Yong‐Qiang Tu
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View article: SPA-PNN ligand for the kinetic resolution of carbocyclic and heterocyclic spiranes by asymmetric hydrogenation
SPA-PNN ligand for the kinetic resolution of carbocyclic and heterocyclic spiranes by asymmetric hydrogenation Open
The chiral carbocyclic and heterocyclic spirane scaffolds are widely present in natural products and pharmaceutical molecules. Efficient, concise, and enantioenriched synthesis of these structures is a significant objective in both academi…
View article: Enhancing Generalizability in Molecular Conformation Generation with METRIZATION-Informed Geometric Diffusion Pretraining
Enhancing Generalizability in Molecular Conformation Generation with METRIZATION-Informed Geometric Diffusion Pretraining Open
Diffusion-based generative models have recently excelled in generating molecular conformations but struggled with the generalization issue -- models trained on one dataset may produce meaningless conformations on out-of-distribution molecu…
View article: Acupuncture clinical hotspots and trends from 2013 to 2022: A bibliometric and visualized analysis
Acupuncture clinical hotspots and trends from 2013 to 2022: A bibliometric and visualized analysis Open
Through bibliometric analysis, trends in international acupuncture clinical development, key research areas, and current scientific issues were identified based on literature published from 2013 to 2022. Literature on acupuncture in clinic…
View article: In-depth insight into structure-reactivity/regioselectivity relationship of Lewis acid catalyzed cascade 4πe-cyclization/dicycloexpansion reaction
In-depth insight into structure-reactivity/regioselectivity relationship of Lewis acid catalyzed cascade 4πe-cyclization/dicycloexpansion reaction Open
View article: Regional Weather Variable Predictions by Machine Learning With Near-Surface Observational and Atmospheric Numerical Data
Regional Weather Variable Predictions by Machine Learning With Near-Surface Observational and Atmospheric Numerical Data Open
View article: Regional Weather Variable Predictions by Machine Learning with Near-Surface Observational and Atmospheric Numerical Data
Regional Weather Variable Predictions by Machine Learning with Near-Surface Observational and Atmospheric Numerical Data Open
Accurate and timely regional weather prediction is vital for sectors dependent on weather-related decisions. Traditional prediction methods, based on atmospheric equations, often struggle with coarse temporal resolutions and inaccuracies. …
View article: Atroposelective synthesis of biaxial bridged eight-membered terphenyls via a Co/SPDO-catalyzed aerobic oxidative coupling/desymmetrization of phenols
Atroposelective synthesis of biaxial bridged eight-membered terphenyls via a Co/SPDO-catalyzed aerobic oxidative coupling/desymmetrization of phenols Open
Bridged chiral biaryls are axially chiral compounds with a medium-sized ring connecting the two arenes. Compared with plentiful methods for the enantioselective synthesis of biaryl compounds, synthetic approaches for this subclass of bridg…
View article: Multistage Microstructured Ionic Skin for Real‐Time Vital Signs Monitoring and Human‐Machine Interaction
Multistage Microstructured Ionic Skin for Real‐Time Vital Signs Monitoring and Human‐Machine Interaction Open
Skin‐like electronics research aiming to mimic even surpass human‐like specific tactile cognition by operating perception‐to‐cognition‐to‐feedback of stimulus to build intelligent cognition systems for certain imperceptible or inappreciabl…
View article: Ni-Catalyzed Enantioselective Reductive Cross- and Homo-Coupling of Aryl Electrophiles: Synthesis of Axially Chiral Diaryl Dicarboxylates
Ni-Catalyzed Enantioselective Reductive Cross- and Homo-Coupling of Aryl Electrophiles: Synthesis of Axially Chiral Diaryl Dicarboxylates Open
View article: Multistage micro-structured ionic skin for real-time vital signs monitoring and human-machine interaction
Multistage micro-structured ionic skin for real-time vital signs monitoring and human-machine interaction Open
Skin-like electronics research aiming to mimic even surpass human-like specific tactile cognition by operating perception-to-cognition-to-feedback of stimulus to build intelligent cognition systems for certain imperceptible or inappreciabl…
View article: CCC pincer Ru complex-catalyzed C–H vinylation/6π-E-cyclization of aldimines for constructing 4 <i>H</i> -pyrido[1,2- <i>a</i> ]pyrimidines
CCC pincer Ru complex-catalyzed C–H vinylation/6π-E-cyclization of aldimines for constructing 4 <i>H</i> -pyrido[1,2- <i>a</i> ]pyrimidines Open
A convenient and efficient approach to construct a series of N -heteropolycycles using a unique CCC pincer NHC–Ru( iii )-catalyzed cascade C–H vinylation/6π-electrocyclization of pyridyl aldimines with unactivated vinyl bromides/triflates …
View article: CCDC 2286180: Experimental Crystal Structure Determination
CCDC 2286180: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2286182: Experimental Crystal Structure Determination
CCDC 2286182: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2286181: Experimental Crystal Structure Determination
CCDC 2286181: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267606: Experimental Crystal Structure Determination
CCDC 2267606: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267613: Experimental Crystal Structure Determination
CCDC 2267613: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267607: Experimental Crystal Structure Determination
CCDC 2267607: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267612: Experimental Crystal Structure Determination
CCDC 2267612: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267610: Experimental Crystal Structure Determination
CCDC 2267610: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267214: Experimental Crystal Structure Determination
CCDC 2267214: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267611: Experimental Crystal Structure Determination
CCDC 2267611: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267608: Experimental Crystal Structure Determination
CCDC 2267608: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2278859: Experimental Crystal Structure Determination
CCDC 2278859: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2267609: Experimental Crystal Structure Determination
CCDC 2267609: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Numerical simulation and experimental validation of deposited corners of any angle in direct ink writing
Numerical simulation and experimental validation of deposited corners of any angle in direct ink writing Open
Direct ink writing (DIW) belongs to material extrusion based additive manufacturing (MEAM) and the molding quality of deposited corners has an impact on the geometrical quality of three dimensional (3D) parts fabricated by DIW. To fully un…
View article: An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade
An efficient approach to angular tricyclic molecular architecture via Nazarov-like cyclization and double ring-expansion cascade Open
View article: CCDC 1983099: Experimental Crystal Structure Determination
CCDC 1983099: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1983097: Experimental Crystal Structure Determination
CCDC 1983097: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1983096: Experimental Crystal Structure Determination
CCDC 1983096: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Cu(<scp>ii</scp>)/SPDO complex catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6
Cu(<span>ii</span>)/SPDO complex catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6 Open
A novel classical kinetic resolution of Baeyer–Villiger oxidation catalyzed by a Cu( ii )/SPDO complex with excellent enantioselectivity, regioselectivity and wide substrate scope is reported for the first time and explore the synthetic ap…