Yuto Eguchi
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Design of Near-UV Photoluminescent Liquid-Crystalline Dimers: Roles of Fluorinated Aromatic Ring Position and Flexible Linker Open
Near-ultraviolet photoluminescence liquid-crystalline molecules (PLLCs) have attracted attention for temperature-responsive photoluminescence (PL) modulation and ON/OFF sensing under external stimuli. We recently developed mesogenic dimers…
View article: Synthesis of Janus All-<i>Cis</i> Tetrafluorocyclohexanes Carrying 1,4-Diether Motifs
Synthesis of Janus All-<i>Cis</i> Tetrafluorocyclohexanes Carrying 1,4-Diether Motifs Open
Nucleophilic aromatic substitutions (SNAr) of alkoxides on pentafluoroaryl ethers are explored as a first step in a synthesis sequence to generate all-cis 2,3,5,6-tetrafluorocyclohexyl-1,4-dialkyl ethers 1. The SNAr reaction was explored b…
(1E)-1,2-Diaryldiazene Derivatives Containing a Donor–π-Acceptor-Type Tolane Skeleton as Smectic Liquid–Crystalline Dyes Open
Considerable attention has been paid to (1E)-1,2-diaryldiazenes (azo dyes) possessing liquid–crystalline (LC) and optical properties because they can switch color through thermal phase transitions and photoisomerizations. Although multifun…