Volodymyr M. Hiiuk
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View article: Bioinspired Synthesis of Twin <i>abeo</i> ‐Steroids Bufogargarizins A and B via a Divergent Intramolecular Aldol Addition Reaction
Bioinspired Synthesis of Twin <i>abeo</i> ‐Steroids Bufogargarizins A and B via a Divergent Intramolecular Aldol Addition Reaction Open
This manuscript describes a concise bioinspired synthesis of twin abeo ‐steroids bufogargarizins A and B with an unusual [7.5.6.5] and [5.7.6.5] skeletons and a highly oxidized D‐ring with an α‐pyrone substituent from (+)‐methyl estrone. T…
View article: Bioinspired Synthesis of Twin <i>abeo</i> ‐Steroids Bufogargarizins A and B via a Divergent Intramolecular Aldol Addition Reaction
Bioinspired Synthesis of Twin <i>abeo</i> ‐Steroids Bufogargarizins A and B via a Divergent Intramolecular Aldol Addition Reaction Open
This manuscript describes a concise bioinspired synthesis of twin abeo ‐steroids bufogargarizins A and B with an unusual [7.5.6.5] and [5.7.6.5] skeletons and a highly oxidized D‐ring with an α‐pyrone substituent from (+)‐methyl estrone. T…
View article: Detergent‐free isolation and characterization of amyloid precursor protein <scp>C99</scp> in <i>E. coli</i> native lipid‐nanodiscs using non‐ionic polymer
Detergent‐free isolation and characterization of amyloid precursor protein <span>C99</span> in <i>E. coli</i> native lipid‐nanodiscs using non‐ionic polymer Open
Alzheimer's disease (AD), a progressive neurodegenerative disorder, is characterized by cognitive decline resulting from neuronal cell death. A key contributor to AD pathology is C99, a membrane‐bound β‐secretase‐cleaved fragment of amyloi…
View article: Nanodisc reconstitution and characterization of amyloid-β precursor protein C99
Nanodisc reconstitution and characterization of amyloid-β precursor protein C99 Open
Amyloid precursor protein (APP) plays a pivotal role in the pathology of Alzheimer’s disease. Since the fragmentation of the membrane-bound APP that results in the production of amyloid-beta peptides is the starting point for amyloid toxic…
View article: CCDC 2212766: Experimental Crystal Structure Determination
CCDC 2212766: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212768: Experimental Crystal Structure Determination
CCDC 2212768: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212765: Experimental Crystal Structure Determination
CCDC 2212765: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2212767: Experimental Crystal Structure Determination
CCDC 2212767: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Highly Porous Cyanometallic Spin-Crossover Frameworks Employing Pyridazino[4,5-d]pyridazine Bridge
Highly Porous Cyanometallic Spin-Crossover Frameworks Employing Pyridazino[4,5-d]pyridazine Bridge Open
Single crystals of two spin-crossover (SCO) cyanometallic coordination polymers based on the pyridazino[4,5-d]pyridazine ligand (pp) of the composition [Fe(pp)M(CN)4]∙G (where M = Pd, Pt; G = guest molecules) were obtained by a slow diffus…
View article: Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)<sub>2</sub>{M(CN)<sub>2</sub>}<sub>2</sub>] (M = Ag, Au)
Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)<sub>2</sub>{M(CN)<sub>2</sub>}<sub>2</sub>] (M = Ag, Au) Open
Two 2D Hofmann-type complexes of the composition [Fe(Phpz)2{M(CN)2}2] (where Phpz = 2-phenylpyrazine; M = Ag, Au) have been synthesized, and their spin-crossover (SCO) behavior has been thoroughly characterized. Single-crystal X-ray analys…
View article: SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS
SPIN-CROSSOVER IRON(II) COORDINATION COMPOUNDS: FABRICATION OF FUNCTIONAL MATERIALS AND THEIR INTEGRATION INTO MICRO- AND NANOCONSTRUCTIONS Open
Development of micro- and nanosized spin-crossover (SCO) materials has become an important research direction within the past decade. Such an interest is associated with high perceptive of practical application of these materials in nanoel…
View article: Spin crossover in iron(<scp>ii</scp>) Hofmann clathrates analogues with 1,2,3-triazole
Spin crossover in iron(<span>ii</span>) Hofmann clathrates analogues with 1,2,3-triazole Open
2D coordination cyanometallic frameworks supported by the 1,2,3-triazole ligand display thermally induced cooperative spin crossover.
View article: Spin crossover in 2D iron(<scp>ii</scp>) phthalazine cyanometallic complexes
Spin crossover in 2D iron(<span>ii</span>) phthalazine cyanometallic complexes Open
Two new spin-crossover analogues of Hofmann clathrates based on a bicyclic ligand phthalazine have been synthesized.
View article: CCDC 1878181: Experimental Crystal Structure Determination
CCDC 1878181: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Room temperature hysteretic spin crossover in a new cyanoheterometallic framework
Room temperature hysteretic spin crossover in a new cyanoheterometallic framework Open
A new iron(ii)-based spin-crossover compound with thermal hysteresis operating under ambient conditions is reported.
View article: CCDC 1878182: Experimental Crystal Structure Determination
CCDC 1878182: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Crystal structure of<i>catena</i>-poly[[[tetraaquairon(II)]-<i>trans</i>-μ-1,2-bis(pyridin-4-yl)ethene-κ<sup>2</sup><i>N</i>:<i>N</i>′] bis(<i>p</i>-toluenesulfonate) methanol disolvate]
Crystal structure of<i>catena</i>-poly[[[tetraaquairon(II)]-<i>trans</i>-μ-1,2-bis(pyridin-4-yl)ethene-κ<sup>2</sup><i>N</i>:<i>N</i>′] bis(<i>p</i>-toluenesulfonate) methanol disolvate] Open
In the title polymeric complex, {[Fe(C 12 H 10 N 2 ) 2 (H 2 O) 4 ](CH 3 C 6 H 4 SO 3 ) 2 ·2CH 3 OH} n , the Fe II cation, located on an inversion centre, is coordinated by four water molecules in the equatorial positions and two 1,2-bis(py…
View article: CCDC 1587771: Experimental Crystal Structure Determination
CCDC 1587771: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …