Yan Suffren
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View article: Magneto‐Optical Correlations in a High Symmetry Dysprosium Complex Reveal an Almost “Ideal Non‐SMM” and Orange‐to‐Red Dy<sup>III</sup>‐Based Emitter
Magneto‐Optical Correlations in a High Symmetry Dysprosium Complex Reveal an Almost “Ideal Non‐SMM” and Orange‐to‐Red Dy<sup>III</sup>‐Based Emitter Open
The importance of investigating high‐symmetry systems in order to reveal properties that would otherwise be concealed in less symmetrical compounds is demonstrated. This is particularly true for discrete coordination complexes that tend to…
View article: Crystalline Phase Induction Strategy for the Design of Luminescent Lanthanide Coordination Polymers: Toward Plastic Waste Recycling
Crystalline Phase Induction Strategy for the Design of Luminescent Lanthanide Coordination Polymers: Toward Plastic Waste Recycling Open
Reactions in water between a lanthanide chloride and the disodium salt of tetrachloro-phthalate (tcpa2-) lead to a family of isostructural coordination polymers with the general chemical formula [Ln2(tcpa)3(H2O)4]∞ with Ln = La-Pr (Family …
View article: Multiphoton excitation and energy transfer pathways in Mn <sup>2+</sup> –sulfonyl calixarene complexes
Multiphoton excitation and energy transfer pathways in Mn <sup>2+</sup> –sulfonyl calixarene complexes Open
Sensitization of Mn 2+ ions via one- and two-photon excitation.
View article: Luminescence and Single‐Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near‐Planar Tricoordinate Ytterbium(III) Amide
Luminescence and Single‐Molecule Magnet Properties in Ideal Symmetry Compounds: Example of a Near‐Planar Tricoordinate Ytterbium(III) Amide Open
We are reporting on the use of a low‐coordinate Yb III amide with near‐ideal planar trigonal [Yb{N(SiMe 3 ) 2 } 3 ] ( 1 ) and on a bipyramidal trigonal derivative [Yb{N(SiMe 2 H) 2 } 3 ⋅ (thf) 2 ] ( 2 ) that constitute quintessential cases…
View article: Halogen-Bonds-Based Strategy for the Design of Highly Luminescent Lanthanide Coordination Polymers as Taggants for Plastic Waste Sorting
Halogen-Bonds-Based Strategy for the Design of Highly Luminescent Lanthanide Coordination Polymers as Taggants for Plastic Waste Sorting Open
Reactions in water between a lanthanide ion and 3,4,5,6-tetrachloro-phthalate lead to a new series of iso-structural coordination polymers with general chemical formula [Ln2(tcpa)3(H2O)6]∞ with Ln = Eu-Yb plus Y. The crystal structure has …
View article: Investigation and control of metallogel formation for the deposition of supramolecular nanotubes of single-chain magnets
Investigation and control of metallogel formation for the deposition of supramolecular nanotubes of single-chain magnets Open
Metallogels are versatile and intriguing objects that can be used as media for the deposition of extended molecular architectures on surfaces.
View article: Strong coupling between spin crossover, fluorescence and viscoelasticity in soft nanocomposites
Strong coupling between spin crossover, fluorescence and viscoelasticity in soft nanocomposites Open
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View article: Luminescence and mechanoluminescence of Ba4Si6O16:Eu2+, <i>RE</i> phosphors
Luminescence and mechanoluminescence of Ba4Si6O16:Eu2+, <i>RE</i> phosphors Open
The luminescence properties of green Ba4Si6O16:Eu2+, rare-earths (RE) (RE = Sc, Y, La and Lu except Pm) phosphors are reported. Their long-lasting phosphorescence is discussed in view of trap depths and concentrations determined from therm…
View article: CCDC 971080: Experimental Crystal Structure Determination
CCDC 971080: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 971129: Experimental Crystal Structure Determination
CCDC 971129: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Synthesis, Luminescence and Energy Transfer Properties of Ce3+/Mn2+ Co-Doped Calcium Carbodiimide Phosphors
Synthesis, Luminescence and Energy Transfer Properties of Ce3+/Mn2+ Co-Doped Calcium Carbodiimide Phosphors Open
Ce3+-doped and Ce3+/Mn2+ co-doped calcium carbodiimide (CaCN2) phosphors were synthesized from doped calcium carbonate and carbon nitride by a solid-state reaction at 700 °C under flowing NH3 using a very short reaction time (1 h). The sam…
View article: Lanthanide-Based Coordination Polymers Molecular Alloys Stability: A Thermochemical Approach
Lanthanide-Based Coordination Polymers Molecular Alloys Stability: A Thermochemical Approach Open
In this study, we investigate the thermodynamics of lanthanide-based coordination polymer molecular alloys. We demonstrate that if lanthanide ions have many chemical similarities, the solubility of homo-lanthanide-based coordination polyme…
View article: CCDC 2178278: Experimental Crystal Structure Determination
CCDC 2178278: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Metallogels: a novel approach for the nanostructuration of single-chain magnets
Metallogels: a novel approach for the nanostructuration of single-chain magnets Open
Supramolecular nanotubes of single-chain magnets (SCMs) can be assembled in gel phase and transferred intact on surface.
View article: Luminance and Brightness: Application to Lanthanide-Based Coordination Polymers
Luminance and Brightness: Application to Lanthanide-Based Coordination Polymers Open
Measuring the luminance of lanthanide-based coordination polymers under UV excitation is of prime importance for many technological applications. This study highlights that the quantum yield gives no information about the luminescence inte…
View article: Investigation of Intermetallic Energy Transfers in Lanthanide Coordination Polymers Molecular Alloys: Case Study of Trimesate-Based Compounds
Investigation of Intermetallic Energy Transfers in Lanthanide Coordination Polymers Molecular Alloys: Case Study of Trimesate-Based Compounds Open
Reactions in water at ambient temperature and pressure between a lanthanide ion and benzene-1,3,5-tricarboxylate (or trimesate) lead to two series of iso-structural coordination polymers. Their general chemical formula is [Ln(tma)(H2O)6]∞ …
View article: Synthesis, Crystal Structure, and Luminescence Properties of the Iso-Reticular Series of Lanthanide Coordination Polymers Synthesized from Hexa-Lanthanide Molecular Precursors
Synthesis, Crystal Structure, and Luminescence Properties of the Iso-Reticular Series of Lanthanide Coordination Polymers Synthesized from Hexa-Lanthanide Molecular Precursors Open
Microwave-assisted reactions in DMSO, between a hexa-lanthanide octahedral complex ([Ln6(μ6-O)(μ3-OH)8(NO3)6(H2O)12·2NO3·2H2O] with Ln = Nd-Yb plus Y) and either 3-halogenobenzoic acid (hereafter symbolized by 3-xbH with x = f or c for flu…