Yong Rui Poh
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View article: Mode-specific versus local heating effects in infrared laser driven reactions
Mode-specific versus local heating effects in infrared laser driven reactions Open
Using an infrared laser to control a molecule's reactivity by targeting specific vibrational modes has long been of interest to chemists. Rapid intramolecular vibrational energy redistribution (IVR) in molecules poses significant challenge…
View article: Photoredox Catalysis with Spin Magnetic Field Effects: A Scheme for Chiral Resolution
Photoredox Catalysis with Spin Magnetic Field Effects: A Scheme for Chiral Resolution Open
Quantities that break both mirror symmetry and time-reversal symmetry, such as the orbital angular momentum, are known to connect molecular chirality with an applied magnetic field. This concept has led to observations such as magneto-chir…
View article: Stirring effects on AC-induced chemoselectivity in reversible electrochemical reactions
Stirring effects on AC-induced chemoselectivity in reversible electrochemical reactions Open
Bulk electrolysis presents a sustainable alternative to heat-driven chemical synthesis and modulating the applied potential across time, a process known as alternating current (AC) electrosynthesis, adds the possibility of chemoselectivity…
View article: Physico-chemical principles of AC electrosynthesis: reversible reactions
Physico-chemical principles of AC electrosynthesis: reversible reactions Open
Electrolysis integrates renewable energy into chemical manufacturing and is key towards sustainable chemistry. Controlling the waveform beyond direct current (DC) addresses the long-standing obstacle of chemoselectivity, yet it also expand…
View article: Alternant Hydrocarbon Diradicals as Optically Addressable Molecular Qubits
Alternant Hydrocarbon Diradicals as Optically Addressable Molecular Qubits Open
High-spin molecules allow for bottom-up qubit design and are promising platforms for magnetic sensing and quantum information science. Optical addressability of molecular electron spins has also been proposed in first-row transition-metal …
View article: Physico-chemical principles of AC electrosynthesis
Physico-chemical principles of AC electrosynthesis Open
Electrolysis integrates renewable energy into chemical manufacturing and is key towards sustainable chemistry. Controlling the waveform beyond direct current addresses the long-standing obstacle of chemoselectivity, yet it also expands the…
View article: Physico-chemical principles of AC electrosynthesis
Physico-chemical principles of AC electrosynthesis Open
Electrolysis integrates renewable energy into chemical manufacturing and is key towards sustainable chemistry. Controlling the waveform beyond direct current addresses the long-standing obstacle of chemoselectivity, yet it also expands the…
View article: Sub-wavelength chemical imaging of a modified reaction due to vibrational strong coupling
Sub-wavelength chemical imaging of a modified reaction due to vibrational strong coupling Open
This study explores the impact of vibrational strong coupling (VSC) on intrinsic physical and chemical properties of molecules within plasmonic nanocavities. We demonstrate how the formation of polariton states decreases the stage temperat…
View article: Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry
Swinging between shine and shadow: Theoretical advances on thermally activated vibropolaritonic chemistry Open
Polariton chemistry has emerged as an appealing branch of synthetic chemistry that promises mode selectivity and a cleaner approach to kinetic control. Of particular interest are the numerous experiments in which reactivity has been modifi…