Yoshinao Oosawa
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View article: The Layered Composite Crystal Structure of the Ternary Sulfide, (SnS)<sub>1.15</sub>TaS<sub>2</sub> “SnTaS<sub>3</sub>”
The Layered Composite Crystal Structure of the Ternary Sulfide, (SnS)<sub>1.15</sub>TaS<sub>2</sub> “SnTaS<sub>3</sub>” Open
The crystal structure of a new type of ternary sulfide with a layered composite crystal structure, (SnS) 1.15 TaS 2 was studied by the single crystal X-ray diffraction method. The precession photograph of (SnS) 1.15 TaS 2 revealed the comp…
View article: Photocatalytic hydrogen and oxygen evolution using ternary niobates and relationship between photocatalytic properties and physical properties.
Photocatalytic hydrogen and oxygen evolution using ternary niobates and relationship between photocatalytic properties and physical properties. Open
三元系ニナブ酸塩の光触媒的性質をつぎの方法で測定した:1)電子供与体 (HCOOH, CH3OH) 存在下における光触媒的水素発生速度の測定;2)電子受容体 (KBrO3) 存在下における光触媒的酸素発生速度の測定;3)紫外-可視拡散反射スペクトルを用いたパンドギャップエネルギー(Eg)の測定。フラットバンドポテンシャル (Vfb) と価電子帯の頂上のポテンシャル (Vtop of VB) を三元系ニオブ酸塩の Mulliken の電気陰性度と Eg から推箕した。三元系チ…
View article: Effect of surface hydroxyl density on photocatalytic oxygen generation in aqueous TiO2 suspensions
Effect of surface hydroxyl density on photocatalytic oxygen generation in aqueous TiO2 suspensions Open
TiO2 powders with various surface hydroxyl densities have been prepared by thermal treatment (600–1000 °C), and their activity for photocatalytic oxygen evolution in aqueous suspensions has been investigated in the presence of various elec…
View article: Kinetics of the Catalytic Decomposition of Hydrogen Iodide in the Magnesium–Iodine Thermochemical Cycle
Kinetics of the Catalytic Decomposition of Hydrogen Iodide in the Magnesium–Iodine Thermochemical Cycle Open
The decomposition of hydrogen iodide serves as the hydrogen-evolution step in several thermochemical water-splitting cycles, including the Magnesium–Iodine cycle. A kinetic analysis of the catalytic decomposition of hydrogen iodide has bee…
View article: Crystal and Molecular Structure of a Chelating Ylide Complex of Palladium: [(Benzoylmethylene)diphenyl-2-(diphenylphosphino)ethylphosphorane]dichloropalladium(II) Toluene Solvate
Crystal and Molecular Structure of a Chelating Ylide Complex of Palladium: [(Benzoylmethylene)diphenyl-2-(diphenylphosphino)ethylphosphorane]dichloropalladium(II) Toluene Solvate Open
The crystal structure of the title compound was solved by single-crystal X-ray diffraction techniques. Crystals are monoclinic, space group P21/c, with cell dimensions a=13.39(5), b=16.88(1), c=19.85(6) Å, β=123.54(1)°, Z=4. The final R wa…