Guofu Zi
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View article: Synthesis and Reactivity of Lewis-Base-Supported Terminal Thorium Imido Metallocene, (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Th═N(<i>p</i>-tolyl)(dmap)<sub>2</sub>
Synthesis and Reactivity of Lewis-Base-Supported Terminal Thorium Imido Metallocene, (η<sup>5</sup>-C<sub>5</sub>Me<sub>5</sub>)<sub>2</sub>Th═N(<i>p</i>-tolyl)(dmap)<sub>2</sub> Open
Treatment of (η5-C5Me5)2ThMe2 (1) with p-tolylNH2 in toluene, in the presence of 4-dimethylaminopyridine (dmap), affords a Lewis base-supported terminal thorium imido metallocene, (η5-C5Me5)2Th═N(p-tolyl)(dmap)2 (5), alongside the release …
View article: Influence of 1,2,4-Tri-<i>tert</i>-butylcyclopentadienyl Ligand on the Reactivity of the Thorium Bipyridyl Metallocene [η<sup>5</sup>-1,2,4-(Me<sub>3</sub>C)<sub>3</sub>C<sub>5</sub>H<sub>2</sub>]<sub>2</sub>Th(bipy)]
Influence of 1,2,4-Tri-<i>tert</i>-butylcyclopentadienyl Ligand on the Reactivity of the Thorium Bipyridyl Metallocene [η<sup>5</sup>-1,2,4-(Me<sub>3</sub>C)<sub>3</sub>C<sub>5</sub>H<sub>2</sub>]<sub>2</sub>Th(bipy)] Open
The thorium bipyridyl metallocene (Cp3tBu)2Th(bipy) (1; Cp3tBu = η5-1,2,4-(Me3C)3C5H2) shows a rich reactivity toward a series of small molecules. For example, complex 1 may act as a synthon for the (Cp3tBu)2Th(II) fragment as illustrated …
View article: Intrinsic Reactivity of [<i>η</i><sup>5</sup>-1,3-(Me<sub>3</sub>C)<sub>2</sub>C<sub>5</sub>H<sub>3</sub>]<sub>2</sub>Th(bipy) toward Small Molecules
Intrinsic Reactivity of [<i>η</i><sup>5</sup>-1,3-(Me<sub>3</sub>C)<sub>2</sub>C<sub>5</sub>H<sub>3</sub>]<sub>2</sub>Th(bipy) toward Small Molecules Open
The reactivity of the thorium bipyridyl metallocene (Cp2tBu)2Th(bipy) (1; Cp2tBu = η5-1,3-(Me3C)2C5H3) toward a series of small molecules was explored, and the emerging reactivity pattern can be categorized: (1) It may act as a synthon for…
View article: Reactivity Studies on the Lewis Base-Supported Terminal Uranium Imido Metallocene [η<sup>5</sup>-1,3-(Me<sub>3</sub>C)<sub>2</sub>C<sub>5</sub>H<sub>3</sub>]<sub>2</sub>U═N(<i>p</i>-tolyl)(dmap)
Reactivity Studies on the Lewis Base-Supported Terminal Uranium Imido Metallocene [η<sup>5</sup>-1,3-(Me<sub>3</sub>C)<sub>2</sub>C<sub>5</sub>H<sub>3</sub>]<sub>2</sub>U═N(<i>p</i>-tolyl)(dmap) Open
Addition of p-tolylNH2 to a toluene solution of [η5-1,3-(Me3C)2C5H3]2UMe2 (1) in the presence of 4-dimethylaminopyridine (dmap) yields the Lewis base-supported terminal uranium imido metallocene, [η5-1,3-(Me3C)2C5H3]2U═N(p-tolyl)(dmap) (2)…
View article: Experimental and Computational Studies on Uranium Diazomethanediide Complexes
Experimental and Computational Studies on Uranium Diazomethanediide Complexes Open
Uranium diazomethanediide complexes can be prepared and their synthesis, structure and reactivity were explored. Reaction of the uranium imido compound [ η 5 ‐1,2,4‐(Me 3 Si) 3 C 5 H 2 ] 2 U=N( p ‐tolyl)(dmap) ( 1 ) or [ η 5 ‐1,3‐(Me 3 C) …
View article: Experimental and Computational Studies on Uranium Diazomethanediide Complexes
Experimental and Computational Studies on Uranium Diazomethanediide Complexes Open
Uranium diazomethanediide complexes can be prepared and their synthesis, structure and reactivity were explored. Reaction of the uranium imido compound [ η 5 ‐1,2,4‐(Me 3 Si) 3 C 5 H 2 ] 2 U=N( p ‐tolyl)(dmap) ( 1 ) or [ η 5 ‐1,3‐(Me 3 C) …
View article: CCDC 2243486: Experimental Crystal Structure Determination
CCDC 2243486: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: A Comprehensive Study Concerning the Synthesis, Structure, and Reactivity of Terminal Uranium Oxido, Sulfido, and Selenido Metallocenes
A Comprehensive Study Concerning the Synthesis, Structure, and Reactivity of Terminal Uranium Oxido, Sulfido, and Selenido Metallocenes Open
Terminal uranium oxido, sulfido, and selenido metallocenes were synthesized, and their reactivity was comprehensively studied. Heating of an equimolar mixture of [η5-1,2,4-(Me3Si)3C5H2]2UMe2 (2) and [η5-1,2,4-(Me3Si)3C5H2]2U(NH-p-tolyl)2 (…
View article: CCDC 2235529: Experimental Crystal Structure Determination
CCDC 2235529: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: Influence of the 1,2,4-Tri-<i>tert</i>-butylcyclopentadienyl Ligand on the Reactivity of the Uranium Bipyridyl Metallocene [η<sup>5</sup>-1,2,4-(Me<sub>3</sub>C)<sub>3</sub>C<sub>5</sub>H<sub>2</sub>]<sub>2</sub>U(bipy)
Influence of the 1,2,4-Tri-<i>tert</i>-butylcyclopentadienyl Ligand on the Reactivity of the Uranium Bipyridyl Metallocene [η<sup>5</sup>-1,2,4-(Me<sub>3</sub>C)<sub>3</sub>C<sub>5</sub>H<sub>2</sub>]<sub>2</sub>U(bipy) Open
The uranium bipyridyl metallocene, [η5-1,2,4-(Me3C)3C5H2]2U(bipy) (2), prepared from [η5-1,2,4-(Me3C)3C5H2]2UCl2 (1) and 2,2′-bipyridine in the presence of potassium graphite (KC8) has been evaluated in small-molecule activation. In contac…
View article: Highly enantioselective Rh-catalyzed asymmetric reductive dearomatization of multi-nitrogen polycyclic pyrazolo[1,5-<i>a</i>]pyrimidines
Highly enantioselective Rh-catalyzed asymmetric reductive dearomatization of multi-nitrogen polycyclic pyrazolo[1,5-<i>a</i>]pyrimidines Open
A highly enantioselective Rh-catalyzed reductive dearomatization of pyrazolo[1,5- a ]pyrimidines has been realized for the first time by two strategies to afford chiral 4,5,6,7-tetrahydropyrazolo[1,5- a ]pyrimidines with excellent enantios…
View article: CCDC 2214887: Experimental Crystal Structure Determination
CCDC 2214887: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214889: Experimental Crystal Structure Determination
CCDC 2214889: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214883: Experimental Crystal Structure Determination
CCDC 2214883: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214904: Experimental Crystal Structure Determination
CCDC 2214904: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214892: Experimental Crystal Structure Determination
CCDC 2214892: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214901: Experimental Crystal Structure Determination
CCDC 2214901: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214893: Experimental Crystal Structure Determination
CCDC 2214893: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214903: Experimental Crystal Structure Determination
CCDC 2214903: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214881: Experimental Crystal Structure Determination
CCDC 2214881: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214886: Experimental Crystal Structure Determination
CCDC 2214886: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214880: Experimental Crystal Structure Determination
CCDC 2214880: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214878: Experimental Crystal Structure Determination
CCDC 2214878: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214891: Experimental Crystal Structure Determination
CCDC 2214891: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214895: Experimental Crystal Structure Determination
CCDC 2214895: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214902: Experimental Crystal Structure Determination
CCDC 2214902: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214894: Experimental Crystal Structure Determination
CCDC 2214894: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214877: Experimental Crystal Structure Determination
CCDC 2214877: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …
View article: CCDC 2214890: Experimental Crystal Structure Determination
CCDC 2214890: Experimental Crystal Structure Determination Open
An entry from the Cambridge Structural Database, the world’s repository for small molecule crystal structures. The entry contains experimental data from a crystal diffraction study. The deposited dataset for this entry is freely available …