Yannick Gama
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View article: Asymmetric Oxidation of Enol Derivatives to α-Alkoxy Carbonyls Using Iminium Salt Catalysts: A Synthetic and Computational Study
Asymmetric Oxidation of Enol Derivatives to α-Alkoxy Carbonyls Using Iminium Salt Catalysts: A Synthetic and Computational Study Open
We report herein the first examples of asymmetric oxidation of enol ether and ester substrates using iminium salt organocatalysis, affording moderate to excellent enantioselectivities of up to 98% ee for tetralone-derived substrates in the…
View article: Studies towards the synthesis of tagetitoxin
Studies towards the synthesis of tagetitoxin Open
The natural product tagetitoxin is a phytotoxin which was first isolated from the bacterium Pseudomonas syringae pv. tagetis in 1981. Tagetitoxin is an inhibitor of chloroplast and bacteria RNAP and also selectively inhibits RNAP III in eu…