Xinquan Hu
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View article: Enantiodivergent Rh‐Catalyzed Reductive Hydroformylation of Alkenyl Boronic Esters
Enantiodivergent Rh‐Catalyzed Reductive Hydroformylation of Alkenyl Boronic Esters Open
We herein report the first enantioselective Rh‐catalyzed reductive hydroformylation of alkenyl boronic esters. By employing either “camouflage” or “direct” reductive AHF strategy, enantiodivergent synthesis of chiral γ ‐boryl alcohols has …
View article: 2-(5-Phenylpyrazol-3-yl)-8-arylimino-5,6,7-trihydroquinolyliron Chlorides as Precatalysts for Ethylene Oligomerization
2-(5-Phenylpyrazol-3-yl)-8-arylimino-5,6,7-trihydroquinolyliron Chlorides as Precatalysts for Ethylene Oligomerization Open
A series of 2-(5-phenylpyrazol-3-yl)-8-arylimino-5,6,7-trihydroquinolyliron chlorides (Fe1–Fe6) have been prepared and characterized by FT-IR spectra and elemental analysis. In single-crystal X-ray crystallography, Fe4 shows a distorted tr…
View article: Pd(<scp>ii</scp>)-Catalyzed enantioselective C–H olefination toward the synthesis of <i>P</i>-stereogenic phosphinamides
Pd(<span>ii</span>)-Catalyzed enantioselective C–H olefination toward the synthesis of <i>P</i>-stereogenic phosphinamides Open
A Pd( ii )-catalyzed enantioselective C–H olefination toward the synthesis of P -stereogenic phosphines is reported.
View article: CCDC 2120756: Experimental Crystal Structure Determination
CCDC 2120756: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2120760: Experimental Crystal Structure Determination
CCDC 2120760: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235251: Experimental Crystal Structure Determination
CCDC 2235251: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2054900: Experimental Crystal Structure Determination
CCDC 2054900: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2054901: Experimental Crystal Structure Determination
CCDC 2054901: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Response of Wue of Maize at Ear Stage to the Coupling Effect of Co2 and Temperature
Response of Wue of Maize at Ear Stage to the Coupling Effect of Co2 and Temperature Open
View article: Phosphine-Free Nnn-Manganese(Ii) Catalyzed C-Alkylation of Methyl N-Heteroarenes Via Borrowing Hydrogen
Phosphine-Free Nnn-Manganese(Ii) Catalyzed C-Alkylation of Methyl N-Heteroarenes Via Borrowing Hydrogen Open
View article: CCDC 2106748: Experimental Crystal Structure Determination
CCDC 2106748: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Recent Advance of Ketones Synthesis from Carboxylic Esters
Recent Advance of Ketones Synthesis from Carboxylic Esters Open
Carboxylic esters are widely obtained, low-cost and readily available.Their conversions have attracted widespread attention.Ketones are important synthetic intermediates, which can be used to synthesize complicated drug molecules and funct…
View article: Pd(II)-Catalyzed Enantioselective C—H Olefination of 2-(Arylsulfinyl)pyridines through Kinetic Resolution
Pd(II)-Catalyzed Enantioselective C—H Olefination of 2-(Arylsulfinyl)pyridines through Kinetic Resolution Open
A Pd(II)-catalyzed enantioselective C-H olefination of 2-(arylsulfinyl)pyridines through kinetic resolution is developed.A wide range of chiral sulfoxides were prepared in good to high yields and selectivity (up to 99% ee, s-factor of up t…
View article: CCDC 2105336: Experimental Crystal Structure Determination
CCDC 2105336: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2105337: Experimental Crystal Structure Determination
CCDC 2105337: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2106747: Experimental Crystal Structure Determination
CCDC 2106747: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Chromosome‐level assembly of the <i>Neolamarckia cadamba</i> genome provides insights into the evolution of cadambine biosynthesis
Chromosome‐level assembly of the <i>Neolamarckia cadamba</i> genome provides insights into the evolution of cadambine biosynthesis Open
SUMMARY Neolamarckia cadamba (Roxb.), a close relative of Coffea canephora and Ophiorrhiza pumila , is an important traditional medicine in Southeast Asia. Three major glycosidic monoterpenoid indole alkaloids (MIAs), cadambine and its der…
View article: CCDC 2087029: Experimental Crystal Structure Determination
CCDC 2087029: Experimental Crystal Structure Determination Open
View article: CCDC 2043312: Experimental Crystal Structure Determination
CCDC 2043312: Experimental Crystal Structure Determination Open
View article: CCDC 2054348: Experimental Crystal Structure Determination
CCDC 2054348: Experimental Crystal Structure Determination Open
View article: A chromatography-free and aqueous waste-free process for thioamide preparation with Lawesson’s reagent
A chromatography-free and aqueous waste-free process for thioamide preparation with Lawesson’s reagent Open
After completing the thio-substitution with Lawesson’s reagent, ethanol was found to be effective in the decomposition of the inherent stoichiometric six-membered-ring byproduct from the Lawesson’s reagent to a highly polarized diethyl thi…
View article: Bis(imino)-6,7-dihydro-5<i>H</i>-quinoline-cobalt complexes as highly active catalysts for the formation of vinyl-terminated PE waxes; steps towards inhibiting deactivation pathways through targeted ligand design
Bis(imino)-6,7-dihydro-5<i>H</i>-quinoline-cobalt complexes as highly active catalysts for the formation of vinyl-terminated PE waxes; steps towards inhibiting deactivation pathways through targeted ligand design Open
Narrowly dispersed PE waxes with high levels of vinyl functionality are produced using the depicted cobalt polymerization catalysts.
View article: A Column-Free and Aqueous Waste-Free Process for Thioamide Preparation with Lawesson’s reagent
A Column-Free and Aqueous Waste-Free Process for Thioamide Preparation with Lawesson’s reagent Open
After completing thio-substitution with the Lawesson’s reagent, ethanol was found to be able to efficiently decompose the inherent stoichiometric six-membered-ring by-product from the Lawesson’s reagent to a highly polarized diethyl thioph…
View article: CCDC 1911076: Experimental Crystal Structure Determination
CCDC 1911076: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Highly Linear Polyethylenes Achieved Using Thermo-Stable and Efficient Cobalt Precatalysts Bearing Carbocyclic-Fused NNN-Pincer Ligand
Highly Linear Polyethylenes Achieved Using Thermo-Stable and Efficient Cobalt Precatalysts Bearing Carbocyclic-Fused NNN-Pincer Ligand Open
Six examples of 2-(1-arylimino)ethyl-9-arylimino-5,6,7,8-tetrahydrocycloheptapyridine-cobalt(II) chloride complexes, [2-(1-ArN)C2H3-9-ArN-5,6,7,8-C5H8C5H3N]CoCl2, (Ar = 2-(C5H9)-6-MeC6H3 Co1, 2-(C6H11)-6-MeC6H3 Co2, 2-(C8H15)-6-MeC6H3 Co3,…
View article: Selectivity Effects on <i>N</i>,<i>N</i>,<i>N</i>′-Cobalt Catalyzed Ethylene Dimerization/Trimerization Dictated through Choice of Aluminoxane Cocatalyst
Selectivity Effects on <i>N</i>,<i>N</i>,<i>N</i>′-Cobalt Catalyzed Ethylene Dimerization/Trimerization Dictated through Choice of Aluminoxane Cocatalyst Open
The file associated with this record is under embargo until 12 months after publication, in accordance with the publisher's self-archiving policy. The full text may be available through the publisher links provided above.
View article: CCDC 1879149: Experimental Crystal Structure Determination
CCDC 1879149: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1897124: Experimental Crystal Structure Determination
CCDC 1897124: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1897125: Experimental Crystal Structure Determination
CCDC 1897125: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: <i>gem</i>-Dimethyl-substituted bis(imino)dihydroquinolines as thermally stable supports for highly active cobalt catalysts that produce linear PE waxes
<i>gem</i>-Dimethyl-substituted bis(imino)dihydroquinolines as thermally stable supports for highly active cobalt catalysts that produce linear PE waxes Open
Linear polyethylene waxes with vinyl content can be generated using the depicted N,N,N′-Co catalyst at an industrially relevant operating temperature of 70 °C.