Vivek Bagchi
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View article: Nano-interfacial interactions in 2-D Ni<sub>3</sub>S<sub>2</sub>–Ni<sub>3</sub>N nanosheets for the hydrogen evolution reaction in an alkaline medium
Nano-interfacial interactions in 2-D Ni<sub>3</sub>S<sub>2</sub>–Ni<sub>3</sub>N nanosheets for the hydrogen evolution reaction in an alkaline medium Open
Herein, a heterostructure of Ni 3 S 2 –Ni 3 N was prepared by a three-step synthesis procedure that consists of the formation of Ni 3 S 2 on NF, the electrodeposition of Ni(OH) 2 over Ni 3 S 2 and nitridation in the presence of ammonia.
A 3D-hierarchical flower like architecture of anion induced layered double hydroxides for competing anodic reactions Open
In this study, the partially sulfurized CoFeLDH was synthesized by using Na 2 S as the sulfur source. The catalyst performed excellently for UOR & OER requiring a lower overpotential of 171 and 268 mV at the current density of 40 mA cm −2 …
Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents Open
Recent research has highlighted the key role played by the electron affinity of the active metal-nitrene/imido oxidant as the driving force in nitrene additions to olefins to afford valuable aziridines. The present work showcases a library…
View article: Uniformly Decorated Molybdenum Carbide/Nitride Nanostructures on Biomass Templates for Hydrogen Evolution Reaction Applications
Uniformly Decorated Molybdenum Carbide/Nitride Nanostructures on Biomass Templates for Hydrogen Evolution Reaction Applications Open
Natural fibrils derived from biomass were used as a template to synthesize uniformly decorated nanoparticles (10-12 nm) of molybdenum carbide (Mo2C) and molybdenum nitride (Mo2N) supported on carbon. The nanoparticles have been synthesized…
Hydrated FePO<sub>4</sub> nanoparticles supported on P-doped RGO show enhanced ORR activity compared to their dehydrated form in an alkaline medium Open
One-step hydrothermal growth of FePO4 nanoparticles (15–25 nm) uniformly decorated on the P-doped reduced graphene oxide (PRGO) was studied for oxygen reduction reaction (ORR) activity.
Environmentally Benign Metal-Free Reduction of GO Using Molecular Hydrogen: A Mechanistic Insight Open
A simple yet effective methodology to obtain high-quality reduced graphene oxide (RGO) using a tetrahydrofuran suspension of GO under hydrogen at moderate pressure has been demonstrated. The extent of reduction as a function of the pressur…
Comparative Nitrene-Transfer Chemistry to Olefinic Substrates Mediated by a Library of Anionic Mn(II) Triphenylamido-Amine Reagents and M(II) Congeners (M = Fe, Co, Ni) Favoring Aromatic over Aliphatic Alkenes Open
Selective amination of σ and π entities such as C-H and C=C bonds of substrates remains a challenging endeavor for current catalytic methodologies devoted to the synthesis of abundant nitrogen-containing chemicals. The present work address…
CCDC 1482576: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …