Yu‐Lin Lu
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View article: Anionic Hofmeister Effect Differentiated Subcellular Distributions of pH‐Responsive Metal–Organic Cages for Tumor Photodynamic Immunotherapy
Anionic Hofmeister Effect Differentiated Subcellular Distributions of pH‐Responsive Metal–Organic Cages for Tumor Photodynamic Immunotherapy Open
The precise control of subcellular distribution offers significant advantages for advancing the understanding of cellular biology and targeted theranostics strategies. Herein, we report anionic Hofmeister effect triggered allostery of pH‐r…
View article: Enantioselective dearomative ortho-cycloaddition transformation of unactivated arenes by cage-confined visible-light photocatalysis
Enantioselective dearomative ortho-cycloaddition transformation of unactivated arenes by cage-confined visible-light photocatalysis Open
Photoinduced dearomatization of arenes is a powerful strategy in organic synthesis to disrupt the stable aromaticity; however, the asymmetric dearomatization photocatalysis of unactivated arenes remains highly challenging and rare. Herein …
View article: Photo‐ or Electrochemical N‐P <i>Cross</i>‐Hetero‐Dehydrogenative Couplings between Amines and Phosphonothioates
Photo‐ or Electrochemical N‐P <i>Cross</i>‐Hetero‐Dehydrogenative Couplings between Amines and Phosphonothioates Open
We present two distinct synthetic approaches for the synthesis of diversely functionalized thiophosphoramidates, employing either photochemical or electrochemical strategies via N−P cross ‐hetero‐dehydrogenative coupling. Both methods prov…
View article: A Highly Charged Positive Cage Causes Simultaneous Enhancement of Type‐II and O<sub>2</sub>‐Independent‐Type‐I Photodynamic Therapy via One‐/Two‐Photon Stimulation and Tumor Immunotherapy via PANoptosis and Ferroptosis
A Highly Charged Positive Cage Causes Simultaneous Enhancement of Type‐II and O<sub>2</sub>‐Independent‐Type‐I Photodynamic Therapy via One‐/Two‐Photon Stimulation and Tumor Immunotherapy via PANoptosis and Ferroptosis Open
To solve the oxygen dependence problem of photodynamic therapy (PDT), it is critical to explore photosensitizers that do not rely on O 2 molecule to generate reactive oxygen species (ROS). Herein, a stable cationic metal‐organic cage [Pd 6…
View article: Photocatalysis Meets Confinement: An Emerging Opportunity for Photoinduced Organic Transformations
Photocatalysis Meets Confinement: An Emerging Opportunity for Photoinduced Organic Transformations Open
The self‐assembled metal‐organic cages (MOCs) have been evolved as a paradigm of enzyme‐mimic catalysts since they are able to synergize multifunctionalities inherent in metal and organic components and constitute microenvironments charact…
View article: Cover Picture: Dynamic Stereochemistry of M<sub>8</sub>Pd<sub>6</sub> Supramolecular Cages Based on Metal‐Center Lability for Differential Chiral Induction, Resolution, and Recognition (Angew. Chem. Int. Ed. 2/2024)
Cover Picture: Dynamic Stereochemistry of M<sub>8</sub>Pd<sub>6</sub> Supramolecular Cages Based on Metal‐Center Lability for Differential Chiral Induction, Resolution, and Recognition (Angew. Chem. Int. Ed. 2/2024) Open
A fruitful stereochemical scenario of metal-organic cages (MOCs) is demonstrated by Cheng-Yong Su et al. in their Research Article (e202315053). Based on the intrinsic dynamics of different metal ions, it is shown how the dynamic stereoche…
View article: Titelbild: Dynamic Stereochemistry of M<sub>8</sub>Pd<sub>6</sub> Supramolecular Cages Based on Metal‐Center Lability for Differential Chiral Induction, Resolution, and Recognition (Angew. Chem. 2/2024)
Titelbild: Dynamic Stereochemistry of M<sub>8</sub>Pd<sub>6</sub> Supramolecular Cages Based on Metal‐Center Lability for Differential Chiral Induction, Resolution, and Recognition (Angew. Chem. 2/2024) Open
A fruitful stereochemical scenario of metal-organic cages (MOCs) is demonstrated by Cheng-Yong Su et al. in their Research Article (e202315053). Based on the intrinsic dynamics of different metal ions, it is shown how the dynamic stereoche…
View article: Cage-confined multilevel-selective [2+2] cross-photocycloaddition beyond enantioselectivity and biomimicry
Cage-confined multilevel-selective [2+2] cross-photocycloaddition beyond enantioselectivity and biomimicry Open
The last decades witnessed an exciting renaissance in photochemistry where the asymmetric photocatalysis has emerged as a promising solution for stereoselectivity control in radical intermediates. However, a significant hurdle still lies i…
View article: Enantioselective dearomative ortho-cycloaddition transformation of inactive arenes by cage-confined photocatalysis
Enantioselective dearomative ortho-cycloaddition transformation of inactive arenes by cage-confined photocatalysis Open
Photoinduced dearomatization of arenes is a powerful strategy in organic synthesis to disrupt the stable aromaticity; however, the asymmetric dearomatization photocatalysis of inactive arenes remains highly challenging and rare. Herein we …
View article: CCDC 2259926: Experimental Crystal Structure Determination
CCDC 2259926: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A robust protein-mimicking metallo-amine cage showing proton-driven allostery with water as the effector
A robust protein-mimicking metallo-amine cage showing proton-driven allostery with water as the effector Open
The allosteric effect is omnipresent in proteins with two distinct binding sites communicating over a distance to control biological functions and complex processes, which drives an everlasting innovation of molecular-scale devices and mac…
View article: Performance of Continuous Hydrogen Production from Perhydro Benzyltoluene by Catalytic Distillation and Heat Integration Concepts with a Fuel Cell
Performance of Continuous Hydrogen Production from Perhydro Benzyltoluene by Catalytic Distillation and Heat Integration Concepts with a Fuel Cell Open
The benzyltoluene‐based liquid organic hydrogen carrier (LOHC) system enables the safe transport and loss‐free storage of hydrogen. At least 26% of the lower heating value of the released hydrogen, however, has to be invested in form of he…
View article: Acidic open-cage solution containing basic cage-confined nanospaces for multipurpose catalysis
Acidic open-cage solution containing basic cage-confined nanospaces for multipurpose catalysis Open
The nanoscale chemical spaces inherent in porous organic/coordination cages or solid/liquid materials have been continuously explored for their nanoconfinement effect on selective adsorption and reaction of small gas or organic molecules. …
View article: CCDC 1893013: Experimental Crystal Structure Determination
CCDC 1893013: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1892986: Experimental Crystal Structure Determination
CCDC 1892986: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1892985: Experimental Crystal Structure Determination
CCDC 1892985: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1892982: Experimental Crystal Structure Determination
CCDC 1892982: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1892991: Experimental Crystal Structure Determination
CCDC 1892991: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1892990: Experimental Crystal Structure Determination
CCDC 1892990: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 1892983: Experimental Crystal Structure Determination
CCDC 1892983: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Innenrücktitelbild: The Redox Coupling Effect in a Photocatalytic Ru<sup>II</sup>‐Pd<sup>II</sup> Cage with TTF Guest as Electron Relay Mediator for Visible‐Light Hydrogen‐Evolving Promotion (Angew. Chem. 7/2020)
Innenrücktitelbild: The Redox Coupling Effect in a Photocatalytic Ru<sup>II</sup>‐Pd<sup>II</sup> Cage with TTF Guest as Electron Relay Mediator for Visible‐Light Hydrogen‐Evolving Promotion (Angew. Chem. 7/2020) Open
Ein Nanospace-Kopplungseffekt in einem photokatalytischen RuII-PdII-Käfig basiert auf dem Redox-Wechselspiel zwischen einem TTF-Gastmolekül und dem photosensibilisierenden Wirt in der H2-Entwicklung mit sichtbarem Licht. Wie C.-Y. Su und M…
View article: Well-distributed Pt-nanoparticles within confined coordination interspaces of self-sensitized porphyrin metal–organic frameworks: synergistic effect boosting highly efficient photocatalytic hydrogen evolution reaction
Well-distributed Pt-nanoparticles within confined coordination interspaces of self-sensitized porphyrin metal–organic frameworks: synergistic effect boosting highly efficient photocatalytic hydrogen evolution reaction Open
An effective strategy for the fabrication of an efficient HER photocatalyst of Pt@Pd-PCN222(Hf) has been reported.
View article: A dissolution-diffusion sliding model for soft rock grains with hydro-mechanical effect
A dissolution-diffusion sliding model for soft rock grains with hydro-mechanical effect Open
The deformation and failure of soft rock affected by hydro-mechanical (HM) effect are one of the most concerns in geotechnical engineering, which are basically attributed to the grain sliding of soft rock. This study tried to develop a dis…
View article: CCDC 1834360: Experimental Crystal Structure Determination
CCDC 1834360: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …