Timothée M. Petitjean
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View article: Two-Step Constitutional Isomerization of Saturated Cyclic Amines Using Borane Catalysis
Two-Step Constitutional Isomerization of Saturated Cyclic Amines Using Borane Catalysis Open
The prevalence of saturated azacycles within pharmaceuticals, natural products, and agrochemicals has prompted the development of many methods that modify their periphery. In contrast, technologies that interconvert distinct saturated azac…
View article: Reductive Amination of Carbonyl C–C Bonds Enables Formal Nitrogen Insertion
Reductive Amination of Carbonyl C–C Bonds Enables Formal Nitrogen Insertion Open
Given its relevance across numerous fields, reductive amination is one of the oldest and most widely used methods for amine synthesis. As a cornerstone of synthetic chemistry, it has largely remained unchanged since its discovery over a ce…
View article: Reductive amination of carbonyl C–C bonds enables formal nitrogen insertion
Reductive amination of carbonyl C–C bonds enables formal nitrogen insertion Open
Given its ubiquity in various biological and physical processes1–3, the reductive amination of ketones and aldehydes is one of the oldest and most widely used methods for amine synthesis4. As a cornerstone of synthetic chemistry, it has la…