Vincent R. Whiteside
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View article: Probing self-healing dynamics in perovskite solar cells under proton irradiation via in situ and in operando characterization
Probing self-healing dynamics in perovskite solar cells under proton irradiation via in situ and in operando characterization Open
View article: Phonon Polaritons and Epsilon Near Zero Modes in Sapphire Nanostructures
Phonon Polaritons and Epsilon Near Zero Modes in Sapphire Nanostructures Open
Surface phonon polaritons (SPhPs) are promising candidates for enhanced light--matter interactions due to their efficient and low-loss light confinement features. In this work, we present unique light-matter interactions in saphhire within…
View article: Charge carrier extraction and recombination effects in GaInAs/GaAsP multi-quantum well solar cells
Charge carrier extraction and recombination effects in GaInAs/GaAsP multi-quantum well solar cells Open
The carrier extraction and transport mechanisms as well as the relative contributions of radiative and non-radiative recombination processes are investigated in high-quality strain-balanced GaInAs/GaAsP multi-quantum well solar cells recen…
View article: The effects of multiple stressors on the operational performance of (FA,MA,Cs)Pb(I,Br)3 solar cells
The effects of multiple stressors on the operational performance of (FA,MA,Cs)Pb(I,Br)3 solar cells Open
Here, a thorough study of the effects of multiple stressors on a series of FAMACsPb(IBr)3 solar cells was assessed to test the stability of such systems for space applications. Combinations of thermal cycling, constant illumination, and el…
View article: Barrier layer design reduces top electrode ion migration in perovskite solar cells
Barrier layer design reduces top electrode ion migration in perovskite solar cells Open
We report on an examination of mobile ion concentration ( N 0 ) in perovskite solar cells (PSCs) as a function of temperature and device architecture.
View article: Hot carrier dynamics in operational metal halide perovskite solar cells
Hot carrier dynamics in operational metal halide perovskite solar cells Open
While the low-energy side of the Δ A curves remains stable over time, the high-energy side changes dramatically, reflecting hot carrier thermalization, which occurs at different rates on the hole and electron transport sides in perovskite …
View article: Hot Carrier Dynamics in Operational Metal Halide Perovskite Solar Cells
Hot Carrier Dynamics in Operational Metal Halide Perovskite Solar Cells Open
One of the main approaches to inhibit carrier cooling in semiconductor systems enabling the study of hot carrier solar cell protocols is the use of concentrated illumination to obtain high power densities and create a phonon bottleneck. Th…
View article: Radiation versus environmental degradation in unencapsulated metal halide perovskite solar cells
Radiation versus environmental degradation in unencapsulated metal halide perovskite solar cells Open
Here, the radiation hardness of metal halide perovskite solar cells exposed to space conditions versus the effects of environmental degradation are assessed. The relative response of the constituent layers of the architecture to radiation …
View article: Mapping Phonon Polaritons with Visible Light
Mapping Phonon Polaritons with Visible Light Open
Phonon polaritons (PhPs) are hybrid photon-phonon waves which enable strong light-matter interactions and subdiffractional confinement, potentially empowering applications in sensing, nonlinear optics and nanoscale energy manipulation. In …
View article: Mapping Phonon Polaritons with Visible Light
Mapping Phonon Polaritons with Visible Light Open
Phonon polaritons (PhPs) are hybrid photon-phonon waves which enable strong light-matter interactions and subdiffractional confinement, potentially empowering applications in sensing, nonlinear optics and nanoscale energy manipulation. In …
View article: Evidence of hot carrier extraction in metal halide perovskite solar cells
Evidence of hot carrier extraction in metal halide perovskite solar cells Open
The presence of hot carriers is presented in the operational properties of an (FA,Cs)Pb(I, Br, Cl) 3 solar cell at ambient temperatures and under practical solar concentration. Albeit, in a device architecture that is not suitably designed…
View article: Status report on emerging photovoltaics
Status report on emerging photovoltaics Open
This report provides a snapshot of emerging photovoltaic (PV) technologies. It consists of concise contributions from experts in a wide range of fields including silicon, thin film, III-V, perovskite, organic, and dye-sensitized PVs. Strat…
View article: Evidence of Hot Carrier Extraction in Metal Halide Perovskite Solar Cells
Evidence of Hot Carrier Extraction in Metal Halide Perovskite Solar Cells Open
The presence of hot carriers is presented in the operational properties of an (FA,Cs)Pb(I, Br, Cl)3 solar cell at ambient temperatures and under practical solar concentration. At 100 K, clear evidence of hot carriers is observed in both th…
View article: Radiation tolerance and self-healing in triple halide perovskite solar cells
Radiation tolerance and self-healing in triple halide perovskite solar cells Open
The high tolerance and stability of triple halide perovskite solar cells is demonstrated in practical space conditions at high irradiation levels. The solar cells were irradiated for a range of proton energies (75 keV, 300 keV, and 1 MeV) …
View article: Near-unity light-matter interaction in mid-infrared van der Waals nanocavities
Near-unity light-matter interaction in mid-infrared van der Waals nanocavities Open
Accessing mid-infrared radiation is of great importance for a range of applications, including thermal imaging, sensing, and radiative cooling. Here, we study light interaction with hexagonal boron nitride nanocavities and reveal strong an…
View article: Temperature Dependent Carrier Extraction and the Effects of Excitons on Emission and Photovoltaic Performance in Cs0.05FA0.79MA0.16Pb(I0.83Br0.17)3 Solar Cells
Temperature Dependent Carrier Extraction and the Effects of Excitons on Emission and Photovoltaic Performance in Cs0.05FA0.79MA0.16Pb(I0.83Br0.17)3 Solar Cells Open
The photovoltaic parameters of triple cation perovskite\n[Cs0.05FA0.79MA0.16Pb(I0.83Br0.17)3] solar cells are investigated focusing\non\nthe electro-optical properties and …
View article: FACsPb Triple Halide Perovskite Solar Cells with Thermal Operation over 200 °C
FACsPb Triple Halide Perovskite Solar Cells with Thermal Operation over 200 °C Open
Formamidinium cesium (FACs) perovskites solar cells have been shown to be among the most stable metal halide perovskites. In this report high-temperature data are presented which systematically and statistically demonstrate the high therma…
View article: Toward Hot Carrier Extraction in Intervalley Photovoltaic Devices
Toward Hot Carrier Extraction in Intervalley Photovoltaic Devices Open
InGaAs heterostructures have demonstrated the means to maintain hot carrier behavior under practical operating conditions via valley photovoltaics. However, enhancing the extraction to create a fully operational hot carrier solar cell requ…
View article: Pathways to hot carrier solar cells
Pathways to hot carrier solar cells Open
Hot carrier solar cells (HCSCs) were first proposed many decades ago. Over the intervening years, there has been a continuing quest to create these cells that hold promise to shatter the Shockley–Queisser efficiency limit on single-junctio…
View article: Non-equilibrium hot-carrier transport in type-II multiple-quantum wells for solar-cell applications
Non-equilibrium hot-carrier transport in type-II multiple-quantum wells for solar-cell applications Open
Prototypes for hot-carrier solar cells based on type-II InAs/AlAsSb multiple quantum wells are examined for AC photoconductivity as a function of lattice temperature and photoexcitation energy to determine the photoexcited charge carrier t…
View article: Hot carrier relaxation and inhibited thermalization in superlattice heterostructures: The potential for phonon management
Hot carrier relaxation and inhibited thermalization in superlattice heterostructures: The potential for phonon management Open
One of the main loss mechanisms in photovoltaic solar cells is the thermalization of photogenerated hot carriers via phonon-mediated relaxation. By inhibiting these relaxation mechanisms and reducing thermalization losses, it may be possib…
View article: Hot-carrier dynamics in InAs/AlAsSb multiple-quantum wells
Hot-carrier dynamics in InAs/AlAsSb multiple-quantum wells Open
View article: Hot carrier redistribution, electron-phonon interaction, and their role in carrier relaxation in thin film halide perovskites
Hot carrier redistribution, electron-phonon interaction, and their role in carrier relaxation in thin film halide perovskites Open
Temperature dependent (4K-300K) photoluminescence and transmission spectra are analyzed to study the effect of changing the different components of a perovskite compound, be it A, B, or X. Four different films are compared: FAMAPbSnI3, FAP…
View article: Challenges, myths, and opportunities in hot carrier solar cells
Challenges, myths, and opportunities in hot carrier solar cells Open
Hot carrier solar cells hold the promise of efficiency significantly greater than that predicted by the Shockley–Queisser limit. Consequently, there has been considerable effort to create cells that achieve this goal, but so far, this has …
View article: Publisher Correction: Exploiting intervalley scattering to harness hot carriers in III–V solar cells
Publisher Correction: Exploiting intervalley scattering to harness hot carriers in III–V solar cells Open
View article: Role of Exciton Binding Energy on LO Phonon Broadening and Polaron Formation in (BA)<sub>2</sub>PbI<sub>4</sub> Ruddlesden–Popper Films
Role of Exciton Binding Energy on LO Phonon Broadening and Polaron Formation in (BA)<sub>2</sub>PbI<sub>4</sub> Ruddlesden–Popper Films Open
The effect of carrier–carrier and carrier–phonon interactions is presented in n = 1 (2D) (BA)2PbI4 Ruddlesden–Popper thin films, and their effect is compared to that of conventional MAPbI3. While temperatur…
View article: Rb<sub>4</sub>Ag<sub>2</sub>BiBr<sub>9</sub>: A Lead-Free Visible Light Absorbing Halide Semiconductor with Improved Stability
Rb<sub>4</sub>Ag<sub>2</sub>BiBr<sub>9</sub>: A Lead-Free Visible Light Absorbing Halide Semiconductor with Improved Stability Open
Replacement of the toxic heavy element lead in metal halide perovskites has been attracting a great interest because the high toxicity and poor air stability are two of the major barriers for their widespread utilization. Recently, mixed-c…
View article: CSD 1871838: Experimental Crystal Structure Determination
CSD 1871838: Experimental Crystal Structure Determination Open
View article: Enhanced hot electron lifetimes in quantum wells with inhibited phonon coupling
Enhanced hot electron lifetimes in quantum wells with inhibited phonon coupling Open
View article: CCDC 1576892: Experimental Crystal Structure Determination
CCDC 1576892: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …