Viacheslav Iablokov
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View article: Promoting the Cleavage of C–O Bonds at the Interface between a Metal Oxide Cluster and a Co(0001) Support
Promoting the Cleavage of C–O Bonds at the Interface between a Metal Oxide Cluster and a Co(0001) Support Open
As a first step toward the rational design of Co-based catalysts with a higher activity and selectivity, we determine how one can activate a C–O bond at the interface between a metal oxide cluster and a Co(0001) support. The hypothesis her…
View article: Superior Fischer-Tropsch performance of uniform cobalt nanoparticles deposited into mesoporous SiC
Superior Fischer-Tropsch performance of uniform cobalt nanoparticles deposited into mesoporous SiC Open
View article: Mesoporous SiC with Potential Catalytic Application by Electrochemical Dissolution of Polycrystalline 3C-SiC
Mesoporous SiC with Potential Catalytic Application by Electrochemical Dissolution of Polycrystalline 3C-SiC Open
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View article: Size and Surface Chemistry Tuning of Silicon Carbide Nanoparticles
Size and Surface Chemistry Tuning of Silicon Carbide Nanoparticles Open
Chemical transformations on the surface of commercially available 3C-SiC nanoparticles were studied by means of FTIR, XPS, and temperature-programmed desorption mass spectrometry methods. Thermal oxidation of SiC NPs resulted in the format…
View article: Size-Dependent Activity and Selectivity of Fe/MCF-17 in the Catalytic Hydrogenation of Carbon Monoxide Using Fe(0) Nanoparticles as Precursors
Size-Dependent Activity and Selectivity of Fe/MCF-17 in the Catalytic Hydrogenation of Carbon Monoxide Using Fe(0) Nanoparticles as Precursors Open
Monodisperse Fe(0) nanoparticles\nwith diameters between 1.8 and\n9.0 nm were prepared from organometallic {Fe[N(SiMe3)2]2}2 and intercalated into mesoporous\nMCF-17 silica. We observed high tu…
View article: Mesoporous silicon carbide via nanocasting of Ludox® xerogel
Mesoporous silicon carbide via nanocasting of Ludox® xerogel Open
Porous SiC with uniformly sized 12 nm and 22 nm spherical pores was synthesized from nanocomposites of polycarbosilane and xerogels of SiO2NPs as templates. Addition of Ni2+to the composite significantly improved the …