W. Clegg
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View article: A Rare Thermochromic Zwitterionic Nickel (II) Complex of the Bulky Alpha Ligand 1,2-Bis-(di-tbutylphosphinomethyl)Benzene
A Rare Thermochromic Zwitterionic Nickel (II) Complex of the Bulky Alpha Ligand 1,2-Bis-(di-tbutylphosphinomethyl)Benzene Open
The reaction of the bulky ligand 1,2-bis-(di-tert-butylphosphinomethyl)benzene, 1 with [Ni(DME)Cl2], 3, DME = 1,2-dimethoxyethane, at room temperature over extended periods, affords the new blue Zwitterionic complex [2-(C6H4-CH2P(H)tBu2-1-…
View article: <span style="letter-spacing: -.2pt; mso-ansi-language: EN-GB;">A Rare Thermochromic Zwitterionic Nickel(II) Complex of the Bulky Alpha Ligand 1,2-Bis-(di-<sup>t</sup>butylphosphinomethyl)benzene
<span>A Rare Thermochromic Zwitterionic Nickel(II) Complex of the Bulky Alpha Ligand 1,2-Bis-(di-<sup>t</sup>butylphosphinomethyl)benzene Open
The reaction of the bulky ligand 1,2-bis-(di-tert-butylphosphinomethyl)benzene,1 with [Ni(DME)Cl2], 3, DME = 1,2-dimethoxyethane, at room temperature over extended periods, affords the new blue Zwitterionic complex [(1,2-C6H4-CH2PtBu2-2-C6…
View article: A Rare Thermochromic Zwitterionic Nickel(II) Complex of the Bulky Alpha Ligand 1,2-Bis-(di-tbutylphosphinomethyl)benzene
A Rare Thermochromic Zwitterionic Nickel(II) Complex of the Bulky Alpha Ligand 1,2-Bis-(di-tbutylphosphinomethyl)benzene Open
The reaction of the bulky ligand 1,2-bis-(di-tert-butylphosphinomethyl)benzene with [Ni(DME)Cl2] affords the blue Zwitterionic complex containing a phosphonium group and an anionic nickel trichloride. The neutral and stable complex is of i…
View article: A Rapid General Synthesis and the Spectroscopic Data of 2,2′-Bis-(di-isopropylphosphino)-1,1′-dibromoferrocene, (bpdbf), 1,1′,2,2′-Tetrakis-(di-isopropylphosphino) Ferrocene, (tdipf) and Related Ligands: Taking dppf into the Future
A Rapid General Synthesis and the Spectroscopic Data of 2,2′-Bis-(di-isopropylphosphino)-1,1′-dibromoferrocene, (bpdbf), 1,1′,2,2′-Tetrakis-(di-isopropylphosphino) Ferrocene, (tdipf) and Related Ligands: Taking dppf into the Future Open
In this paper, the clean high yielding, synthesis, and structure of the tetraphosphine ligand, 1,1′,2,2′-tetrakis-(di-isopropyl-phosphino)ferrocene, (tdipf), is described. In addition, improved synthesis methods for 1,1′,2,2′-tetrakis(diph…
View article: A Rapid General Synthesis and the Spectroscopic Data of 2,2′-Bis-(Di-Isopropylphosphino)-1,1′-Dibromoferrocene, (<em>bpdbf</em>), 1,1′, 2,2′-Tetrakis-(Di-Isopropylphosphino) Ferrocene, (<em>tdipf</em>) and Related Ligands. Taking <em>dppf </em>into the Future
A Rapid General Synthesis and the Spectroscopic Data of 2,2′-Bis-(Di-Isopropylphosphino)-1,1′-Dibromoferrocene, (<em>bpdbf</em>), 1,1′, 2,2′-Tetrakis-(Di-Isopropylphosphino) Ferrocene, (<em>tdipf</em>) and Related Ligands. Taking <em>dppf </em>into the Future Open
The clean high yielding, synthesis and structure of the tetraphosphine ligand, 1,1´,2,2´-tetrakis-(di-isopropyl-phosphino)ferrocene, (tdipf), is described. In addition, an improved synthesis of the 1,1´,2,2´-tetraki…
View article: The Sensitivity of Structure to Ionic Radius and Reaction Stoichiometry: A Crystallographic Study of Metal Coordination and Hydrogen Bonding in Barbiturate Complexes of All Five Alkali Metals Li–Cs
The Sensitivity of Structure to Ionic Radius and Reaction Stoichiometry: A Crystallographic Study of Metal Coordination and Hydrogen Bonding in Barbiturate Complexes of All Five Alkali Metals Li–Cs Open
A systematic study has been conducted on barbiturate complexes of all five alkali metals, Li–Cs, prepared from metal carbonates or hydroxides in an aqueous solution without other potential ligands present, varying the stoichiometric ratio …
View article: Extended Hydrogen-Bonded Molybdenum Arrays Derived from Carboxylic Acids and Dianilines: ROP Capability of the Complexes and Parent Acids and Dianilines
Extended Hydrogen-Bonded Molybdenum Arrays Derived from Carboxylic Acids and Dianilines: ROP Capability of the Complexes and Parent Acids and Dianilines Open
From reactions involving sodium molybdate and dianilines [2,2′-(NH2)C6H4]2(CH2)n (n = 0, 1, 2) and amino-functionalized carboxylic acids 1,2-(NH2)(CO2H)C6H4 or 2-H2NC6H3-1,4-(CO2H)2, in the presence of Et3N and Me3SiCl, products adopting H…
View article: The Sensitivity of Structure to Ionic Radius and Reaction Stoichiometry. A Crystallographic Study of Metal Coordination and Hydrogen Bonding in Barbiturate Complexes of All Five Alkali Metals Li–Cs
The Sensitivity of Structure to Ionic Radius and Reaction Stoichiometry. A Crystallographic Study of Metal Coordination and Hydrogen Bonding in Barbiturate Complexes of All Five Alkali Metals Li–Cs Open
A systematic study has been conducted on barbiturate complexes of all five alkali metals Li–Cs prepared from the metal carbonates or hydroxide in aqueous solution without other potential ligands present, varying the stoichiometric ratio of…
View article: Expanding Luminescence Horizons in Macropolyhedral Heteroboranes
Expanding Luminescence Horizons in Macropolyhedral Heteroboranes Open
Luminescence is observed in three novel macropolyhedral nineteen‐ and eighteen‐vertex chalcogenaboranes: Se 2 B 17 H 17 ( 1 ), SeB 17 H 19 ( 3 ) and SeB 18 H 20 ( 4 ). This led us to the recognition that previously published macropolyhedra…
View article: Expanding Luminescence Horizons in Macropolyhedral Heteroboranes
Expanding Luminescence Horizons in Macropolyhedral Heteroboranes Open
Luminescence is observed in three novel macropolyhedral nineteen‐ and eighteen‐vertex chalcogenaboranes: Se 2 B 17 H 17 ( 1 ), SeB 17 H 19 ( 3 ) and SeB 18 H 20 ( 4 ). This led us to the recognition that previously published macropolyhedra…
View article: Synthesis and crystal structure of a silver(I) 6-methylmercaptopurine riboside complex
Synthesis and crystal structure of a silver(I) 6-methylmercaptopurine riboside complex Open
Silver nitrate reacts with 6-methylmercaptopurine riboside (6-MMPR) in aqueous solution containing methanol and dimethyl sulfoxide at room temperature to give a colourless crystalline complex, namely, bis(6-methylmercaptopurine riboside-κ …
View article: CCDC 2326554: Experimental Crystal Structure Determination
CCDC 2326554: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Investigating the Competitive Factors of Metal–Anion Coordination, Coordination by Water, and Hydrogen Bonding in Complexes of Cyanuric Acid with the Alkaline Earth Metals
Investigating the Competitive Factors of Metal–Anion Coordination, Coordination by Water, and Hydrogen Bonding in Complexes of Cyanuric Acid with the Alkaline Earth Metals Open
A survey of the trends in metal–ligand coordination and hydrogen bonding has been carried out on complexes of singly deprotonated cyanuric acid CY− and alkaline earth metals, synthesised from aqueous solution and characterised by X-ray cry…
View article: CCDC 2326555: Experimental Crystal Structure Determination
CCDC 2326555: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305192: Experimental Crystal Structure Determination
CCDC 2305192: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305202: Experimental Crystal Structure Determination
CCDC 2305202: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305198: Experimental Crystal Structure Determination
CCDC 2305198: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305201: Experimental Crystal Structure Determination
CCDC 2305201: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305193: Experimental Crystal Structure Determination
CCDC 2305193: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305199: Experimental Crystal Structure Determination
CCDC 2305199: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305195: Experimental Crystal Structure Determination
CCDC 2305195: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305200: Experimental Crystal Structure Determination
CCDC 2305200: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305196: Experimental Crystal Structure Determination
CCDC 2305196: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305194: Experimental Crystal Structure Determination
CCDC 2305194: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2305197: Experimental Crystal Structure Determination
CCDC 2305197: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Investigating the Competitive Factors of Metal-Anion Coordination, Coordination by Water, and Hydrogen Bonding in Complexes of Cyanuric Acid with the Alkaline Earth Metals
Investigating the Competitive Factors of Metal-Anion Coordination, Coordination by Water, and Hydrogen Bonding in Complexes of Cyanuric Acid with the Alkaline Earth Metals Open
A survey of the trends in metal-ligand coordination and hydrogen bonding has been carried out on complexes of singly deprotonated cyanuric acid CY− and alkaline earth metals, synthesised from aqueous solution and characterised by X-ray cry…
View article: Alkali Metal Complexes of Phosphine–Borane-Substituted Benzyl Ligands and Their Application in the Synthesis of B–H···Sn Stabilized Dialkylstannylenes
Alkali Metal Complexes of Phosphine–Borane-Substituted Benzyl Ligands and Their Application in the Synthesis of B–H···Sn Stabilized Dialkylstannylenes Open
The benzyl-substituted phosphine–boranes PhCH2P(BH3)R2 [R = iPr (1H), Ph (2H), Cy (3H)] are accessible through either the reaction between R2PCl and PhCH2MgBr, followed by treatment with BH3·SMe2 or the reaction between R2P(BH)3Li and PhCH…
View article: CCDC 2306310: Experimental Crystal Structure Determination
CCDC 2306310: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306312: Experimental Crystal Structure Determination
CCDC 2306312: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2306313: Experimental Crystal Structure Determination
CCDC 2306313: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …