Tongling Liang
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View article: Effect of chloride substitution on the performance of a benzhydryl-substituted bis(arylimino)pyridyl–cobalt ethylene polymerization catalyst
Effect of chloride substitution on the performance of a benzhydryl-substituted bis(arylimino)pyridyl–cobalt ethylene polymerization catalyst Open
To address the impact of chloride substitution on the performance of a benzhydryl-substituted bis(arylimino)pyridyl–cobalt ethylene polymerization catalyst, this work reports a new family of unsymmetrical N' , N' , N'' -cobalt(II) chloride…
View article: Synergistic regulation of metal–organic cage architectures via temperature- and solvent-driven atropisomerism
Synergistic regulation of metal–organic cage architectures via temperature- and solvent-driven atropisomerism Open
Regulating multistimulus responses in artificial systems remains a challenge in smart material development. We present a versatile chemical switching system that precisely controls the self-assembly of metal–organic cages via temperature a…
View article: Molecular Geometry‐Property Relationship of Benzodipyrrole‐Based A‐DA'D‐A Type Acceptors for High‐Performance Organic Solar Cells
Molecular Geometry‐Property Relationship of Benzodipyrrole‐Based A‐DA'D‐A Type Acceptors for High‐Performance Organic Solar Cells Open
Molecular geometry plays a crucial role in determining the physical and chemical properties of organic semiconductor materials. However, there is little research on the molecular geometry‐property relationship of A‐DA'D‐A type small molecu…
View article: Achieving Dynamic Circularly Polarized Luminescence with 2D Hydrogen‐Bonded Organic Frameworks
Achieving Dynamic Circularly Polarized Luminescence with 2D Hydrogen‐Bonded Organic Frameworks Open
Significant advances have been made in the preparation and application of luminescent hydrogen‐bonded organic frameworks (HOFs) in recent years. These materials exhibit unique structural flexibility in accommodating guest molecules, render…
View article: An Organic–Inorganic Hybrid Semiconducting Quantum Spin Liquid Candidate: (BEDT-TTF)3[Cu2(μ-C2O4)3·CH3CH2OH·1.2H2O]
An Organic–Inorganic Hybrid Semiconducting Quantum Spin Liquid Candidate: (BEDT-TTF)3[Cu2(μ-C2O4)3·CH3CH2OH·1.2H2O] Open
The organic–inorganic hybrid (BEDT-TTF)3[Cu2(μ-C2O4)3·CH3CH2OH·1.2H2O] (I) was obtained using the electrocrystallization method. It comprises a θ21-phase organic donor layer and a two-dimensional inorganic antiferromagnetic honeycomb latti…
View article: Asymmetric small-molecule acceptor enables suppressed electron-vibration coupling and minimized driving force for organic solar cells
Asymmetric small-molecule acceptor enables suppressed electron-vibration coupling and minimized driving force for organic solar cells Open
Minimizing the energy loss, particularly the non-radiative energy loss (Δ E nr ), without sacrificing the charge collection efficiency, is the key to further improve the photovoltaic performance of organic solar cells (OSCs). Herein, we pr…
View article: Dynamic hydrogen-bonding enables high-performance and mechanically robust organic solar cells processed with non-halogenated solvent
Dynamic hydrogen-bonding enables high-performance and mechanically robust organic solar cells processed with non-halogenated solvent Open
Developing active-layer systems with both high performance and mechanical robustness is a crucial step towards achieving future commercialization of flexible and stretchable organic solar cells (OSCs). Herein, we design and synthesize a se…
View article: Modulation of 2-imino-6,7-dihydroquinlin-8(5<i>H</i>)-imine-iron ethylene polymerization catalysts through (cyclo)alkyl, benzhydryl and halide substitution
Modulation of 2-imino-6,7-dihydroquinlin-8(5<i>H</i>)-imine-iron ethylene polymerization catalysts through (cyclo)alkyl, benzhydryl and halide substitution Open
The depicted benzhydryl-containing Fe catalysts appended with ortho -C n H 2 n −1 ( n = 5, 6, 8) and ortho -halide groups, showed high activity/thermostability for C 2 H 4 polymerization.
View article: High molecular weight polyethylene <i>via</i> the spatial proximity of benzosuberyl in iminopyridine nickel catalysts
High molecular weight polyethylene <i>via</i> the spatial proximity of benzosuberyl in iminopyridine nickel catalysts Open
Iminopyridine nickel catalysts are typically gave low molecular weight PE. Upon activation with MAO, the prepared nickel complexes exhibited significantly high molecular weights PE of 56–182 kg mol −1 with narrower dispersity of 1.5–1.8.
View article: Fluoro- & trifluoromethoxy-modified bis(imino)pyridyliron chloride enhancing the activity and stability of vinyl polyethylenes
Fluoro- & trifluoromethoxy-modified bis(imino)pyridyliron chloride enhancing the activity and stability of vinyl polyethylenes Open
High-performance multi-fluorine-substituted bis(imino)pyridyl Fe catalysts for ethylene polymerization achieve peak activity of 17.28 × 10 6 g (PE) mol −1 (Fe) h −1 at 70 °C showing excellent thermal stability and producing tailored-MW lin…
View article: Correction: Axial-phenyl-constrained bis(imino)acenaphthene-nickel precatalysts enhance ethylene polymerization
Correction: Axial-phenyl-constrained bis(imino)acenaphthene-nickel precatalysts enhance ethylene polymerization Open
Correction for ‘Axial-phenyl-constrained bis(imino)acenaphthene-nickel precatalysts enhance ethylene polymerization’ by Quanchao Wang et al. , Polym. Chem. , 2024, https://doi.org/10.1039/d4py01110d.
View article: An Organic-Inorganic Hybrid Semiconducting Quantum Spin Liquid Candidate: (BEDT-TTF)<sub>3</sub>[Cu<sub>2</sub>(m-C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·2CH<sub>3</sub>CH<sub>2</sub>OH
An Organic-Inorganic Hybrid Semiconducting Quantum Spin Liquid Candidate: (BEDT-TTF)<sub>3</sub>[Cu<sub>2</sub>(m-C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>]·2CH<sub>3</sub>CH<sub>2</sub>OH Open
The organic-inorganic hybrid (BEDT-TTF)3[Cu2(m-C2O4)3]·2CH3CH2OH (I)was synthesized using the electrocrystallization method. It composes q21-phase organic donor layer and an inorganic antiferromagnetic honeycomb lattice with the Jahn-Telle…
View article: Achieving Linear α-Macro-olefins in Ethylene Polymerization through Precisely Tuned Bis(imino)pyridylcobalt Precatalysts with Steric and Electronic Parameters
Achieving Linear α-Macro-olefins in Ethylene Polymerization through Precisely Tuned Bis(imino)pyridylcobalt Precatalysts with Steric and Electronic Parameters Open
Synthesis of functional polyethylene from ethylene alone is tricky and heavily dependent on both the type and structure of the precatalyst and the choice of cocatalyst used in the polymerization. In the present study, a series of cobalt pr…
View article: Light‐Up Fluorescence and Circularly Polarized Luminescence in Achiral Interlocked Framework via Adaptive Lone Pair‐π Interaction Confinement
Light‐Up Fluorescence and Circularly Polarized Luminescence in Achiral Interlocked Framework via Adaptive Lone Pair‐π Interaction Confinement Open
Interactions between lone pairs and aromatic π systems are significant across biology and self‐assembled materials. Herein, employing an achiral confinement metal–organic framework (MOF) encapsulates guest molecules, it is successfully rea…
View article: Controlled interconversion of macrocyclic atropisomers via defined intermediates
Controlled interconversion of macrocyclic atropisomers via defined intermediates Open
Macrocyclic conformations play a crucial role in regulating their properties. Our understanding of the determinants to control macrocyclic conformation interconversion is still in its infancy. Here we present a macrocycle, octamethyl cyclo…
View article: The Jahn-Teller Effect on One-dimensional Copper-Oxalate Framework Cu(μ-C<sub>2</sub>O<sub>4</sub>)[(CH<sub>3</sub>)<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)<sub>2</sub>]·4H<sub>2</sub>O
The Jahn-Teller Effect on One-dimensional Copper-Oxalate Framework Cu(μ-C<sub>2</sub>O<sub>4</sub>)[(CH<sub>3</sub>)<sub>2</sub>NCH<sub>2</sub>CH<sub>2</sub>N(CH<sub>3</sub>)<sub>2</sub>]·4H<sub>2</sub>O Open
A one-dimensional copper-oxalate framework is obtained. The Jahn-Teller distorted Cu(II) is octahedrally coordinated by four O from two bisbidentate oxalates and two N from one bidentate N, N, N’ N’-tetramethyldiamine and forms a one-dimen…
View article: CCDC 2307265: Experimental Crystal Structure Determination
CCDC 2307265: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2307267: Experimental Crystal Structure Determination
CCDC 2307267: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2307266: Experimental Crystal Structure Determination
CCDC 2307266: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2307264: Experimental Crystal Structure Determination
CCDC 2307264: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: C-shaped <i>ortho</i>-benzodipyrrole-based acceptors with different electronic effects of top substituents for as-cast green-solvent processed high-performance organic solar cells
C-shaped <i>ortho</i>-benzodipyrrole-based acceptors with different electronic effects of top substituents for as-cast green-solvent processed high-performance organic solar cells Open
We systematically investigated the effects of the top substituents on the physicochemical properties of SMAs and achieved the highest PCE for OSCs processed using a non-halogenated solvent without any extra treatment.
View article: Pentatomic carbon ring conjugated nitrogen-doped nanographene
Pentatomic carbon ring conjugated nitrogen-doped nanographene Open
A N-doped nanographene 1 was synthesized. Compared to the hexatomic carbon ring conjugated TB(phen), this study focuses on the effects corresponding to the pentatomic carbon ring conjugation and substituent group of 1 on the physical prope…
View article: CCDC 2277727: Experimental Crystal Structure Determination
CCDC 2277727: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285916: Experimental Crystal Structure Determination
CCDC 2285916: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285914: Experimental Crystal Structure Determination
CCDC 2285914: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2285915: Experimental Crystal Structure Determination
CCDC 2285915: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262894: Experimental Crystal Structure Determination
CCDC 2262894: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2262895: Experimental Crystal Structure Determination
CCDC 2262895: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: N,N-Bis(2,4-Dibenzhydryl-6-cycloalkylphenyl)butane-2,3-diimine–Nickel Complexes as Tunable and Effective Catalysts for High-Molecular-Weight PE Elastomers
N,N-Bis(2,4-Dibenzhydryl-6-cycloalkylphenyl)butane-2,3-diimine–Nickel Complexes as Tunable and Effective Catalysts for High-Molecular-Weight PE Elastomers Open
Four examples of N,N-bis(aryl)butane-2,3-diimine–nickel(II) bromide complexes, [ArN=C(Me)-C(Me)=NAr]NiBr2 (where Ar = 2-(C5H9)-4,6-(CHPh2)2C6H2 (Ni1), Ar = 2-(C6H11)-4,6-(CHPh2)2C6H2 (Ni2), 2-(C8H15)-4,6-(CHPh2)2C6H2 (Ni3) and 2-(C12H23)-4…
View article: CCDC 2237034: Experimental Crystal Structure Determination
CCDC 2237034: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …