Xinwu Ba
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View article: Emerging Photo-Initiating Systems in Coatings from Molecular Engineering Perspectives
Emerging Photo-Initiating Systems in Coatings from Molecular Engineering Perspectives Open
Photoinitiators (PIs) are pivotal in enabling energy-efficient, spatiotemporally controlled photopolymerization for coatings. To address application-specific demands of coatings, diverse systems of Norrish-Type I (e.g., oxime esters, acylp…
View article: Tandem Suzuki Polymerization/Heck Cyclization Reaction to Form Ladder-Type 9,9′-Bifluorenylidene-Based Conjugated Polymer
Tandem Suzuki Polymerization/Heck Cyclization Reaction to Form Ladder-Type 9,9′-Bifluorenylidene-Based Conjugated Polymer Open
The synthesis of ladder-type 9,9′-bifluorenylidene-based conjugated polymer is reported. Unlike the typical synthetic strategy, the new designed ladder-type conjugated polymer is achieved via tandem Suzuki polymerization/Heck cyclization r…
View article: Synthesis of Hyperbranched Flame Retardants with Varied Branched Chains’ Rigidity and Performance of Modified Epoxy Resins
Synthesis of Hyperbranched Flame Retardants with Varied Branched Chains’ Rigidity and Performance of Modified Epoxy Resins Open
To overcome the high flammability and brittleness of epoxy resins without sacrificing their glass transition temperature (Tg) and mechanical properties, three epoxy-terminated hyperbranched flame retardants (EHBFRs) with a rigid central co…
View article: Aminated halloysite/Jute/phenol-formaldehyde composites with enhanced mechanical properties, improved lightweight character and lowered fire hazard
Aminated halloysite/Jute/phenol-formaldehyde composites with enhanced mechanical properties, improved lightweight character and lowered fire hazard Open
Organic fiber can be used as reinforcement in polymeric products, but usually aggravates the burden on fire hazard. On the other hand, the addition of nonflammable inorganic particles would bring concerns to the demand of lightweight. In t…
View article: Binding and inhibitory activities: A novel oral therapeutic agent for the treatment of hyperphosphataemia rats
Binding and inhibitory activities: A novel oral therapeutic agent for the treatment of hyperphosphataemia rats Open
Novel oral therapeutic agents based on inhibition or binding activity without adverse events in CKD patients are urgently needed. Here, 5/6 nephrectomy (NX) rats were used to construct a CKD model. Aminated cellulose (AC711), which is meta…
View article: Pyrene-functionalized halloysite nanotubes for simultaneously detecting and separating Hg(ii) in aqueous media: A comprehensive comparison on interparticle and intraparticle excimers
Pyrene-functionalized halloysite nanotubes for simultaneously detecting and separating Hg(ii) in aqueous media: A comprehensive comparison on interparticle and intraparticle excimers Open
The development of a facile approach to simultaneously detect and separate Hg( ii ) ions in an aqueous solution is a challenging topic in the chemosensing field. Herein, we focus on constructing the Hg( ii )-sensitive fluorescence “turn-on…
View article: Large Eddy Simulation of N-Heptane Premixed Flame in Low Temperature Ignition Regime
Large Eddy Simulation of N-Heptane Premixed Flame in Low Temperature Ignition Regime Open
This paper presents a Large Eddy Simulation (LES) study of the effect of low temperature chemistry on the structure and propagation of n-heptane/air turbulent premixed flame with transport Probability Density Function (t-PDF) model based o…
View article: Novel Chemical Cross-Linked Ionogel Based on Acrylate Terminated Hyperbranched Polymer with Superior Ionic Conductivity for High Performance Lithium-Ion Batteries
Novel Chemical Cross-Linked Ionogel Based on Acrylate Terminated Hyperbranched Polymer with Superior Ionic Conductivity for High Performance Lithium-Ion Batteries Open
A new family of chemical cross-linked ionogel is successfully synthesized by photopolymerization of hyperbranched aliphatic polyester with acrylate terminal groups in an ionic liquid of 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF…
View article: CCDC 1818252: Experimental Crystal Structure Determination
CCDC 1818252: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis and Characterization of Fully Conjugated Ladder Naphthalene Bisimide Copolymers
Synthesis and Characterization of Fully Conjugated Ladder Naphthalene Bisimide Copolymers Open
Fully conjugated ladder copolymers have attracted considerable attention due to their unique fused-ring structure and optoelectronic properties. In this study, two fully conjugated ladder naphthalene diimide (NDI) copolymers, P(NDI-CZL) an…
View article: Facile construction of a hyperbranched poly(acrylamide) bearing tetraphenylethene units: a novel fluorescence probe with a highly selective and sensitive response to Zn<sup>2+</sup>
Facile construction of a hyperbranched poly(acrylamide) bearing tetraphenylethene units: a novel fluorescence probe with a highly selective and sensitive response to Zn<sup>2+</sup> Open
A novel fluorescent HPEAM-TPEAH, possessing a highly selective and sensitive response to Zn2+, was synthesized using RAFT.
View article: Investigation of a halloysite-based fluorescence probe with a highly selective and sensitive “turn-on” response upon hydrogen peroxide
Investigation of a halloysite-based fluorescence probe with a highly selective and sensitive “turn-on” response upon hydrogen peroxide Open
Inorganic halloysite nanotubes (HNTs) were modified with an organic fluorescein derivative (PA) to prepare HNTs-based hybrid fluorescence probe (HNTs-PA).
View article: Synthesis, characterization and fluorescent properties of water-soluble glycopolymer bearing curcumin pendant residues
Synthesis, characterization and fluorescent properties of water-soluble glycopolymer bearing curcumin pendant residues Open
Curcumin is a potential natural anticancer drug with low oral bioavailability because of poor water solubility. The aqueous solubility of curcumin is enhanced by means of modification with the carbohydrate units. Polymerization of the curc…
View article: The Synthesis of Backbone Thermo and pH Responsive Hyperbranched Poly(Bis(N,N-Propyl Acryl Amide))s by RAFT
The Synthesis of Backbone Thermo and pH Responsive Hyperbranched Poly(Bis(N,N-Propyl Acryl Amide))s by RAFT Open
Hyperbranched poly(methylene-bis-acrylamide), poly(bis(N,N-propyl acryl amide)) (HPNPAM) and poly(bis(N,N-butyl acryl amide)) were synthesized by reversible addition-fragmentation chain transfer polymerization. HPNPAMs showed lower critica…
View article: Synthesis of TiO <sub>2</sub> nanoparticles in the PAMAM hydrogen network template
Synthesis of TiO <sub>2</sub> nanoparticles in the PAMAM hydrogen network template Open
Intramolecular nanocavities in polyamidoamine (PAMAM) are usually used as a good template to synthesize nanoparticles. In this paper, TiO 2 nanoparticles were prepared successfully by the interspaces of the hydrogen network between PAMAM. …
View article: Synthesis and Characterization of Alternating Polymers Incorporating Boron-Chelated Heterochrysene Units
Synthesis and Characterization of Alternating Polymers Incorporating Boron-Chelated Heterochrysene Units Open
The novel boron-chelated π-conjugated polymers named as BF2-poly and BPh2-poly were synthesized by a feasible condensation-chelation strategy. First, conjugated polymers bearing Boc group were prepared by using palladium-catalyzed Suzuki–M…