Lan‐Sun Zheng
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View article: Azulene in a Bowl: A Nonalternant Buckybowl With 5/7 Topology, Azulene‐Derived Properties, and Fullerene Complexation
Azulene in a Bowl: A Nonalternant Buckybowl With 5/7 Topology, Azulene‐Derived Properties, and Fullerene Complexation Open
Despite the intriguing potential of azulene‐embedded nanocarbons, their integration into curved buckybowl architectures has remained unexplored due to synthetic and stability challenges. Herein, we report an azulene‐containing buckybowl 6 …
View article: CCDC 2374496: Experimental Crystal Structure Determination
CCDC 2374496: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: High-Efficiency Synthesis of Giant Fullerenes from Single-Carbon Molecules
High-Efficiency Synthesis of Giant Fullerenes from Single-Carbon Molecules Open
View article: Synergistically activating N2 and CO2 at water microdroplet interfaces
Synergistically activating N2 and CO2 at water microdroplet interfaces Open
Nitrogen (N2), one of the most stable molecules, can be fixed naturally by lightning. However, industrial nitrogen fixation via the Haber–Bosch and Ostwald processes is energy-intensive and exacerbates carbon dioxide (CO2) emissions. Meanw…
View article: A Giant Chiral Metal-Peptide Cage with Five-Fold Symmetry
A Giant Chiral Metal-Peptide Cage with Five-Fold Symmetry Open
View article: CCDC 2392646: Experimental Crystal Structure Determination
CCDC 2392646: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Mechanistic Insights of Propane Dehydroaromatization Over Gallosilicate Mfi Zeolites by in Situ Capture of Fleeting Intermediates
Mechanistic Insights of Propane Dehydroaromatization Over Gallosilicate Mfi Zeolites by in Situ Capture of Fleeting Intermediates Open
View article: Polyacetylene formation under simulated circumstellar conditions
Polyacetylene formation under simulated circumstellar conditions Open
Carbon-chain molecules serve as precursors for complex molecules in the interstellar medium and act as indicators of both current physical conditions and past evolutionary trends. They hold significant importance in interstellar chemistry.…
View article: Corannulene‐Based Quintuple [6]/[7]Helicenes: Well‐Preserved Bowl Core, Inhibited Bowl Inversion and Supramolecular Assembly with Fullerenes
Corannulene‐Based Quintuple [6]/[7]Helicenes: Well‐Preserved Bowl Core, Inhibited Bowl Inversion and Supramolecular Assembly with Fullerenes Open
Herein, corannulene‐based quintuple [6]helicenes ( Q[6]H‐1 and Q[6]H‐2 ) and [7]helicene ( Q[7]H ) were synthesized via penta‐fold Heck and Mallory reaction. Notably, Q[7]H represents the highest reported helicene based on corannulene. X‐r…
View article: Bottom-up construction of chiral metal-peptide assemblies from metal cluster motifs
Bottom-up construction of chiral metal-peptide assemblies from metal cluster motifs Open
View article: Structurally Compact Penta(N,N‐diphenylamino)corannulene as Dopant‐free Hole Transport Materials for Stable and Efficient Perovskite Solar Cells
Structurally Compact Penta(N,N‐diphenylamino)corannulene as Dopant‐free Hole Transport Materials for Stable and Efficient Perovskite Solar Cells Open
Hole transport materials (HTMs) are essential for improving the stability and efficiency of perovskite solar cells (PSCs). In this study, we have designed and synthesized a novel organic small molecule HTM, cor‐(DPA) 5 , characterized by a…
View article: Achieving Bright Up‐Conversion Luminescence of Eu<sup>3</sup>⁺ and Tb<sup>3</sup>⁺ Ions within Coordination Polymers
Achieving Bright Up‐Conversion Luminescence of Eu<sup>3</sup>⁺ and Tb<sup>3</sup>⁺ Ions within Coordination Polymers Open
Achieving the up‐conversion luminescence (UCL) centered around trivalent lanthanide (Ln 3+ ) ions in coordination polymers (CPs) is extremely challenging. Herein, Yb 3 ⁺‐doped Ln‐CPs of [Eu 1‐x Yb x (pfbz) 2 (phen)Cl] (x = 0.3, namely 3 ; …
View article: Enhancement of Magneto-Chiral Dichroism Intensity by Chemical Design: The Key Role of Magnetic-Dipole Allowed Transitions
Enhancement of Magneto-Chiral Dichroism Intensity by Chemical Design: The Key Role of Magnetic-Dipole Allowed Transitions Open
Here we report on the strong magneto-chiral dichroism (MChD) detected through visible and near-infrared light absorption up to 5.0 T on {Er5Ni6} metal clusters obtained by reaction of enantiopure chiral ligands and Ni…
View article: Hierarchical Homochiral Assembly of Polyhedral Cage-Type Nanoclusters
Hierarchical Homochiral Assembly of Polyhedral Cage-Type Nanoclusters Open
View article: CCDC 1954098: Experimental Crystal Structure Determination
CCDC 1954098: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Achievement of a giant electromechanical conversion coefficient in a molecule-based ferroelectric
Achievement of a giant electromechanical conversion coefficient in a molecule-based ferroelectric Open
A molecule-based ferroelectric, possessing the highest d 33 × g 33 values recorded to date, achieves a record power density of 120 μW cm −2 in ferroelectric@PDMS PEGs, offering a viable method to enhance the electromechanical conversion co…
View article: Enhancing the performance of molecule-based piezoelectric sensors by optimizing their microstructures
Enhancing the performance of molecule-based piezoelectric sensors by optimizing their microstructures Open
A molecule-based ferroelectric [(CH 3 ) 3 NCH 2 CH 2 Br][GaBr 4 ] (1), with a d 33 value of 331 pC N −1 , was synthesized. The power density of the 1@S-PDMS piezoelectric sensor, featuring optimized microstructures, is up to 490 μW cm −2 .
View article: Single-molecule magnet behavior in heterometallic decanuclear [Ln<sub>2</sub>Fe<sub>8</sub>] (Ln = Y, Dy, Ho, Tb, Gd) coordination clusters
Single-molecule magnet behavior in heterometallic decanuclear [Ln<sub>2</sub>Fe<sub>8</sub>] (Ln = Y, Dy, Ho, Tb, Gd) coordination clusters Open
A family of coordination clusters Ln 2 Fe 8 has been prepared. The current work offers magneto-structural correlation models for investigating the single-molecule magnet behavior in lanthanide–iron systems.
View article: Soluble Gd6Cu24 clusters: effective molecular electrocatalysts for water oxidation
Soluble Gd6Cu24 clusters: effective molecular electrocatalysts for water oxidation Open
Two synthesized Gd6Cu24 clusters—Gd6Cu24-IM and Gd6Cu24-AC—exhibit excellent electrocatalytic water oxidation activity in an aqueous solution of a weak acid (pH = 6) and had turnover frequencies of 319 and 169 s −1 at 1.70 V, respectively.
View article: CCDC 2244839: Experimental Crystal Structure Determination
CCDC 2244839: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2039925: Experimental Crystal Structure Determination
CCDC 2039925: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2039924: Experimental Crystal Structure Determination
CCDC 2039924: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2039923: Experimental Crystal Structure Determination
CCDC 2039923: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2039922: Experimental Crystal Structure Determination
CCDC 2039922: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2039926: Experimental Crystal Structure Determination
CCDC 2039926: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2039921: Experimental Crystal Structure Determination
CCDC 2039921: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2279324: Experimental Crystal Structure Determination
CCDC 2279324: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2279323: Experimental Crystal Structure Determination
CCDC 2279323: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CSD 2213909: Experimental Crystal Structure Determination
CSD 2213909: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…
View article: CSD 2213908: Experimental Crystal Structure Determination
CSD 2213908: Experimental Crystal Structure Determination Open
An entry from the Inorganic Crystal Structure Database, the world’s repository for inorganic crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely availabl…