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View article: Effect of functionalization on axially substituted 2,7-pyrene covalent triazine frameworks for dual sensing applications
Effect of functionalization on axially substituted 2,7-pyrene covalent triazine frameworks for dual sensing applications Open
View article: Novel DMAP@Mesoporous Silica Hybrid Heterogeneous Catalysts for the Knoevenagel Condensation: Greener Synthesis through Eco‐friendly Solvents
Novel DMAP@Mesoporous Silica Hybrid Heterogeneous Catalysts for the Knoevenagel Condensation: Greener Synthesis through Eco‐friendly Solvents Open
This article reports a sustainable synthesis of a novel organic‐inorganic hybrid catalysts, featuring 4‐(dimethylamino)pyridine (DMAP) immobilized onto mesoporous MCM‐41 silica and amorphous Aerosil silica supports. Using (±)‐2‐methyltetra…
View article: Ti-Functionalised Mww Silica Zeolites in the Role of Catalysts for Diphenyl Sulphide Oxidation with H2o2
Ti-Functionalised Mww Silica Zeolites in the Role of Catalysts for Diphenyl Sulphide Oxidation with H2o2 Open
View article: Multi-component catalysts with integrated MWW-type layers and mixed oxide domains for glucose-to-formic acid oxidation
Multi-component catalysts with integrated MWW-type layers and mixed oxide domains for glucose-to-formic acid oxidation Open
Multi-component catalysts combining MWW-type zeolitic layers and MgAl mixed oxides are synthesized via different methodologies with tailored acid–base properties, exhibiting promising activity for the oxidation of glucose into formic acid.
View article: New Layered Chalcogenide‐Type Metal Sulfide Materials with Improved Properties for Solar Fuel Production Applications
New Layered Chalcogenide‐Type Metal Sulfide Materials with Improved Properties for Solar Fuel Production Applications Open
Novel lamellar chalcogenide materials, named as ITQ‐75, are synthesized, focusing on the advancement and alteration of metal (tin and zinc) sulfide‐based microstructured materials. These are achieved via hydro(solvo)thermal processes in th…
View article: Thiophene-Based Covalent Triazine Frameworks as Visible-Light-Driven Heterogeneous Photocatalysts for the Oxidative Coupling of Amines
Thiophene-Based Covalent Triazine Frameworks as Visible-Light-Driven Heterogeneous Photocatalysts for the Oxidative Coupling of Amines Open
This study reports on a metal-free Covalent Triazine Framework (CTF) incorporating bithiophene structural units (TP-CTF) with a semicrystalline structure as an efficient heterogeneous photocatalyst under visible light irradiation. The phys…
View article: A New Preparation of Polyphenylacetylene Semiconductor: Potential for Supercapacitor Usagea New Preparation of Polyphenylacetylene Semiconductor: Potential for Supercapacitor Usage
A New Preparation of Polyphenylacetylene Semiconductor: Potential for Supercapacitor Usagea New Preparation of Polyphenylacetylene Semiconductor: Potential for Supercapacitor Usage Open
View article: Design and characterization of multi-component lamellar materials based on MWW-type zeolitic layers and metal oxide sub-domains
Design and characterization of multi-component lamellar materials based on MWW-type zeolitic layers and metal oxide sub-domains Open
Design and preparation of multi-component materials containing zeolitic MWW layers and sub-domains of mixed metal oxides following synthesis strategies.
View article: Unveiling the potential of a covalent triazine framework based on [1]benzothieno[3,2-<i>b</i>][1]benzothiophene (DPhBTBT-CTF) as a metal-free heterogeneous photocatalyst
Unveiling the potential of a covalent triazine framework based on [1]benzothieno[3,2-<i>b</i>][1]benzothiophene (DPhBTBT-CTF) as a metal-free heterogeneous photocatalyst Open
A novel covalent triazine framework (DPhBTBT-CTF) prepared by microwave cyclotrimerization of BTBT units was proved as very versatile photocatalyst for different reactions: oxidations, bromination, Diels–Alder cycloaddition and hydroxylati…
View article: Physicochemical properties and NH<sub>3</sub>-SCR catalytic performance of intercalated layered aluminosilicates
Physicochemical properties and NH<sub>3</sub>-SCR catalytic performance of intercalated layered aluminosilicates Open
The representative of natural layered clays, bentonite, was modified according to two routes and tested as a new catalyst for selective catalytic reduction of nitrogen oxides with ammonia (NH3-SCR). The natural acid-activated cl…
View article: Synthesis, Characterization, and NH3-SCR Catalytic Performance of Fe-Modified MCM-36 Intercalated with Various Pillars
Synthesis, Characterization, and NH3-SCR Catalytic Performance of Fe-Modified MCM-36 Intercalated with Various Pillars Open
Two series of MCM-36 zeolites intercalated with various pillars and modified with iron were synthesized, analyzed with respect to their physicochemical properties, and tested as catalysts for the NH3-SCR process. It was found that the char…
View article: Sulfide organic polymers as novel and efficient metal-free heterogeneous Lewis acid catalysts for esterification reactions
Sulfide organic polymers as novel and efficient metal-free heterogeneous Lewis acid catalysts for esterification reactions Open
Organosulfide-based covalent organic polymers (SOPs) were prepared, via click processes, through S N 2 or thiol–yne coupling reactions, which exhibited high conversions and efficient recyclability for carboxylic acid esterification reactio…
View article: Synthesis, characterization & catalysis of ITQ 2D metal–organic frameworks and spectroscopic & photodynamic properties of their composites with organic dyes
Synthesis, characterization & catalysis of ITQ 2D metal–organic frameworks and spectroscopic & photodynamic properties of their composites with organic dyes Open
We provide a detailed review of 2D-ITQ-MOFs, novel 2D hybrid materials, which is focused on their synthesis, specific catalytic applications and photophysical properties of composites with different luminescent dyes.
View article: Synthesis, Characterization, and Nh3-Scr Catalytic Performance of Fe-Modified Mcm-36 Intercalated with Various Pillars
Synthesis, Characterization, and Nh3-Scr Catalytic Performance of Fe-Modified Mcm-36 Intercalated with Various Pillars Open
View article: Hybrid organic–inorganic nanoparticles with associated functionality for catalytic transformation of biomass substrates
Hybrid organic–inorganic nanoparticles with associated functionality for catalytic transformation of biomass substrates Open
Rational synthesis design in a single synthesis step under soft conditions of organic–inorganic spherical nanoparticles with tunable acidic, basic and amphiphilic properties for the conversion of biomass molecules into platform chemicals.
View article: Hydrotalcite-Modified Clinoptilolite as the Catalyst for Selective Catalytic Reduction of NO with Ammonia (NH3-SCR)
Hydrotalcite-Modified Clinoptilolite as the Catalyst for Selective Catalytic Reduction of NO with Ammonia (NH3-SCR) Open
A series of clinoptilolite-supported catalysts, modified with hydrotalcite-like phase (HT) by co-precipitation, were prepared and tested in NH3-SCR reactions. It was found that deposition of HT on clinoptilolite increased conversion of NO …
View article: CCDC 2180928: Experimental Crystal Structure Determination
CCDC 2180928: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2180927: Experimental Crystal Structure Determination
CCDC 2180927: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Nitrogen-rich cobalt (II) MOFs as efficient bifunctional catalysts for single or tandem oxidation and CO2 conversion reactions
Nitrogen-rich cobalt (II) MOFs as efficient bifunctional catalysts for single or tandem oxidation and CO2 conversion reactions Open
The development of efficient catalysts that include the advantages of homogeneous and heterogeneous catalysts is a challenge that can be achieved with metal-organic frameworks (MOFs) since they can incorporate different functionalities in …
View article: Catalytic Performance and Sulfur Dioxide Resistance of One-Pot Synthesized Fe-MCM-22 in Selective Catalytic Reduction of Nitrogen Oxides with Ammonia (NH3-SCR)—The Effect of Iron Content
Catalytic Performance and Sulfur Dioxide Resistance of One-Pot Synthesized Fe-MCM-22 in Selective Catalytic Reduction of Nitrogen Oxides with Ammonia (NH3-SCR)—The Effect of Iron Content Open
The catalytic performance of Fe-catalysts in selective catalytic reduction of nitrogen oxides with ammonia (NH3-SCR) strongly depends on the nature of iron sites. Therefore, we aimed to prepare and investigate the catalytic potential of Fe…
View article: Bifunctional hybrid organosiliceous catalysts for aldol condensation – hydrogenation tandem reactions of furfural in continuous-flow reactor
Bifunctional hybrid organosiliceous catalysts for aldol condensation – hydrogenation tandem reactions of furfural in continuous-flow reactor Open
View article: Catalytic Performance of One-Pot Synthesized Fe-MWW Layered Zeolites (MCM-22, MCM-36, and ITQ-2) in Selective Catalytic Reduction of Nitrogen Oxides with Ammonia
Catalytic Performance of One-Pot Synthesized Fe-MWW Layered Zeolites (MCM-22, MCM-36, and ITQ-2) in Selective Catalytic Reduction of Nitrogen Oxides with Ammonia Open
The application of layered zeolites of MWW topology in environmental catalysis has attracted growing attention in recent years; however, only a few studies have explored their performance in selective catalytic reduction with ammonia (NH3-…
View article: Bifunctional Hybrid Organosiliceous Catalysts for Aldol Condensation – Hydrogenation Tandem Reactions of Furfural in Continuous-Flow Reactor
Bifunctional Hybrid Organosiliceous Catalysts for Aldol Condensation – Hydrogenation Tandem Reactions of Furfural in Continuous-Flow Reactor Open
View article: Interrogating the Behaviour of a Styryl Dye Interacting with a Mesoscopic 2D-MOF and Its Luminescent Vapochromic Sensing
Interrogating the Behaviour of a Styryl Dye Interacting with a Mesoscopic 2D-MOF and Its Luminescent Vapochromic Sensing Open
In this contribution, we report on the solid-state-photodynamical properties and further applications of a low dimensional composite material composed by the luminescent trans-4-(dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyra…
View article: Phenyl Extended Naphthalene‐Based Covalent Triazine Frameworks as Versatile Metal‐Free Heterogeneous Photocatalysts
Phenyl Extended Naphthalene‐Based Covalent Triazine Frameworks as Versatile Metal‐Free Heterogeneous Photocatalysts Open
Two new covalent triazines frameworks (CTFs) containing phenyl extended naphthalene units (with and without methoxy groups in the naphthalene core) are prepared by thermal and microwave activation. Both procedures yield similar chemical st…
View article: Open-Framework Chalcogenide Materials - from isolated clusters to highly ordered structures - and their photocalytic applications
Open-Framework Chalcogenide Materials - from isolated clusters to highly ordered structures - and their photocalytic applications Open
View article: Active Base Hybrid Organosilica Materials based on Pyrrolidine Builder Units for Fine Chemicals Production
Active Base Hybrid Organosilica Materials based on Pyrrolidine Builder Units for Fine Chemicals Production Open
The catalytic activity of “pyrrolidine type” fragments included or anchored in the mesoporous silica supports or polymeric frameworks have been fully reported for enantioselective transformation. Nevertheless, low attention was focused on …
View article: Structure and reactive properties of Nb-impregnated two-dimensional pillared MWW zeolites for total oxidation of volatile organic compounds
Structure and reactive properties of Nb-impregnated two-dimensional pillared MWW zeolites for total oxidation of volatile organic compounds Open
View article: Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review
Porous Silica-Based Organic-Inorganic Hybrid Catalysts: A Review Open
Hybrid organic-inorganic catalysts have been extensively investigated by several research groups in the last decades, as they allow combining the structural robust-ness of inorganic solids with the versatility of organic chemistry. Within …
View article: Titanium–silicon ferrierites and their delaminated forms modified with copper as effective catalysts for low-temperature NH<sub>3</sub>-SCR
Titanium–silicon ferrierites and their delaminated forms modified with copper as effective catalysts for low-temperature NH<sub>3</sub>-SCR Open
Titanium–silicon ferrierites with different Si/Ti ratios and their delaminated forms were modified with copper by ion-exchange.