Tim Gitzinger
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View article: Abrupt Change from Ionic to Covalent Bonding in Nickel Halides Accompanied by Ligand Field Inversion
Abrupt Change from Ionic to Covalent Bonding in Nickel Halides Accompanied by Ligand Field Inversion Open
The electronic configuration of transition metal centers and their ligands is crucial for redox reactions in metal catalysis and electrochemistry. We characterize the electronic structure of gas-phase nickel monohalide cations via nickel L…
View article: Electronic Structure of the Complete Series of Gas-Phase Manganese Acetylacetonates by X-ray Absorption Spectroscopy
Electronic Structure of the Complete Series of Gas-Phase Manganese Acetylacetonates by X-ray Absorption Spectroscopy Open
Metal centers in transition metal-ligand complexes occur in a variety of oxidation states causing their redox activity and therefore making them relevant for applications in physics and chemistry. The electronic state of these complexes ca…
View article: Iron L<sub>3</sub>-edge energy shifts for the full range of possible 3d occupations within the same oxidation state of iron halides
Iron L<sub>3</sub>-edge energy shifts for the full range of possible 3d occupations within the same oxidation state of iron halides Open
Chemical shift spread of 420meV of formally identical metal centers solely induced by change in metal 3d occupation.