article (e202219127), Christophe Werlé and co-workers developed a molecular template based on these d…
View article: CCDC 2220405: Experimental Crystal Structure Determination
CCDC 2220405: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2117074: Experimental Crystal Structure Determination
CCDC 2117074: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2117073: Experimental Crystal Structure Determination
CCDC 2117073: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2181638: Experimental Crystal Structure Determination
CCDC 2181638: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2181637: Experimental Crystal Structure Determination
CCDC 2181637: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2110200: Experimental Crystal Structure Determination
CCDC 2110200: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes
A Cooperative Rhodium/Secondary Phosphine Oxide [Rh/P(O)<i>n</i>Bu<sub>2</sub>] Template for Catalytic Hydrodefluorination of Perfluoroarenes Open
The selective activation of C−F bonds under mild reaction conditions remains an ongoing challenge of bond activation. Here, we present a cooperative [Rh/P(O) n Bu 2 ] template for catalytic hydrodefluorination (HDF) of perfluoroarenes. In …
View article: CCDC 2212977: Experimental Crystal Structure Determination
CCDC 2212977: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212976: Experimental Crystal Structure Determination
CCDC 2212976: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212975: Experimental Crystal Structure Determination
CCDC 2212975: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Sulfur-Ligated [2Fe-2C] Clusters as Synthetic Model Systems for Nitrogenase
Sulfur-Ligated [2Fe-2C] Clusters as Synthetic Model Systems for Nitrogenase Open
Metal clusters featuring carbon and sulfur donors have coordination environments comparable to the active site of nitrogenase enzymes. Here, we report a series of di-iron clusters supported by the dianionic yldiide ligands, in which the Fe…
View article: CCDC 2190208: Experimental Crystal Structure Determination
CCDC 2190208: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2190210: Experimental Crystal Structure Determination
CCDC 2190210: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …