Chunying Duan
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View article: Molecular Device-Inspired Reticular Framework for Modulating Anisotropic Electron Transfer in Synergistic Photoredox and Transition-Metal Catalysis
Molecular Device-Inspired Reticular Framework for Modulating Anisotropic Electron Transfer in Synergistic Photoredox and Transition-Metal Catalysis Open
View article: Dual Cofactor Co‐Decorated Covalent Organic Framework as an Electron Transfer Regulator for Biomimetic Dioxygen Activation
Dual Cofactor Co‐Decorated Covalent Organic Framework as an Electron Transfer Regulator for Biomimetic Dioxygen Activation Open
Mimicking the synergy of multiple active sites of oxygenase to achieve selective O 2 activation for various oxidations is a very challenging but meaningful task. By introducing the reduced nicotinamide adenine dinucleotide (NADH) active si…
View article: Heme/NADH Mimics Co‐Decorated Allosteric Capsules for Regulating Oxygen Activation and Upregulating Intracellular Methionine Depletion
Heme/NADH Mimics Co‐Decorated Allosteric Capsules for Regulating Oxygen Activation and Upregulating Intracellular Methionine Depletion Open
Stimuli‐responsive behaviors in living bodies provide the fundamental principles for developing switchable architectures that apply to the direct function regulation. Herein, by incorporating both the µ ‐oxo bridged Fe III ‐porphyrins and …
View article: Encapsulating an iron complex in a heme and anthraquinone codecorated capsule for multiphoton C(sp3)−H bond oxygenation
Encapsulating an iron complex in a heme and anthraquinone codecorated capsule for multiphoton C(sp3)−H bond oxygenation Open
The allosteric effect in proteins controls biological function omnipotently, but simulating both the regulatory functions and catalytic processes of analogues faces marked challenges. By encapsulating a non-heme FeIII-complex in…
View article: Carbon Dots@Silica-Based Dual-Emission Ratiometric Fluorescent Sensor for Highly Selective Detection of Cu2+ and Thiram
Carbon Dots@Silica-Based Dual-Emission Ratiometric Fluorescent Sensor for Highly Selective Detection of Cu2+ and Thiram Open
View article: Carbon Dots@Silica-Based Dual-Emission Ratiometric Fluorescent Sensor for Highly Selective Detection of Cu2+ and Thiram
Carbon Dots@Silica-Based Dual-Emission Ratiometric Fluorescent Sensor for Highly Selective Detection of Cu2+ and Thiram Open
View article: Selective Arene Photonitration via Iron-Complex β-Homolysis
Selective Arene Photonitration via Iron-Complex β-Homolysis Open
Nitroaromatics, as an important member and source of nitrogen-containing aromatics, is bringing enormous economic benefits in fields of pharmaceuticals, dyes, pesticides, functional materials, fertilizers, and explosives. Nonetheless, the …
View article: Modulating the Aggregation States of a Pd<sub>6</sub>L<sub>4</sub> Cage for Selectivity Flipping during the Stereo‐Divergent Semi‐Hydrogenation of Alkynes
Modulating the Aggregation States of a Pd<sub>6</sub>L<sub>4</sub> Cage for Selectivity Flipping during the Stereo‐Divergent Semi‐Hydrogenation of Alkynes Open
An enzyme‐mimicking catalytic system has been established using a singular palladium‐based octahedral cage as the supramolecular reactor, deftly unlocking the off‐on‐off selectivity in the semi‐hydrogenation of alkynes. Water serves as a c…
View article: Energy transfer-mediated multiphoton synergistic excitation for selective C(sp3)–H functionalization with coordination polymer
Energy transfer-mediated multiphoton synergistic excitation for selective C(sp3)–H functionalization with coordination polymer Open
View article: Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping
Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping Open
The challenging synthesis of thermodynamic-unfavored cis-olefins through catalytic cross-coupling reactions requires the synergistic interaction of substrate-activating units and configuration-regulating catalysts. Successfully hitting the…
View article: Ruthenium(II)-Catalyzed C–H Allylation of N,N-Dialkylthiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination
Ruthenium(II)-Catalyzed C–H Allylation of N,N-Dialkylthiobenzamides with Allyl Methyl Carbonate by Sulfur Coordination Open
This report describes a Ru(II)-catalyzed C–H allylation of N,N-dialkylthiobenzamides with allyl methyl carbonate. The reaction is carried out using [RuCl2(p-cymene)]2 in the presence of Cu(OAc)2 and Ag2O. This method represents the first e…
View article: Long wavelength near-infrared and red light-driven consecutive photo-induced electron transfer for highly effective photoredox catalysis
Long wavelength near-infrared and red light-driven consecutive photo-induced electron transfer for highly effective photoredox catalysis Open
Consecutive photoinduced electron transfer (conPET) processes accumulate the energies of two photons to overcome the thermodynamic limit of traditional photoredox catalysis. However, the excitation wavelength of conPET systems mainly focus…
View article: A Host–Guest Platform for Highly Efficient, Quantitative, and Rapid Detection of Nitroreductase
A Host–Guest Platform for Highly Efficient, Quantitative, and Rapid Detection of Nitroreductase Open
Nitroreductase (NTR) is an enzyme expressed at an abnormally high level in solid tumors, which is associated with the hypoxia level in tumors. The establishment of a high-performance and convenient fluorescent platform for the fast monitor…
View article: Modifying Parallel Excitations into One Framework for C( <i>sp</i> <sup>3</sup> )─H Bond Activation with Energy Combined More Than Two Photons
Modifying Parallel Excitations into One Framework for C( <i>sp</i> <sup>3</sup> )─H Bond Activation with Energy Combined More Than Two Photons Open
Natural photosynthesis enzymes utilize energies of several photons for challenging oxidation of water, whereas artificial photo‐catalysis typically involves only single‐photon excitation. Herein, a multiphoton excitation strategy is report…
View article: Evolution of Surface Chemistry in Two‐Dimensional MXenes: From Mixed to Tunable Uniform Terminations
Evolution of Surface Chemistry in Two‐Dimensional MXenes: From Mixed to Tunable Uniform Terminations Open
Surface chemistry of MXenes is of great interest as the terminations can define the intrinsic properties of this family of materials. The diverse and tunable terminations also distinguish MXenes from many other 2D materials. Conventional f…
View article: Evolution of Surface Chemistry in Two‐Dimensional MXenes: From Mixed to Tunable Uniform Terminations
Evolution of Surface Chemistry in Two‐Dimensional MXenes: From Mixed to Tunable Uniform Terminations Open
Surface chemistry of MXenes is of great interest as the terminations can define the intrinsic properties of this family of materials. The diverse and tunable terminations also distinguish MXenes from many other 2D materials. Conventional f…
View article: Confinement Effect in Metal–Organic Framework Cu<sub>3</sub>(<b>BTC</b>)<sub>2</sub> for Enhancing Shape Selectivity of Radical Difunctionalization of Alkenes
Confinement Effect in Metal–Organic Framework Cu<sub>3</sub>(<b>BTC</b>)<sub>2</sub> for Enhancing Shape Selectivity of Radical Difunctionalization of Alkenes Open
The radical difunctionalization of alkenes plays a vital role in pharmacy, but the conventional homogeneous catalytic systems are challenging in selectivity and sustainability to afford the target molecules. Herein, the famous readily avai…
View article: Electron transport chain-inspired coordination polymers for macroscopic spatiotemporal scales of charge separation and transport in photocatalysis
Electron transport chain-inspired coordination polymers for macroscopic spatiotemporal scales of charge separation and transport in photocatalysis Open
Inspired by electron transport chain, segregated dye stacking was assembled in a coordination polymer, which endowed photocatalysis with macroscopic spatiotemporal charge separation and transport for reactions in separated biomimetic compa…
View article: A visible-light-catalyzed sulfonylation reaction of an aryl selenonium salt <i>via</i> an electron donor–acceptor complex
A visible-light-catalyzed sulfonylation reaction of an aryl selenonium salt <i>via</i> an electron donor–acceptor complex Open
An efficient synthesis of sulfone structures through selenonium salts and sodium sulfinates was developed.
View article: CCDC 2265265: Experimental Crystal Structure Determination
CCDC 2265265: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2265266: Experimental Crystal Structure Determination
CCDC 2265266: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2144004: Experimental Crystal Structure Determination
CCDC 2144004: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2144003: Experimental Crystal Structure Determination
CCDC 2144003: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2144005: Experimental Crystal Structure Determination
CCDC 2144005: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: In‐Situ‐Grown Cu Dendrites Plasmonically Enhance Electrocatalytic Hydrogen Evolution on Facet‐Engineered Cu<sub>2</sub>O
In‐Situ‐Grown Cu Dendrites Plasmonically Enhance Electrocatalytic Hydrogen Evolution on Facet‐Engineered Cu<sub>2</sub>O Open
Herein, facet‐engineered Cu 2 O nanostructures are synthesized by wet chemical methods for electrocatalytic HER, and it is found that the octahedral Cu 2 O nanostructures with exposed crystal planes of (111) (O‐Cu 2 O) has the best hydroge…
View article: CCDC 2263257: Experimental Crystal Structure Determination
CCDC 2263257: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2252175: Experimental Crystal Structure Determination
CCDC 2252175: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2218139: Experimental Crystal Structure Determination
CCDC 2218139: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2076326: Experimental Crystal Structure Determination
CCDC 2076326: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1938743: Experimental Crystal Structure Determination
CCDC 1938743: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …