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View article: Dynamic helical poly[4]helicene nanoribbon
Dynamic helical poly[4]helicene nanoribbon Open
The precise synthesis of helical graphene nanoribbons (GNRs) with a controlled handedness has a transformative potential as the promising chiral carbon materials. We now report the first synthesis of a dynamic helical poly[4]helicene nanor…
View article: Structural Characterization of a Desolvated Flexible Porous Coordination Polymer Using MicroED
Structural Characterization of a Desolvated Flexible Porous Coordination Polymer Using MicroED Open
Flexible porous coordination polymers (PCPs) and metal-organic frameworks (MOFs) that undergo structural changes upon guest removal/uptake have a wide range of potential applications. However, detailed characterization of the guest removal…
View article: Structural Characterization of a Desolvated Flexible Porous Coordination Polymer Using MicroED
Structural Characterization of a Desolvated Flexible Porous Coordination Polymer Using MicroED Open
Flexible porous coordination polymers (PCPs) and metal-organic frameworks (MOFs) that undergo structural changes upon guest removal/uptake have a wide range of potential applications. However, detailed characterization of the guest removal…
View article: An α-Helically Folded α-Aminoisobutyric Acid (Aib) Oligomer That Assembles into a Metal–Peptide Superhelical Nanotube
An α-Helically Folded α-Aminoisobutyric Acid (Aib) Oligomer That Assembles into a Metal–Peptide Superhelical Nanotube Open
α,α-Disubstituted α-amino acids such as α-aminoisobutyric acid (Aib), in their polymeric structures, are known to form a 310-helical conformation rather than an α-helical conformation, which is usually adopted by polymeric α-mon…
View article: Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction
Uncommon quadruple stacking topology in a honeycomb-sheet MOF compatible with through-space conduction Open
Quadruple stacking topology with an unusual threefold stacking periodicity among four honeycomb sheets was realized in a flexible, wavy honeycomb-sheet MOF (PMC-20).
View article: Synthesis of fully fused tetrapyrazinoporphyrazine polymers bearing three-dimensional structures controlled by steric repulsion
Synthesis of fully fused tetrapyrazinoporphyrazine polymers bearing three-dimensional structures controlled by steric repulsion Open
The synthesis and characterization of fused aromatic networks composed of zinc tetrapyrazinoporphyrazines are reported.
View article: Synthesis of fully fused tetrapyrazinoporphyrazine polymers bearing three-dimensional structures controlled by steric repulsion
Synthesis of fully fused tetrapyrazinoporphyrazine polymers bearing three-dimensional structures controlled by steric repulsion Open
The synthesis and characterization of fused aromatic networks composed of zinc tetrapyrazinoporphyrazines are reported. The steric repulsion of bulky substituents induced the formation of three-dimensional structures. Thus-obtained insolub…
View article: Ultrafast Luminescence Detection with Selective Adsorption of Carbon Disulfide in a Gold(I) Metal−Organic Framework
Ultrafast Luminescence Detection with Selective Adsorption of Carbon Disulfide in a Gold(I) Metal−Organic Framework Open
Although a widely used and important industrial chemical, carbon disulfide (CS 2 ) poses a number of hazards due to its volatility and toxicity. As such, the development of multifunctional materials for the selective capture and easy recog…
View article: Adsorptive-dissolution of O2 into the potential nanospace of a densely fluorinated metal-organic framework
Adsorptive-dissolution of O2 into the potential nanospace of a densely fluorinated metal-organic framework Open
Nanoporous solids, including metal-organic frameworks (MOFs), have long been known to capture small molecules by adsorption on their pore surfaces. Liquids are also known to accommodate small molecules by dissolution. These two processes h…
View article: Modulation of triplet quantum coherence by guest-induced structural changes in a flexible metal-organic framework
Modulation of triplet quantum coherence by guest-induced structural changes in a flexible metal-organic framework Open
Quantum sensing has the potential to improve the sensitivity of chemical sensing by exploiting the characteristics of qubits, which are sensitive to the external environment. Modulation of quantum coherence by target analytes can be a usef…
View article: Modulation of triplet quantum coherence by guest-induced structural changes in a flexible metal-organic framework
Modulation of triplet quantum coherence by guest-induced structural changes in a flexible metal-organic framework Open
Quantum sensing using molecular qubits is expected to provide excellent sensitivity due to the proximity of the sensor to the target analyte. However, many molecular qubits are used at cryogenic temperatures, and how to make molecular qubi…
View article: Dual photoresponsive & water-triggered nitric oxide releasing materials based on rhodium-based metal-organic polyhedra
Dual photoresponsive & water-triggered nitric oxide releasing materials based on rhodium-based metal-organic polyhedra Open
The exogenous administration of nitric oxide (NO) is considered a potential therapeutic treatment against a great variety of diseases due to its significant role in multiple physiological functions. Due to the gaseous nature, short lifetim…
View article: Dual photoresponsive & water-triggered nitric oxide releasing materials based on rhodium-based metal-organic polyhedra
Dual photoresponsive & water-triggered nitric oxide releasing materials based on rhodium-based metal-organic polyhedra Open
The exogenous administration of nitric oxide (NO) is considered a potential therapeutic treatment against a great variety of diseases due to its significant role in multiple physiological functions. Due to the gaseous nature, short lifetim…
View article: CCDC 2235563: Experimental Crystal Structure Determination
CCDC 2235563: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235562: Experimental Crystal Structure Determination
CCDC 2235562: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235561: Experimental Crystal Structure Determination
CCDC 2235561: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235564: Experimental Crystal Structure Determination
CCDC 2235564: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235566: Experimental Crystal Structure Determination
CCDC 2235566: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235565: Experimental Crystal Structure Determination
CCDC 2235565: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: NMR spectrum prediction for dynamic molecules by machine learning: A case study of trefoil knot molecule
NMR spectrum prediction for dynamic molecules by machine learning: A case study of trefoil knot molecule Open
Nuclear magnetic resonance (NMR) spectroscopy is one of the indispensable techniques in chemistry because it enables us to obtain accurate information on the chemical, electronic, and dynamic properties of molecules. Computational simulati…
View article: CCDC 2237412: Experimental Crystal Structure Determination
CCDC 2237412: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2237424: Experimental Crystal Structure Determination
CCDC 2237424: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2237091: Experimental Crystal Structure Determination
CCDC 2237091: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2151633: Experimental Crystal Structure Determination
CCDC 2151633: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2237092: Experimental Crystal Structure Determination
CCDC 2237092: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235244: Experimental Crystal Structure Determination
CCDC 2235244: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235242: Experimental Crystal Structure Determination
CCDC 2235242: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235241: Experimental Crystal Structure Determination
CCDC 2235241: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2150478: Experimental Crystal Structure Determination
CCDC 2150478: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2235246: Experimental Crystal Structure Determination
CCDC 2235246: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …