Valerio Zanotti
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View article: Effective electrocatalysts for hydrogen production from acetic acid by screening of monodentate ligands in cationic diiron hetero-carbyne complexes
Effective electrocatalysts for hydrogen production from acetic acid by screening of monodentate ligands in cationic diiron hetero-carbyne complexes Open
The appropriate selection of monodentate and bridging ligands in diiron bis-cyclopentadienyl complexes of type [Fe 2 Cp 2 (CO)(L)(μ-CO)(μ-CX)] + is key to obtain efficient electrocatalysts for the hydrogen evolution reaction.
View article: CCDC 2158724: Experimental Crystal Structure Determination
CCDC 2158724: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2087771: Experimental Crystal Structure Determination
CCDC 2087771: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2120119: Experimental Crystal Structure Determination
CCDC 2120119: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2120118: Experimental Crystal Structure Determination
CCDC 2120118: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Bringing Homogeneous Iron Catalysts on the Heterogeneous Side: Solutions for Immobilization
Bringing Homogeneous Iron Catalysts on the Heterogeneous Side: Solutions for Immobilization Open
Noble metal catalysts currently dominate the landscape of chemical synthesis, but cheaper and less toxic derivatives are recently emerging as more sustainable solutions. Iron is among the possible alternative metals due to its biocompatibi…
View article: Cyclopentadienone–NHC iron(0) complexes as low valent electrocatalysts for water oxidation
Cyclopentadienone–NHC iron(0) complexes as low valent electrocatalysts for water oxidation Open
Design and application of earth abundant iron based molecular electrocatalysts for water oxidation, an essential challenge for sustainable energy applications.
View article: Synthesis and Reactivity of Poly(propyleneimine) Dendrimers Functionalized with Cyclopentadienone N-Heterocyclic-Carbene Ruthenium(0) Complexes
Synthesis and Reactivity of Poly(propyleneimine) Dendrimers Functionalized with Cyclopentadienone N-Heterocyclic-Carbene Ruthenium(0) Complexes Open
Ligand design in metal chemistry is a fundamental step when pursuing compounds with specific reactivity. In this paper, the functionalization of the OH group in the lateral chain of the N-heterocyclic-carbene (NHC) ligand bound to a bis-ca…
View article: Exploring the Anticancer Potential of Diiron Bis-cyclopentadienyl Complexes with Bridging Hydrocarbyl Ligands: Behavior in Aqueous Media and <i>In Vitro</i> Cytotoxicity
Exploring the Anticancer Potential of Diiron Bis-cyclopentadienyl Complexes with Bridging Hydrocarbyl Ligands: Behavior in Aqueous Media and <i>In Vitro</i> Cytotoxicity Open
A series of diiron complexes based on the [Fe2Cp2(CO)x] skeleton (Cp = η5-C5H5, x = 2, 3; η4-C5H5Ph in place of one Cp in one case) and containing different bridging hydrocarbyl ligands (aminocarbyne, thiocarbyne, allenyl) were preliminari…
View article: CCDC 1947176: Experimental Crystal Structure Determination
CCDC 1947176: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1947175: Experimental Crystal Structure Determination
CCDC 1947175: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Imidazolium Salts of Ruthenium Anionic Cyclopentadienone Complexes: Ion Pair for Bifunctional Catalysis in Ionic Liquids
Imidazolium Salts of Ruthenium Anionic Cyclopentadienone Complexes: Ion Pair for Bifunctional Catalysis in Ionic Liquids Open
The reactivity of the dinuclear complex dicarbonyl[η 4 ‐3,4‐bis(4‐methoxyphenyl)‐2,5‐diphenylcyclopenta‐2,4‐dienone] ( 2 ) with imidazolium salts has been studied using a library of variously functionalized imidazolium salts, and leading t…
View article: Front Cover
Front Cover Open
The cover image is based on the Full Paper Synthesis, reactivity and preliminary biological activity of iron(0) complexes with cyclopentadienone and amino-appended N-heterocyclic carbene ligands by Andrea Cingolani et al., https://doi.org/…
View article: Synthesis, reactivity and preliminary biological activity of iron(0) complexes with cyclopentadienone and amino‐appended <i>N</i>‐heterocyclic carbene ligands
Synthesis, reactivity and preliminary biological activity of iron(0) complexes with cyclopentadienone and amino‐appended <i>N</i>‐heterocyclic carbene ligands Open
Neutral and cationic cyclopentadienone (CpO) N ‐heterocyclic carbene (NHC) bis ‐carbonyl iron(0) complexes bearing, appended to the NHC ligand, either a terminal amino group on the lateral chain, [Fe(η 4 ‐CpO)(CO) 2 (κ C ‐NHC(CH 2 ) n NH 2…
View article: Bond Forming Reactions Involving Isocyanides at Diiron Complexes
Bond Forming Reactions Involving Isocyanides at Diiron Complexes Open
The versatility of isocyanides (CNR) in organic chemistry has been tremendously enhanced by continuous advancement in transition metal catalysis. On the other hand, the urgent need for new and more sustainable synthetic strategies based on…
View article: CCDC 1826966: Experimental Crystal Structure Determination
CCDC 1826966: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C<sub>3</sub> Ligand Triggered by One-Electron Reduction
Controlled Dissociation of Iron and Cyclopentadienyl from a Diiron Complex with a Bridging C<sub>3</sub> Ligand Triggered by One-Electron Reduction Open
The one-electron reduction of a diiron cationic complex revealed unique features: cleavage of the diiron structure occurred despite a multidentate bridging C3 ligand and was accompanied by the clean dissociation of one η5-cyclopentadienyl …
View article: Catalytic Biorefining of Ethanol from Wine Waste to Butanol and Higher Alcohols: Modeling the Life Cycle Assessment and Process Design
Catalytic Biorefining of Ethanol from Wine Waste to Butanol and Higher Alcohols: Modeling the Life Cycle Assessment and Process Design Open
Homologation of bioethanol to butanol and higher alcohols by means of Guerbet reaction was performed with a novel ruthenium based bifunctional catalyst under homogeneous conditions in the presence of a basic cocatalyst. Reaction screening …
View article: DFT Mechanistic Insights into the Alkyne Insertion Reaction Affording Diiron μ-Vinyliminium Complexes and New Functionalization Pathways
DFT Mechanistic Insights into the Alkyne Insertion Reaction Affording Diiron μ-Vinyliminium Complexes and New Functionalization Pathways Open
Insertion of propyne or 2-butyne into the Fe-carbyne bond belonging to the fragment [Fe2Cp2(CO)(μ-CO)μ-CNMe(R)]+ (R = Me or Xyl = 2,6-C6H3Me2) was investigated via density functional theory (DFT), and plausible intermediates were identifie…
View article: Front Cover Picture: Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium(II) Catalysts (Adv. Synth. Catal. 18/2018)
Front Cover Picture: Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium(II) Catalysts (Adv. Synth. Catal. 18/2018) Open
The front cover picture supplied by Carla Carfagna and co‐workers depicts an efficient process for the diastereospecific bis‐alkoxycarbonylation of 1,2‐disubstituted olefins, leading to the synthesis of 2,3‐disubstituted‐succinic diesters.…
View article: Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium(II) Catalysts
Diastereospecific Bis‐alkoxycarbonylation of 1,2‐Disubstituted Olefins Catalyzed by Aryl α‐Diimine Palladium(II) Catalysts Open
Readily synthesized aryl α‐diimine derivatives have been used as efficient ligands for the palladium‐catalyzed oxidative bis‐alkoxycarbonylation reaction of 1,2‐disubstituted olefins. The most active catalyst A was formed in situ from bis‐…
View article: Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study
Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study Open
Invited for the cover of this issue is the group of Fabio Marchetti from the University of Pisa, Italy. The cover image shows the X‐ray structure of a cationic diiron carbonyl cyclopentadienide complex with a bridging aminocarbyne ligand a…
View article: Front Cover: Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study (Eur. J. Inorg. Chem. 8/2018)
Front Cover: Regioselective Nucleophilic Additions to Diiron Carbonyl Complexes Containing a Bridging Aminocarbyne Ligand: A Synthetic, Crystallographic and DFT Study (Eur. J. Inorg. Chem. 8/2018) Open
The Front Cover shows the X-ray structure of a cationic diiron carbonyl cyclopentadienide complex with a bridging aminocarbyne ligand and the sites where various nucleophiles can add selectively, depending on their nature. The synthetic pr…