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View article: Microenvironment engineering unveils surface methoxy species origination in zeolite-catalyzed methanol chemistry under mild conditions
Microenvironment engineering unveils surface methoxy species origination in zeolite-catalyzed methanol chemistry under mild conditions Open
View article: Transition-Metal-Free Aluminosilicate Small-Pore Zeolites Upgrade Methane to Light Olefins
Transition-Metal-Free Aluminosilicate Small-Pore Zeolites Upgrade Methane to Light Olefins Open
Upgrading methane to value-added chemicals is significant but still challenging. Well-designed catalysts are required to activate methane. Extensive efforts have been dedicated to the catalytic conversion of methane over transition-metal-c…
View article: Free-Breathing Spirometer-Gated Proton Pencil Beam Scanning Radiotherapy - Maintain Tumor Coverage with Improved Organ-at-Risk Sparing
Free-Breathing Spirometer-Gated Proton Pencil Beam Scanning Radiotherapy - Maintain Tumor Coverage with Improved Organ-at-Risk Sparing Open
View article: Aluminum Distribution in Ferrierite Zeolites Influences the Performance of Methane Oxidation
Aluminum Distribution in Ferrierite Zeolites Influences the Performance of Methane Oxidation Open
Transition‐metal‐free aluminosilicate FER‐type zeolite has been demonstrated to effectively catalyze methane to methanol using N 2 O as the oxidant with distorted tetra‐coordinated aluminum (Al IV‐2 ) and penta‐coordinated aluminum (Al V )…
View article: Aluminum Distribution in Ferrierite Zeolites Influences the Performance of Methane Oxidation
Aluminum Distribution in Ferrierite Zeolites Influences the Performance of Methane Oxidation Open
Transition‐metal‐free aluminosilicate FER‐type zeolite has been demonstrated to effectively catalyze methane to methanol using N 2 O as the oxidant with distorted tetra‐coordinated aluminum (Al IV‐2 ) and penta‐coordinated aluminum (Al V )…
View article: Isomers of organic structure directing agent influence the Al distribution of AEI zeolite and catalytic performance in methane oxidation
Isomers of organic structure directing agent influence the Al distribution of AEI zeolite and catalytic performance in methane oxidation Open
View article: Physicochemical and in vitro digestive characteristics of water-soluble chickpea polysaccharides extracted using ultrasound and freeze-thaw methods
Physicochemical and in vitro digestive characteristics of water-soluble chickpea polysaccharides extracted using ultrasound and freeze-thaw methods Open
View article: Tandem of Sn‐MFI and TS‐1 Zeolites for Cooperatively Catalyzing Dihydroxyacetone Conversion to Methyl Lactate
Tandem of Sn‐MFI and TS‐1 Zeolites for Cooperatively Catalyzing Dihydroxyacetone Conversion to Methyl Lactate Open
Coordinating the ratio of Brønsted to Lewis acid sites in zeolite catalyst is crucial for the efficient conversion of dihydroxyacetone (DHA) to methyl lactate (ML) in methanol media due to the different acidic requirements of the four fund…
View article: Surpassing stoichiometric limitation for supra-multi-molar adsorption and separation of acid gases
Surpassing stoichiometric limitation for supra-multi-molar adsorption and separation of acid gases Open
View article: Asymmetric rotations slow down diffusion under confinement
Asymmetric rotations slow down diffusion under confinement Open
View article: Microenvironment perturbations driving methanol low-temperature conversion over zeolite
Microenvironment perturbations driving methanol low-temperature conversion over zeolite Open
Compared to methanol, dimethyl ether (DME) is a more ideal and attractive raw material for industrial applications. Typically, the industrially zeolite-catalyzed methanol dehydration to DME occurs at temperatures above 423 kelvin. Improvin…
View article: Anatase-Free Titanosilicate with Quasi-Pure Octahedral Titanium Species for Efficient Selective Oxidations with Hydrogen Peroxide
Anatase-Free Titanosilicate with Quasi-Pure Octahedral Titanium Species for Efficient Selective Oxidations with Hydrogen Peroxide Open
View article: Cu-LTL zeolite: an excellent high-temperature NH3-SCR catalyst with simple synthesis
Cu-LTL zeolite: an excellent high-temperature NH3-SCR catalyst with simple synthesis Open
View article: Cu-LTL zeolite: an excellent high-temperature NH3-SCR catalyst with simple synthesis
Cu-LTL zeolite: an excellent high-temperature NH3-SCR catalyst with simple synthesis Open
View article: Understanding water reaction pathways to control the hydrolytic reactivity of a Zn metal-organic framework
Understanding water reaction pathways to control the hydrolytic reactivity of a Zn metal-organic framework Open
View article: Synergy of pore size and silanols in an –SVR-type zeolite for efficient dynamic benzene/cyclohexane separation
Synergy of pore size and silanols in an –SVR-type zeolite for efficient dynamic benzene/cyclohexane separation Open
The efficient purification of cyclohexane is critical, serving as an essential feedstock to produce resins, nylon fibers and pharmaceutical intermediates. However, efficient purification remains a challenging task due to the similarity of …
View article: Breaking the stability limit of zeolite-based alkane dehydrogenation catalysts
Breaking the stability limit of zeolite-based alkane dehydrogenation catalysts Open
View article: Publisher Correction: Reply to: Diffusion anomaly in nanopores as a rich field for theorists and a challenge for experimentalists
Publisher Correction: Reply to: Diffusion anomaly in nanopores as a rich field for theorists and a challenge for experimentalists Open
View article: Facet‐Dependent Diversity of Pt−O Coordination for Pt<sub>1</sub>/CeO<sub>2</sub> Catalysts Achieved by Oriented Atomic Deposition
Facet‐Dependent Diversity of Pt−O Coordination for Pt<sub>1</sub>/CeO<sub>2</sub> Catalysts Achieved by Oriented Atomic Deposition Open
The surface chemistry of CeO 2 is dictated by the well‐defined facets, which exert great influence on the supported metal species and the catalytic performance. Here we report Pt 1 /CeO 2 catalysts exhibiting specific structures of Pt−O co…
View article: Triple Templates Directed Synthesis of Nitrogen‐Doped Hierarchically Porous Carbons from Pyridine Rich Monomer as Efficient and Reversible SO<sub>2</sub> Adsorbents
Triple Templates Directed Synthesis of Nitrogen‐Doped Hierarchically Porous Carbons from Pyridine Rich Monomer as Efficient and Reversible SO<sub>2</sub> Adsorbents Open
Herein, a variety of 2,6‐diaminopyridine (DAP) derived nitrogen‐doped hierarchically porous carbon (DAP‐NHPC‐T) prepared from carbonization‐induced structure transformation of DAP‐Zn‐SiO 2 ‐P123 nanocomposites are reported, which are facil…
View article: Reply to: Diffusion anomaly in nanopores as a rich field for theorists and a challenge for experimentalists
Reply to: Diffusion anomaly in nanopores as a rich field for theorists and a challenge for experimentalists Open
Here we provide a comprehensive response to the Matter Arising by Brandani et al. 1 .They pointed out that the experimental data presented in Fig. 5e of our published article 2 can be well-fitted by a first-order kinetic model (e.g., surfa…
View article: Confinement driving mechanism of surface methoxy species formation in mordenite zeolite: An interplay of different molecular factors
Confinement driving mechanism of surface methoxy species formation in mordenite zeolite: An interplay of different molecular factors Open
View article: On the Reactivity and Selectivity Trends in the Tandem Diels-Alder Cycloaddition and Dehydrative Aromatization between Dimethylfuran and Ethene Over Solid Acids
On the Reactivity and Selectivity Trends in the Tandem Diels-Alder Cycloaddition and Dehydrative Aromatization between Dimethylfuran and Ethene Over Solid Acids Open
View article: Mechanism of Confinement Compensating for Acid Strength: The Case of Aromatic Wheland Intermediate Formation In Zeolite Catalysis
Mechanism of Confinement Compensating for Acid Strength: The Case of Aromatic Wheland Intermediate Formation In Zeolite Catalysis Open
View article: Targeted Catalytic Cracking to Olefins (TCO): Reaction Mechanism, Production Scheme, and Process Perspectives
Targeted Catalytic Cracking to Olefins (TCO): Reaction Mechanism, Production Scheme, and Process Perspectives Open
Light olefins are important organic building blocks in the chemicals industry. The main low-carbon olefin production methods, such as catalytic cracking and steam cracking, have considerable room for improvement in their utilization of hyd…
View article: Rhodium nanoparticles supported on silanol-rich zeolites beyond the homogeneous Wilkinson’s catalyst for hydroformylation of olefins
Rhodium nanoparticles supported on silanol-rich zeolites beyond the homogeneous Wilkinson’s catalyst for hydroformylation of olefins Open
View article: Hyperloop-like diffusion of long-chain molecules under confinement
Hyperloop-like diffusion of long-chain molecules under confinement Open
The ultrafast transport of adsorbates in confined spaces is a goal pursued by scientists. However, diffusion will be generally slower in nano-channels, as confined spaces inhibit motion. Here we show that the movement of long-chain molecul…
View article: CSD 2225892: Experimental Crystal Structure Determination
CSD 2225892: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2225891: Experimental Crystal Structure Determination
CSD 2225891: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CCDC 2225890: Experimental Crystal Structure Determination
CCDC 2225890: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …