Melanie Pilkington
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View article: The Diverse Reactivity of an Al(I) Carbenoid Towards Phosphorus‐Based Ylides. The Crucial Role of Co‐Crystallised Lithium Halide
The Diverse Reactivity of an Al(I) Carbenoid Towards Phosphorus‐Based Ylides. The Crucial Role of Co‐Crystallised Lithium Halide Open
Attempts to generate NacNacAl‐based (NacNac=[ArNC(Me)CHC(Me)NAr] − ; Ar=2,6‐ i Pr 2 C 6 H 3 ) alkylidenes via reactions with trimethyl(methylidene), triphenyl(methylidene) and triethyl(ethylidene) phosphiranes led to new and unexpected rea…
View article: Oxidative addition chemistry of bis(4,5-dimethoxybenzo)-1,2,5,6-tetrathiocin with cyclopentadienyl metal carbonyl complexes and the mechanochemical transformation of CpCo(dmobdt) to [CpCo(dmobdt)] <sub>2</sub>
Oxidative addition chemistry of bis(4,5-dimethoxybenzo)-1,2,5,6-tetrathiocin with cyclopentadienyl metal carbonyl complexes and the mechanochemical transformation of CpCo(dmobdt) to [CpCo(dmobdt)] <sub>2</sub> Open
Microwave-promoted oxidative addition of tetrathiocin 1 to CpCo(CO) 2 affords CpCo(dmobdt) which undergoes a mechanochemical transformation to [CpCo(dmobdt)] 2 .
View article: A Nanosized {Ni<sup>II</sup><sub>18</sub>} Cluster with a ‘Flying Saucer’ Topology Exhibiting Slow Relaxation of Magnetisation Phenomena at Both 15 K and 1.3 K
A Nanosized {Ni<sup>II</sup><sub>18</sub>} Cluster with a ‘Flying Saucer’ Topology Exhibiting Slow Relaxation of Magnetisation Phenomena at Both 15 K and 1.3 K Open
A high‐nuclearity {Ni 18 } complex ( 1 ) with a unique ‘flying saucer’ motif has been prepared from the organic chelate, α‐methyl‐2‐pyridine‐methanol (mpmH), in conjunction with bridging azido (N 3 − ) and peroxido (O 2 2− ) ligands. Magne…
View article: A Spontaneous Magnetic Moment in an Organic Radical: Synthesis and Characterization of Benzodioxepinyl-1,3,2-dithiazolyl
A Spontaneous Magnetic Moment in an Organic Radical: Synthesis and Characterization of Benzodioxepinyl-1,3,2-dithiazolyl Open
The synthesis of the 1,3,2-dithiazolyl radical (1) derived from 3,4-dihydro-2H-1,5-benzodioxepine is described. Crystals of 1 were grown by vacuum sublimation and adopt the orthorhombic space group Pbca. DC SQUID magnetometry reveals Curie…
View article: Reversible Coupling of Germylone with Isocyanates
Reversible Coupling of Germylone with Isocyanates Open
The germylone dimNHCGe ( 5 , dimNHC=diimino N‐heterocyclic carbene) undergoes a [2+2] cycloaddition with isocyanates RNCO (R=4‐tolyl or 3,5‐xylyl) to furnish novel alkyl carboxamido germylenes 7 (R=4‐tolyl) and 8 (R=3,5‐xylyl), featuring a…
View article: CCDC 2289717: Experimental Crystal Structure Determination
CCDC 2289717: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2289718: Experimental Crystal Structure Determination
CCDC 2289718: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2289716: Experimental Crystal Structure Determination
CCDC 2289716: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2243039: Experimental Crystal Structure Determination
CCDC 2243039: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2243038: Experimental Crystal Structure Determination
CCDC 2243038: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2243036: Experimental Crystal Structure Determination
CCDC 2243036: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2243035: Experimental Crystal Structure Determination
CCDC 2243035: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2243037: Experimental Crystal Structure Determination
CCDC 2243037: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Guanidine‐Supported π‐Complex of Germanium Amenable to Intramolecular C−C Cleavage in Arene and Ge Atom Transfer
A Guanidine‐Supported π‐Complex of Germanium Amenable to Intramolecular C−C Cleavage in Arene and Ge Atom Transfer Open
The germylone dimNHCGe (dimNHC=diimino N‐heterocyclic carbene) reacts with azides N 3 R (R=SiMe 3 or p‐ tolyl) to furnish the first examples of germanium π‐complexes, i. e. guanidine‐ligated compounds (dimNHI−SiMe 3 )Ge (NHI=N‐heterocyclic…
View article: Cover Feature: Base‐Stabilized Phosphinidene Oxide, Imide and Sulfide (Chem. Eur. J. 59/2023)
Cover Feature: Base‐Stabilized Phosphinidene Oxide, Imide and Sulfide (Chem. Eur. J. 59/2023) Open
Phosphinidene conducts an auction for the best P=X bond: Cyclic phosphinoamidinate-supported phosphinidene (NP)P is a natural precursor to base-stabilized PIII compounds (NP)P=X (X=O, NR, S). Interestingly, for the stronger P=O and P=N bon…
View article: CCDC 2283287: Experimental Crystal Structure Determination
CCDC 2283287: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283285: Experimental Crystal Structure Determination
CCDC 2283285: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2283286: Experimental Crystal Structure Determination
CCDC 2283286: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2263722: Experimental Crystal Structure Determination
CCDC 2263722: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2263721: Experimental Crystal Structure Determination
CCDC 2263721: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Selective Zinc‐Catalyzed 1,2‐hydroboration of N‐heteroaromatics via a Non‐Hydride Mechanism
Selective Zinc‐Catalyzed 1,2‐hydroboration of N‐heteroaromatics via a Non‐Hydride Mechanism Open
A novel bidentate amine‐imine ligand precursor LH has been synthesized. This compound was reacted with ZnMe 2 to generate the zinc methyl complex, LZnMe ( 4 ). The latter compound was fully characterized by NMR spectroscopy and single crys…
View article: Base‐Stabilized Phosphinidene Oxide, Imide and Sulfide
Base‐Stabilized Phosphinidene Oxide, Imide and Sulfide Open
Oxidation of a base‐stabilized phosphinidene (κ 2 ‐NNP)P ( 12 , NNP=phosphinoamidinate) with N 2 O afforded a labile phosphinidene oxide (κ 2 ‐NNP)P=O ( 16 ) which was characterized by NMR spectroscopy. Further oxidation of 16 by N 2 O or …
View article: CCDC 2235728: Experimental Crystal Structure Determination
CCDC 2235728: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235726: Experimental Crystal Structure Determination
CCDC 2235726: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235727: Experimental Crystal Structure Determination
CCDC 2235727: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235731: Experimental Crystal Structure Determination
CCDC 2235731: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235730: Experimental Crystal Structure Determination
CCDC 2235730: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235729: Experimental Crystal Structure Determination
CCDC 2235729: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2169577: Experimental Crystal Structure Determination
CCDC 2169577: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2169578: Experimental Crystal Structure Determination
CCDC 2169578: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …