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View article: 4,10-Bis(pyridin-2-ylmethyl)-1,7-dithia-4,10-diazoniacyclododecane bis(perchlorate)
4,10-Bis(pyridin-2-ylmethyl)-1,7-dithia-4,10-diazoniacyclododecane bis(perchlorate) Open
The asymmetric unit of the title compound C(20)H(30)N(4)S(2) (+). 2ClO(4) (-) comprises one macrocyclic cation and two perchlorate anions. In the cation, one of the protonated H atoms bound to the amide N atom is involved in an intra-molec…
View article: CCDC 845426: Experimental Crystal Structure Determination
CCDC 845426: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Bis[μ<sub>2</sub>-bis(diphenylphosphino)methane]bis(μ<sub>2</sub>-ethane-1,2-dithiolato)-μ<sub>4</sub>-sulfido-μ<sub>2</sub>-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate
Bis[μ<sub>2</sub>-bis(diphenylphosphino)methane]bis(μ<sub>2</sub>-ethane-1,2-dithiolato)-μ<sub>4</sub>-sulfido-μ<sub>2</sub>-sulfido-disulfidodimolybdenum(V)disilver(I) dimethylformamide trisolvate Open
Treatment of [Et(4)N](2)[(edt)(2)Mo(2)S(2)(μ-S)(2)] (edt = ethane-dithio-l-ate) with two equivalents of Ag(CH(3)CN)(4)ClO(4) in the presence of bis-(diphenyl-phosphino)methane (dppm) ligand gives rise to the title tetra-nuclear cluster, [A…
View article: Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ<sub>3</sub>-sulfido-dimolybdenum(V)dicopper(I)
Tetraethylammonium dicyanidobis(ethane-1,2-dithiolato)tetra-μ<sub>3</sub>-sulfido-dimolybdenum(V)dicopper(I) Open
The title compound, (C(8)H(20)N)(2)[Cu(2)Mo(2)(C(2)H(4)S(2))(2)(CN)(2)S(4)], is a sulfide-bridged tetranuclear complex in which the complex anion comprises one [(edt)(2)Mo(2)S(2)(μ-S)(2)](2-) unit (edt = ethanedithiol-ate) and two CuCN uni…
View article: Di-μ-sulfato-bis{[bis(3,5-dimethylpyrazol-1-yl)methane]copper(II)}
Di-μ-sulfato-bis{[bis(3,5-dimethylpyrazol-1-yl)methane]copper(II)} Open
The mol-ecule of the title compound, [Cu(2)(SO(4))(2)(C(11)H(16)N(4))(2)], sits on a center of symmetry. The Cu(II) atom has a distorted trigonal-bipyramidal coordination geometry comprising three O atoms of the two symmetry-related SO(4) …