Yan‐Xia Zhao
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View article: Enhanced Water Decontamination by Goethite-Cu0 Activating Oxygen: The Dominance of Valence State in Reactive Oxygen Species Generation
Enhanced Water Decontamination by Goethite-Cu0 Activating Oxygen: The Dominance of Valence State in Reactive Oxygen Species Generation Open
View article: Reactivity of Atomic Oxygen Radical Anions in Metal Oxide Clusters
Reactivity of Atomic Oxygen Radical Anions in Metal Oxide Clusters Open
Atomic oxygen radical anion (O⋅ − ) represents an important type of reactive centre that exists in both chemical and biological systems. Gas‐phase atomic clusters can be studied under isolated and well controlled conditions. Studies of O⋅ …
View article: Conversion of Methane at Room Temperature Mediated by the Ta–Ta σ-Bond
Conversion of Methane at Room Temperature Mediated by the Ta–Ta σ-Bond Open
Metal-metal bonds constitute an important type of reactive centers for chemical transformation; however, the availability of active metal-metal bonds being capable of converting methane under mild conditions, the holy grail in catalysis, r…
View article: Size-dependent reactivity of chromium oxide cluster anions (CrO3)1−4O− towards alkanes
Size-dependent reactivity of chromium oxide cluster anions (CrO3)1−4O− towards alkanes Open
The reactivity of chromium oxide cluster anions (CrO3)1−4O− towards low carbon (C1−C4) alkanes has been experimentally investigated at 298 K by employing a homemade ship-lock-type reactor coupled with a time-of-flight mass spectrometer. Th…
View article: CCDC 2158167: Experimental Crystal Structure Determination
CCDC 2158167: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Frontispiece: Conversion of CH<sub>4</sub> Catalyzed by Gas Phase Ions Containing Metals
Frontispiece: Conversion of CH<sub>4</sub> Catalyzed by Gas Phase Ions Containing Metals Open
This Review discusses the coupling reactions of CH4 molecules and of CH4 with other substrates (O2, O3, N2O, CO2, and H2O) catalyzed by ions containing metals. The mechanistic details for generation of C−C coupling and C−O coupling product…
View article: Conversion of Methane with Oxygen to Produce Hydrogen Catalyzed by Triatomic Rh<sub>3</sub><sup>–</sup> Cluster Anion
Conversion of Methane with Oxygen to Produce Hydrogen Catalyzed by Triatomic Rh<sub>3</sub><sup>–</sup> Cluster Anion Open
Metal catalysts, especially noble metals, have frequently been prepared upon downsizing from nanoparticles to subnanoclusters to catalyze the important reaction of partial oxidation of methane (POM) in order to optimize the catalytic perfo…
View article: Catalytic Co‐Conversion of CH<sub>4</sub> and CO<sub>2</sub> Mediated by Rhodium–Titanium Oxide Anions RhTiO<sub>2</sub><sup>−</sup>
Catalytic Co‐Conversion of CH<sub>4</sub> and CO<sub>2</sub> Mediated by Rhodium–Titanium Oxide Anions RhTiO<sub>2</sub><sup>−</sup> Open
Catalytic co‐conversion of methane with carbon dioxide to produce syngas (2 H 2 +2 CO) involves complicated elementary steps and almost all the elementary reactions are performed at the same high temperature conditions in practical thermoc…
View article: Gemeinsame katalytische Umsetzung von CH<sub>4</sub> und CO<sub>2</sub> durch Rhodium‐Titanoxid‐Anionen RhTiO<sub>2</sub><sup>−</sup>
Gemeinsame katalytische Umsetzung von CH<sub>4</sub> und CO<sub>2</sub> durch Rhodium‐Titanoxid‐Anionen RhTiO<sub>2</sub><sup>−</sup> Open
Die gemeinsame katalytische Umsetzung von Methan mit Kohlendioxid zur Erzeugung von Synthesegas (2 H 2 +2 CO) umfasst komplizierte Elementarschritte, und fast alle Elementarreaktionen werden praktisch bei den gleichen Hochtemperaturbedingu…
View article: CCDC 1957114: Experimental Crystal Structure Determination
CCDC 1957114: Experimental Crystal Structure Determination Open
View article: CCDC 1961898: Experimental Crystal Structure Determination
CCDC 1961898: Experimental Crystal Structure Determination Open
View article: CCDC 1961896: Experimental Crystal Structure Determination
CCDC 1961896: Experimental Crystal Structure Determination Open
View article: CCDC 1957506: Experimental Crystal Structure Determination
CCDC 1957506: Experimental Crystal Structure Determination Open
View article: CCDC 1957507: Experimental Crystal Structure Determination
CCDC 1957507: Experimental Crystal Structure Determination Open
View article: CCDC 1957505: Experimental Crystal Structure Determination
CCDC 1957505: Experimental Crystal Structure Determination Open
View article: Inside Back Cover: Activity of Atomically Precise Titania Nanoparticles in CO Oxidation (Angew. Chem. Int. Ed. 24/2019)
Inside Back Cover: Activity of Atomically Precise Titania Nanoparticles in CO Oxidation (Angew. Chem. Int. Ed. 24/2019) Open
Understanding how properties evolve in atomically precise nanoparticles as their size changes atom by atom is critical for designing functional nanomaterials. In their Communication on page 8002 ff., Y.-X. Zhao, X.-L. Ding and co-workers s…
View article: CCDC 1813406: Experimental Crystal Structure Determination
CCDC 1813406: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A breakthrough in direct conversion of methane to oxygenates under mild conditions
A breakthrough in direct conversion of methane to oxygenates under mild conditions Open
View article: CCDC 1585099: Experimental Crystal Structure Determination
CCDC 1585099: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1500226: Experimental Crystal Structure Determination
CCDC 1500226: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1456032: Experimental Crystal Structure Determination
CCDC 1456032: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1456037: Experimental Crystal Structure Determination
CCDC 1456037: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1456035: Experimental Crystal Structure Determination
CCDC 1456035: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Methane activation by gold-doped titanium oxide cluster anions with closed-shell electronic structures
Methane activation by gold-doped titanium oxide cluster anions with closed-shell electronic structures Open
The complementary active sites of Au + and O 2− ions on gold-doped titanium oxide clusters activate methane under thermal collision conditions.
View article: CCDC 1456036: Experimental Crystal Structure Determination
CCDC 1456036: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1456031: Experimental Crystal Structure Determination
CCDC 1456031: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1060120: Experimental Crystal Structure Determination
CCDC 1060120: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …